Molecular structure and spectral properties of thionaphthalimides

The molecular structure and absorption spectra of monothio- and dithio-naphthalimides were compared to their naphthalimide analogues using AM1, PM3 and ZINDO/S semiempirical quantum chemical methods. The substitution of the 4R-naphthalimide oxygen atoms by sulphur atoms resulted in a red-shift of the absorption spectra by Δλ_max60-65 and 100-140 nm, respectively. The thionated naphthalimide derivatives do not show observable fluorescence due to intersystem crossing to the triplet -states localised at the CS groups. The -absorption bands of monothioimides are located at 525-580 nm (ε=60-80) and those for dithioimides at 535-560 nm (ε=140-390) and 628-686 nm (ε=34-68). None of these transitions are solvent sensitive. The -transitions of N-phenylthioimides have also a small contribution from -states due to a partial conjugation between CS group and π-electronic system of the N-phenyl ring. As a result, the bands of aromatic substituted N-phenylthioimides are red-shifted as compared to those of the aliphatic N-methyl-thioimides.     

De Sitter空间中紧致类空超曲面的积分公式及其Goddard猜想的应用

本文对ｄｅＳｉｔｅｒ空间Ｓｎ＋１１（１）中紧致类空超曲面建立Ｍｉｎｋｏｗｓｋｉ型公式，并给出其到ｒ－次（ｒ＝１，２，…，ｎ－１）平均曲率为常数超曲面的应用．当ｒ＝１时，我们得到Ｍｏｎｔｉｅｌ的结果．     

An Interacting Gauge Field Theoretic Model for Hodge Theory: Basic Canonical Brackets

We derive the basic canonical brackets amongst the creation and annihilation operators for a two （1 ＋ 1）- dimensional （2D） gauge field theoretic model of an interacting Hodge theory where a U（1） gauge field （Aμ） is coupled with the fermionic Dirac fields （ψ and ψ）. In this derivation, we exploit the spin-statistics theorem, normal ordering and the strength of the underlying six infinitesimal continuous symmetries （and the concept of their generators） that are present in the theory. We do not use the definition of the canonical conjugate momenta （corresponding to the basic fields of the theory） anywhere in our whole discussion. Thus, we conjecture that our present approach provides an alternative to the canonical method of quantization for a class of gauge field theories that are physical examples of Hodge theory where the continuous symmetries （and corresponding generators） provide the physical realizations of the de Rham cohomological operators of differential geometry at the algebraic level.     

The thermoelectric working fluid: Thermodynamics and transport

Thermoelectric devices are heat engines, which operate as generators or refrigerators using the conduction electrons as a working fluid. The thermoelectric heat-to-work conversion efficiency has always been typically quite low, but much effort continues to be devoted to the design of new materials boasting improved transport properties that would make them of the electron crystal–phonon glass type of systems. On the other hand, there are comparatively few studies where a proper thermodynamic treatment of the electronic working fluid is proposed. The present article aims at contributing to bridge this gap by addressing both the thermodynamic and transport properties of the thermoelectric working fluid covering a variety of models, including interacting systems.     

Intermittency as a transition to turbulence in pipes: A long tradition from Reynolds to the 21st century

Intermittencies are commonly observed in fluid mechanics, and particularly, in pipe flows. Initially observed by Reynolds (1883), it took one century for reaching a rather full understanding of this phenomenon whose irregular dynamics (apparently stochastic) puzzled hydrodynamicists for decades. In this brief (non-exhaustive) review, mostly focused on the experimental characterization of this transition between laminar and turbulent regimes, we present some key contributions for evidencing the two concomittant and antagonist processes that are involved in this complex transition and were suggested by Reynolds. It is also shown that a clear explicative model was provided, based on the nonlinear dynamical systems theory, the experimental observations in fluid mechanics only providing an applied example, due to its obvious generic nature.     

