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91.
92.
János B. Czirok Ákos Tarcsay Pál D. Mezei András Simon László Balázs 《Supramolecular chemistry》2013,25(10-12):722-728
The size limit of substituents allowing O-through-the-annulus rotation of substituted calix[4]arenes was further extended to the propargyloxy group in 24-propargyloxy-25,26,27-tris(N,N-dimethylcarbamoylmethoxy)-p-tert-butylcalix[4]arene by demonstrating its free but slow motion affording equilibrium between the partial cone and 1,2-alternate conformers. The effect of solvent and upper rim substituents R1 on the conformational inversion was investigated by means of 1H NMR. The rotational isomerisation of the parent (R1 = H) analogue could not unambiguously be detected. The experimental results were supported by comprehensive density functional theory studies. 相似文献
93.
Lisa Roeder Philipp Bender Andreas Tschöpe Rainer Birringer Annette M. Schmidt 《Journal of polymer science. Part A, Polymer chemistry》2012,50(24):1772-1781
The mechanical characterization of complex soft matter by quasi-static magnetometry using nanoscopic magnetic probes is demonstrated for model hydrogels doped with two types of elongated magnetic nanoparticles. Chemically crosslinked poly(acrylamide) (PAAm) hydrogels serve as the matrix in which nickel nanorods or weakly magnetized hematite (α-Fe2O3) ellipsoids are embedded as local probes. We investigated the swelling behavior of the ferrogels in order to verify that their equilibrium swelling degree in water is not influenced by the probes, shows a good correlation with the Frenkel–Flory–Rehner model. The proposed magnetomechanical method relies on a correlation between the shear modulus of the PAAm hydrogel matrix and the coercive fields of the corresponding isotropic ferrogels. By extending the Stoner–Wohlfarth model for single-domain blocked magnetic particles by a term for particle rotation in an elastic matrix, information on the shear modulus of the matrix can be obtained. Comparison of the results with the expected relation from rubber elasticity theory illustrates both the general potential as well as the limits of the approach. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2012 相似文献
94.
Structures of Highly Twisted Amides Relevant to Amide N−C Cross‐Coupling: Evidence for Ground‐State Amide Destabilization 下载免费PDF全文
Dr. Vittorio Pace Prof. Dr. Wolfgang Holzer Guangrong Meng Shicheng Shi Prof. Dr. Roger Lalancette D.Sc. Roman Szostak Prof. Dr. Michal Szostak 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(41):14494-14498
Herein, we show that acyclic amides that have recently enabled a series of elusive transition‐metal‐catalyzed N?C activation/cross‐coupling reactions are highly twisted around the N?C(O) axis by a new destabilization mechanism of the amide bond. A unique effect of the N‐glutarimide substituent, leading to uniformly high twist (ca. 90°) irrespective of the steric effect at the carbon side of the amide bond has been found. This represents the first example of a twisted amide that does not bear significant steric hindrance at the α‐carbon atom. The 15N NMR data show linear correlations between electron density at nitrogen and amide bond twist. This study strongly supports the concept of amide bond ground‐state twist as a blueprint for activation of amides toward N?C bond cleavage. The new mechanism offers considerable opportunities for organic synthesis and biological processes involving non‐planar amide bonds. 相似文献
95.
Malek Taher Maghsoodlou Nourollah Hazeri Sayyed Mostafa Habibi Khorasani Aqil Ghulame Shahzadeh Mahmoud Nassiri 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):913-919
Stable crystalline phosphorus ylides were obtained in excellent yields from the 1:1:1 addition reaction between triphenylphosphine and dialkyl acetylenedicarboxylates in the presence of strong NH acids, such as indole and 2-methyl indole, 3-methyl indole, and 5-boromo indole. These stable ylides exist in a solution as a mixture of two geometrical isomers as a result of the restricted rotation around the carbon–carbon partial double bond resulting from the conjugation of the ylide moiety with the adjacent carbonyl group. 相似文献
96.
In Korchmáros et al. (2018)one-factorizations of the complete graph are constructed for with any odd prime power such that either or . The arithmetic restriction is due to the fact that the vertices of in the construction are the points of a conic in the finite plane of order . Here we work on the Euclidean plane and describe an analogous construction where the role of is taken by a regular -gon. This allows us to remove the above constraints and construct one-factorizations of for every even . 相似文献
97.
Beam structures undergoing finite deflections and rotations in space have extensive application in the subsea industry particularly for the analysis of holistic systems with larger numbers of mooring and riser components. In using the finite element analysis approach, there is an increasing requirement for large element sizes which preserve accuracy with regard to the coupling of axial, bending and torsion response.The authors outline a method for improving the current state of practice for the analysis of riser systems. The approach draws on the convected coordinates method, Euler–Bernoulli beam theory, the principle of virtual work and the finite element method. Two quasi-rotation measures are developed including a quasi-material rotation definition for rotational deformation relative to the convected axis of a beam and a quasi-space rotation definition to deal with the path dependent nature of rotations in three dimensions.The novel aspect of this work is to relate the rate of change of the quasi-material rotation vector along the beam axis to a linear transformation of the beam axis rate-of-rotation vector through utilising the convected coordinates axes system. In this way, incremental values of quasi-material rotation are directly linked to incremental values of nodal quasi-space rotation and a global Newton–Raphson solution technique for interconnecting beam elements is straightforward to assemble.Furthermore, this leads to accurate definitions of coupled axial, bending and torque response for beams with significant deflection. The approach has particular advantages in the analysis of subsea riser sections. Also, the accuracy of the solution is preserved for a fewer number of elements compared to alternative solutions for computationally sensitive load cases with highly non-linear loading regimes. 相似文献
98.
Natasha Samko 《Mathematical Methods in the Applied Sciences》2020,43(16):9416-9434
We find conditions for the boundedness of integral operators commuting with dilations and rotations in a local generalized Morrey space. We also show that under the same conditions, these operators preserve the subspace of such Morrey space, known as vanishing Morrey space. We also give necessary conditions for the boundedness when the kernel is non-negative. In the case of classical Morrey spaces, the obtained sufficient and necessary conditions coincide with each other. In the one-dimensional case, we also obtain similar results for global Morrey spaces. In the case of radial kernels, we also obtain stronger estimates of via spherical means of . We demonstrate the efficiency of the obtained conditions for a variety of examples such as weighted Hardy operators, weighted Hilbert operator, their multidimensional versions, and others. 相似文献
99.
A graph with at least vertices is said to be distance -extendable if, for any matching of with edges in which the edges lie at distance at least pairwise, there exists a perfect matching of containing . In this paper we prove that every 5-connected triangulation on the projective plane of even order is distance 3 7-extendable and distance 4 -extendable for any . 相似文献
100.