全文获取类型
收费全文 | 2621篇 |
免费 | 192篇 |
国内免费 | 347篇 |
专业分类
化学 | 1536篇 |
晶体学 | 3篇 |
力学 | 136篇 |
综合类 | 90篇 |
数学 | 1153篇 |
物理学 | 242篇 |
出版年
2024年 | 2篇 |
2023年 | 19篇 |
2022年 | 65篇 |
2021年 | 61篇 |
2020年 | 77篇 |
2019年 | 51篇 |
2018年 | 52篇 |
2017年 | 107篇 |
2016年 | 94篇 |
2015年 | 80篇 |
2014年 | 113篇 |
2013年 | 162篇 |
2012年 | 127篇 |
2011年 | 131篇 |
2010年 | 118篇 |
2009年 | 161篇 |
2008年 | 187篇 |
2007年 | 165篇 |
2006年 | 140篇 |
2005年 | 154篇 |
2004年 | 128篇 |
2003年 | 106篇 |
2002年 | 121篇 |
2001年 | 88篇 |
2000年 | 87篇 |
1999年 | 72篇 |
1998年 | 83篇 |
1997年 | 60篇 |
1996年 | 67篇 |
1995年 | 54篇 |
1994年 | 46篇 |
1993年 | 24篇 |
1992年 | 35篇 |
1991年 | 10篇 |
1990年 | 27篇 |
1989年 | 16篇 |
1988年 | 17篇 |
1987年 | 11篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1984年 | 5篇 |
1982年 | 7篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1959年 | 2篇 |
1936年 | 1篇 |
排序方式: 共有3160条查询结果,搜索用时 62 毫秒
31.
Zhangjian Hu 《Journal of Mathematical Analysis and Applications》2004,296(2):435-454
We define an extended Cesàro operator Tg with holomorphic symbol g in the unit ball B of Cn. For a large class of weights w we characterize those g for which Tg is bounded (or compact) from Bergman space Lpa,w(B) to Lqa,w(B), 0<p,q<∞. In addition, we obtain some results about equivalent norms, the norm of point evaluation functionals, and the interpolation sequences on Lpa,w(B). 相似文献
32.
多指标区间决策的理想点贴近法 总被引:5,自引:0,他引:5
研究了指标的权重不能完全确定但知道其所在区域的条件下的多指标决策问题 ,给出了方案与理想解的贴近度及其算法 ,按贴近度的大小可以对方案进行排序 .它同传统的决策方法相比较 ,具有需要信息量少 ,简单可靠等特点 .最后用该决策方法分析了一个实际问题 . 相似文献
33.
We give asymptotic formulas for the multiplicities of weights and irreducible summands in high-tensor powers Vλ⊗N of an irreducible representation Vλ of a compact connected Lie group G. The weights are allowed to depend on N, and we obtain several regimes of pointwise asymptotics, ranging from a central limit region to a large deviations region. We use a complex steepest descent method that applies to general asymptotic counting problems for lattice paths with steps in a convex polytope. 相似文献
34.
Ro Jin Pak Ayanendranath Basu 《Annals of the Institute of Statistical Mathematics》1998,50(3):503-521
This paper deals with the minimum disparity estimation in linear regression models. The estimators are defined as statistical quantities which minimize the blended weight Hellinger distance between a weighted kernel density estimator of errors and a smoothed model density of errors. It is shown that the estimators of the regression parameters are asymptotic normally distributed and efficient at the model if the weights of the density estimators are appropriately chosen. 相似文献
35.
36.
Sridevi Kaiti Eric Fossum 《Journal of polymer science. Part A, Polymer chemistry》2006,44(6):2099-2106
A thorough study of the polymerization behavior of 4‐fluoro‐4′‐hydroxytriphenyl‐phosphine oxide, 2 , under nucleophilic aromatic substitution reactions has been carried out. The synthesis of 2 was achieved in excellent yields by the reaction of bis(4‐fluorophenyl)phenylphosphine oxide, 1 , with one equivalent of potassium hydroxide in DMSO/water. The structure and purity of 2 were confirmed via 1H, 13C, and 31P NMR spectroscopy along with elemental analysis. Polymerization reactions of 2 in NMP or DMSO at 180 °C provided the corresponding linear poly(arylene ether phosphine oxide)s, PAEPOs, with number average molecular weights, Mn, ranging from 11,700 to 36,500 Da. All of the polymer samples were completely soluble in chloroform, tetrahydrofuran, DMSO, NMP, and DMAc. The polymerization reactions were accompanied by a competing intramolecular process that resulted in the formation of cyclic oligomeric species that were removed via a final precipitation from methanol. Analysis using 31P NMR spectroscopy and size exclusion chromatography (SEC) confirmed that the majority of the lower molecular weight cyclic species were removed via this process. The polymer samples formed tough films when chloroform solutions were slowly evaporated on a glass slide. The PAEPO samples prepared in this study exhibited excellent thermal stability with Td (5%) values between 503 and 542 in air while the glass transition temperatures ranged from 223 to 237 °C. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2099–2106, 2006 相似文献
37.
