混合碱处理制备微介孔催化剂及其噻吩烷基化催化性能

以SiO_2/Al2O3物质的量比为50的H-ZSM-5分子筛为母体,分别采用Na_2CO_3溶液处理后加入TPAOH溶液进行二次晶化法以及Na_2CO_3/TPAOH混合溶液同时处理法,制备了微孔-介孔多级孔HZSM-5催化剂,对其噻吩烷基化反应催化性能进行了研究。结果表明,采用4 mol/L的Na_2CO_3溶液处理后的催化剂在TPAOH溶液中发生了二次晶化;当TPAOH溶液浓度为0.3 mol/L、晶化温度为170℃、晶化时间为24 h时,得到的HZ(CO_2-3-TPA+,0.3-24-170)催化剂具有适宜的孔径和酸性,其噻吩烷基化转化率最高(99.1%)。而Na_2CO_3/TPAOH同时处理HZSM-5分子筛所得的催化剂,由于生成大量SiO_2堵塞了孔道,覆盖了催化剂表面,降低了催化剂的平均孔径和酸性,不适合噻吩烷基化反应。     

浮力对混合对流流动及换热特性的影响

用热线和冷线相结合的技术测量垂直圆管内逆混合对流流体的平均速度、 温度以及它们的脉动. 较详细地研究了浮力对逆混合对流的流动特性和传热特性的影响. 评 估了实验中采用的冷线测量温度补偿速度探头温度敏感的影响. 逆混合对流的传热结果用无 量纲参数Ω (Ω= Grd / Red2 )来表示，其中，基于管道直 径的雷诺数Red变化范围为900~18000, 浮力参数Ω变化范围为 0.004899~0.5047. 研究结果表明，浮力对逆混合对流的换热有强化作用. 随着葛拉晓夫数Grd的增加，温度脉动，流向雷诺正应力和流向温度通量增 大，并且在靠近壁面的流体区域尤其明显. 热线与冷线相结合的技术适合于研究非绝热的流 动测量，可以用于研究浮力对流动和换热特性的影响.     

等速上仰翼型动态失速现象研究

翼型大迎角绕流的静态失速将造成升力突降和气动性能急剧恶化，但利用非定常运动所产生 的动态失速效应，可以大大地延缓气流分离和失速现象的发生. 采用Rogers发 展的双时间步Roe格式，求解拟压缩性修正不可压N-S方程. 数值模拟了低雷诺数 ($Re=4.8 \times 10^{4}$)条件下NACA0015翼型作等速上仰($\alpha =0^{\circ} \sim 60^{\circ}$)的动态失速过程，同Walker的试验结果比 较，验证了计算结果的正确性. 研究了该过程中主涡、二次涡和三次涡的发展，升 力系数随攻角变化，以及不同上仰速度对动态失速效应所造成的影响.     

稳恒扩展裂纹尖端的弹粘塑性场

采用弹粘塑性力学模型代替通常的弹塑性模型，对于I型和Ⅱ型问题，分别求得了不可压缩材料中平面应变动态扩展裂纹尖端的指数奇异性场和对数奇异性场，消除了弹塑性解中存在的塑性激波。通过数值计算，分别求得了两种奇异属性的分界线，建立起统一的裂纹尖端奇异性场。     

A variant of the low-Reynolds-number two-equation turbulence model applied to variable property mixed convection flows

Previous work has demonstrated that the low-Reynolds-number model of Launder and Sharma (1974) offers significant advantages over other two-equation turbulence models in the computation of highly non-universal buoyancy-influenced (or “mixed convection”) pipe flows. It is known, however, that the Launder and Sharma model does not possess high quantitative accuracy in regard to simpler forced convection flows. A variant of the low-Reynolds-number scheme is developed here by reference to data for constant property forced convection flows. The re-optimized model and the Launder and Sharma formulation are then examined against experimental measurements for mixed convection flows, including cases in which variable property effects are significant.     

An efficient method for solving the mixed direct-inverse problem of the transonic rotational flow in plane casades

The method in [1] has been extended to the case of rotational flow in this paper. A new method for dealing with the shock wave is presented. This method has the advantages of both the shock-fitting and the shock capturing methods. The direct problem and the mixed direct-inverse problem of the rotational flow in a transonic plane cascade at both design and off design conditions are solved, and the results show that the present method has rapid convergence rate and high accuracy even for the flow with moderately strong shocks. The calculations have been carried out on the DPS-8 computer, and for the direct problem, only 50–80 iterations are needed, and 50–80 seconds of CPU time are required.     

Nano-Fabrication by Cathodic Plasma Electrolysis

Cathodic plasma electrolytic (CPE) techniques are new groups of coating processes, which can be used for fabrication of nanostructured layers on surface of a wide range of metallic substrates. The most exciting visible feature of these atmospheric-based plasma techniques is continuous sparking on processed surface inside an electrolyte. Unlike the anodic part of plasma electrolysis (usually known as plasma electrolytic oxidation (PEO) or micro arc oxidation (MAO)), which is commonly used for oxidation of light metals/alloys such as aluminum, titanium and magnesium, CPE techniques can clean and coat different metals and alloys such as steel, copper, and light metals/alloys with formation of wide range of nanostructures including complex carbides, carbonitrides, intermetallics, and even oxides. It has been observed that the properties of obtained layers depend on the characteristics of achieved nanostructures such as average size, distribution and average coordination number of nanocrystallites. Furthermore, the properties of the processed surface can be tailored by tailoring the nanostructure characteristics. There is limited literature available on the mechanism of CPE and its connection to the morphology of nanostructured layers. This article addresses the two important aspects of CPE, namely characterization of nanostructured layers and mechanism of cathodic plasma electrolysis, which are reviewed in accordance to the morphology of fabricated nanostructures.     

一种基于组合不确定型OWA算子的区间数群决策方法

在群决策中,由于决策环境的不确定性,决策者给出区间效信息.基于区间数可能度矩阵公式和互补判断矩阵的排序公式,提出了一种组合不确定型OWA算子,它是不确定型OWA算子的推广.该算子能集结群决策中区间数信息,文中给出了其在应用的具体步骤,最后实例分析说明了该方法的有效性和可行性.     

具广义V-不变凸多目标变分的混合对偶性

在函数广义V-不变凸性的条件下,建立了多目标变分关于有效解的混合对偶理论.