首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9919篇
  免费   696篇
  国内免费   346篇
化学   3239篇
晶体学   35篇
力学   659篇
综合类   58篇
数学   4727篇
物理学   2243篇
  2024年   16篇
  2023年   155篇
  2022年   247篇
  2021年   308篇
  2020年   387篇
  2019年   335篇
  2018年   342篇
  2017年   384篇
  2016年   338篇
  2015年   305篇
  2014年   549篇
  2013年   1206篇
  2012年   562篇
  2011年   570篇
  2010年   444篇
  2009年   688篇
  2008年   693篇
  2007年   535篇
  2006年   429篇
  2005年   411篇
  2004年   309篇
  2003年   206篇
  2002年   182篇
  2001年   114篇
  2000年   145篇
  1999年   154篇
  1998年   122篇
  1997年   120篇
  1996年   113篇
  1995年   73篇
  1994年   65篇
  1993年   52篇
  1992年   47篇
  1991年   25篇
  1990年   16篇
  1989年   23篇
  1988年   16篇
  1987年   18篇
  1986年   17篇
  1985年   43篇
  1984年   50篇
  1983年   20篇
  1982年   25篇
  1981年   26篇
  1980年   17篇
  1979年   16篇
  1978年   12篇
  1977年   8篇
  1976年   7篇
  1973年   5篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
101.
Two-dimensional antiplane time-harmonic Green’s functions for a circular inhomogeneity with an imperfect interface are derived. Here the linear spring model with vanishing thickness is employed to characterize the imperfect interface. Explicit expressions for the displacement and the stress fields induced by time-harmonic antiplane line forces located both in the unbounded matrix and in the circular inhomogeneity are presented. When the circular frequency approaches zero, our results reduce to those for the static case. Numerical results are presented to show the influence of the frequency and the imperfection of the interface on the stress and displacement fields.  相似文献   
102.
本文从理论上讨论了费歇判别与回归模型的等价,指出了利用费歇判别值对企业的综合经济效益进行排序是不合理的,并提出了改进的综合评价方法  相似文献   
103.
Different strains of baker’s yeast(Saccharomyces cerevisiae) were imaged with an atomic force microscope (AFM). The images of uncoated and nonfixed samples were reproducible with high-constrast and nanometer-resolution. Molecules from the polysaccharide surface of the cell wall were pictured and the distance of atoms was measured. The preparation of samples was easy, suggesting that AFM is a useful tool in this type of analyses.  相似文献   
104.
A solution to the BBGKY hierarchy for nonequilibrium distribution functions is obtained within modified boundary conditions. The boundary conditions take into account explicitly both the nonequilibrium one-particle distribution function as well as local conservation laws. As a result, modified group expansions are proposed. On the basis of these expansions, a generalized kinetic equation for hard spheres and a generalized Bogolubov–Lenard–Balescu kinetic equation for a dense electron gas are derived within the polarization approximation.  相似文献   
105.
It is shown that laser evaporation of a solid target followed by adiabatic expansion can be used to produce cold beams of neutral small open shell molecules. LIF is applied to detect CuH (X 1), CH (X 2), SiH (X 2), CuO (X 2), and FeO (X 5). A production of 109±1 molecules/sr in a single pulse is obtained for SiH. For a copper target, the optical emission of the jet plume is discussed.  相似文献   
106.
LetN be a sufficiently large even integer and
  相似文献   
107.
Nan Z  Ren-Qing Y  Xu-Zhang Y  Zhi-Ren L 《Talanta》1985,32(12):1129-1132
A new titrimetric method for determination of tin (4%) in aluminium alloys, tin- and lead-base alloys, solders, white bearing alloys, special bronzes and silver brazing alloys is proposed. HEDTA, Semi-Xylenol Orange and bismuth perchlorate are used as titrant, indicator and back-titrant respectively. Measures are taken to overcome the hydrolysis of Sn(IV). Monochloroacetic acid and ethylene glycol are added as auxiliary agents. The standard deviation of this method was found to be 0.2 mg and its coefficient of variation to vary from 0.25 to 2%, according to amount of tin. A novel method of sample decomposition and a modified method for separating Sn(IV) are also suggested.  相似文献   
108.
0IntroductionIncreasinginterestisfocusedonthestudyofmagnetic,electronicandoptoelectronicpropertiesoflow鄄dimensionalorganic鄄inorganichybridcompoun鄄ds[1~3].Studiesshowthatcomplexconsistingoforganicandinorganiccomponentshavegreatpotentialforthecreationoff…  相似文献   
109.
Luminescent stilbenoid chromophores with diethoxysilane end groups are prepared via Heck reactions. Diethoxysilane-substituted styrenes are used as vinylic components, thus allowing the combined connection of the chromophore to the silane moiety with an extension of the π-system. Monodisperse oligo(phenylenevinylene)s of different conjugation lengths and bromine or iodine as reactive sites are used as coupling partners. Electrical and optical properties are tuned via the length of the conjugated system, electron withdrawing cyanide and electron donating alkoxy side chains, the latter guarantee high solubility of the final compounds.Dedicated to Prof. Dr. H. Ringsdorf on the occasion of his 75th birthday  相似文献   
110.
Three new aromatic diester–dicarboxylic acids containing furan rings, namely, benzofuro[2,3-b]benzofuran-2,9-dicarboxyl-bis-phenyl ester-4,4-dicarboxylic acid, benzofuro[2,3-b]benzofuran-2,9-dicarboxyl-bis-phenyl ester-3,3-dicarboxylic acid and benzofuro[2,3-b]benzofuran-2,9-dicarboxyl-bis-naphthyl ester-2,2-dicarboxylic acid were synthesized by the reaction of benzofuro[2,3-b]benzofuran-2,9-dicarbonyl chloride with 4-hydroxybenzoic acid, 3-hydroxybenzoic acid and 3-hydroxy-naphthalene-2-carboxylic acid, respectively. Diester–dicarboxylic acids were characterized by FT-IR and NMR spectroscopy and elemental analyses. Then, these monomers were converted to aromatic copoly(ester–amide)s by their reaction with various aromatic diamines via the direct polycondensation. These polymers were characterized by viscosity measurements, solubility tests, FT-IR, Ultraviolet and 1H-NMR spectroscopy and thermogravimetry. The polymers with inherent viscosities in the range of 0.16–0.37 dl/g in dimethyl sulfoxide at 30 °C were obtained in high yield. Most of them dissolved readily at room temperature in polar solvents. The synthesized copoly(ester–amide)s possessed glass-transition temperatures from 210–255 °C. The copoly(ester–amide)s exhibited excellent thermal stabilities and had 10% weight loss at temperature above 295 °C under nitrogen atmosphere.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号