Chen Hou Rongjun Qu Chunnuan Ji Chunhua Wang Chengguo Wang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):219-225
FeCl3 coordinated by isophthalic acid was first used as a catalyst in the azobisisobutyronitrile‐initiated reverse atom transfer radical polymerization of acrylonitrile. N,N‐Dimethylformamide was used as a solvent to improve the solubility of the ligand. An FeCl3‐to‐isophthalic acid ratio of 0.5 not only gave the best control of the molecular weight and its distribution but also provided rather a rapid reaction rate. The effects of different solvents on the polymerization of acrylonitrile were also investigated. The rate of the polymerization in N,N‐dimethylformamide was faster than that in propylene carbonate and toluene. The molecular weight of polyacrylonitrile agreed reasonably well with the theoretical molecular weight in N,N‐dimethylformamide. The rate of polymerization increased with increasing polymerization temperature, and the apparent activation energy was calculated to be 59.9 kJ mol?1. Reverse atom transfer radical polymerization was first used to successfully synthesize acrylonitrile polymers with a molecular weight higher than 80,000 and a narrow polydispersity as low as 1.22. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 219–225, 2006 相似文献
38.
Siripon Anantawaraskul João B. P. Soares Preechathorn Jirachaithorn Jumras Limtrakul 《Journal of Polymer Science.Polymer Physics》2006,44(19):2749-2759
Four polyethylene samples (PE) with different molecular weight distributions (MWD) were analyzed by crystallization analysis fractionation (Crystaf) at several cooling rates to investigate the effect of MWD and cooling rate on their Crystaf profiles. Using these results, we developed a mathematical model for Crystaf that considers crystallization kinetic effects, which are ignored in all previous Crystaf models. The Crystaf model we proposed can fit the experimental Crystaf profiles of the 4 polyethylene resins very well. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2749–2759, 2006 相似文献
39.
For the problem of estimating the normal mean based on a random sample X
1,...,X
n when a prior value 0 is available, a class of shrinkage estimators % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-qqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xHapdbiqaaeGaciGaaiaabeqaamaabaabaaGcbaWaaubeaeqaje% aWbaGaamOBaaWcbeqdbaGafqiVd0MbaKaaaaGccaqGGaGaaiikaiaa% dUgacaGGPaGaeyypa0Jaam4AaiaacIcadaqfqaqabKqaahaacaqGUb% aaleqaneaacaqGubaaaOGaaiykaiaabccadaqfqaqabKqaahaacaWG% UbaaleqaneaaceqGybGbaebaaaGccaqGGaGaey4kaSIaaeiiaiaacI% cacaaIXaGaaeiiaiabgkHiTiaabccacaWGRbGaaiikamaavababeqc% baCaaiaab6gaaSqab0qaaiaabsfaaaGccaGGPaGaaiykamaavababe% qcbaCaaiaad6gaaSqab0qaaiabeY7aTbaaaaa!5615!\[\mathop {\hat \mu }\nolimits_n {\rm{ }}(k) = k(\mathop {\rm{T}}\nolimits_{\rm{n}} ){\rm{ }}\mathop {{\rm{\bar X}}}\nolimits_n {\rm{ }} + {\rm{ }}(1{\rm{ }} - {\rm{ }}k(\mathop {\rm{T}}\nolimits_{\rm{n}} ))\mathop \mu \nolimits_n \] is considered, where % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-qqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xHapdbiqaaeGaciGaaiaabeqaamaabaabaaGcbaWaaubeaeqaje% aWbaGaamOBaaWcbeqcdawaaiaadsfaaaGccaqGGaGaaeypaiaabcca% caWGUbWaaWbaaSqabeaacaaIXaGaai4laiaaikdaaaGccaGGOaWaa0% aaaeaacaWGybaaamaaBaaajeaWbaGaamOBaaWcbeaakiaabccacqGH% sislcaqGGaWaaubeaeqajeaWbaGaaGimaaWcbeqdbaGaaeiVdaaaki% aacMcacaqGGaGaae4laiabeccaGiabeo8aZbaa!4C33!\[\mathop T\nolimits_n {\rm{ = }}n^{1/2} (\overline X _n {\rm{ }} - {\rm{ }}\mathop {\rm{\mu }}\nolimits_0 ){\rm{ /}} \sigma \] and k is a weight function. For certain choices of k, % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-qqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xHapdbiqaaeGaciGaaiaabeqaamaabaabaaGcbaWaaubeaeqaje% aWbaGaamOBaaWcbeqdbaGafqiVd0MbaKaaaaGccaqGGaGaaiikaiaa% dUgacaGGPaaaaa!3CEE!\[\mathop {\hat \mu }\nolimits_n {\rm{ }}(k)\] coincides with previously studied preliminary test and shrinkage estimators. We consider choosing k from a natural non-parametric family of weight functions so as to minimize average risk relative to a specified prior p. We study how, by varying p, the MSE efficiency (relative to \-X) properties of % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-qqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xHapdbiqaaeGaciGaaiaabeqaamaabaabaaGcbaWaaubeaeqaje% aWbaGaamOBaaWcbeqdbaGafqiVd0MbaKaaaaGccaqGGaGaaiikaiaa% dUgacaGGPaaaaa!3CEE!\[\mathop {\hat \mu }\nolimits_n {\rm{ }}(k)\] can be controlled. In the process, a certain robustness property of the usual family of posterior mean estimators, corresponding to the conjugate normal priors, is observed. 相似文献
40.
α—甲基苯乙烯离子聚合体分子量分布 总被引:1,自引:0,他引:1
聚α-甲基苯乙烯-丁二烯-α-甲基苯乙烯嵌段共聚物是一种性能优异的热塑性弹性体。常温下,α-甲基苯乙烯的聚合是在极性添加剂存在下进行的,添加剂的种类,用量及聚合温度不仅影响聚合动力学,尚且影响聚合物分子量及其分布,控制α-甲基苯乙烯聚合速率、 相似文献