WENO schemes applied to the quasi-relativistic Vlasov–Maxwell model for laser–plasma interaction

In this paper we focus on WENO-based methods for the simulation of the 1D Quasi-Relativistic Vlasov–Maxwell (QRVM) model used to describe how a laser wave interacts with and heats a plasma by penetrating into it. We propose several non-oscillatory methods based on either Runge–Kutta (explicit) or Time-Splitting (implicit) time discretizations. We then show preliminary numerical experiments.     

Quantum simulation of zero-temperature quantum phases and incompressible states of light via non-Markovian reservoir engineering techniques

We review recent theoretical developments on the stabilization of strongly correlated quantum fluids of light in driven-dissipative photonic devices through novel non-Markovian reservoir engineering techniques. This approach allows one to compensate losses and refill selectively the photonic population so as to sustain a desired steady state. It relies in particular on the use of a frequency-dependent incoherent pump, which can be implemented, e.g., via embedded two-level systems maintained at a strong inversion of population. As specific applications of these methods, we discuss the generation of Mott Insulator (MI) and Fractional Quantum Hall (FQH) states of light. As a first step, we present the case of a narrowband emission spectrum and show how this allows for the stabilization of MI and FQH states under the condition that the photonic states are relatively flat in energy. As soon as the photonic bandbwidth becomes comparable to the emission linewidth, important non-equilibrium signatures and entropy generation appear, and a novel dissipative phase transition from a Mott Insulating state toward a superfluid (SF) phase is unveiled. As a second step, we review a more advanced configuration based on reservoirs with a broadband frequency distribution, and we highlight the potential of this configuration for the quantum simulation of equilibrium quantum phases at zero temperature with tunable chemical potential. As a proof of principle, we establish the applicability of our scheme to the Bose–Hubbard model by confirming the presence of a perfect agreement with the ground-state predictions both in the Mott insulating and superfluid regions, and more generally in all parts of the parameter space. Future prospects towards the quantum simulation of more complex configurations are finally outlined, along with a discussion of our scheme as a concrete realization of quantum annealing.     

Detecting itinerant single microwave photons

Single-photon detectors are fundamental tools of investigation in quantum optics and play a central role in measurement theory and quantum informatics. Photodetectors based on different technologies exist at optical frequencies and much effort is currently being spent on pushing their efficiencies to meet the demands coming from the quantum computing and quantum communication proposals. In the microwave regime, however, a single-photon detector has remained elusive, although several theoretical proposals have been put forth. In this article, we review these recent proposals, especially focusing on non-destructive detectors of propagating microwave photons. These detection schemes using superconducting artificial atoms can reach detection efficiencies of 90% with the existing technologies and are ripe for experimental investigations.     

Dephosphatation under UV light of water by Ti-PILC with activation by secondary species (La,Se, and Rb)

Me/Ti-PILC catalysts (Me: La, Se, Rb) were prepared with 60% in weight of Ti-species and 3% in weight of Me-secondary species added under ultrasounds. All materials were characterized by XRF, XPS, XRD, BET, HR-TEM/EDS, FEG-SEM and UV-vis. Three kinds of Ti-oxide nanoparticles were identified: (1) Ti-pillars within the clay layers, (2) rutile nanoflowers, and (3) anatase. In UV-vis spectra, no significant change in the band-gap was observed. In La and Se samples, small variations of the anatase XRD lines are associated with cationic diffusion after deposition of secondary species and calcination. An O1s XPS-peak (533.5 eV) is attributed to oxygen vacancies generated by this diffusion. Phosphate photo-removal in water was studied using phosphoric acid solution (75.97 g L⁻¹). Dephosphatation is significantly improved in the presence of Me-species as La/Ti-PILC > Se/Ti-PILC > Rb/Ti-PILC > Ti-PILC. Partial dephosphatation by adsorption is possible in the dark but is strongly improved by UV irradiation. With a La catalyst and under UV irradiation, phosphates (6.6 × 10⁻³ mol L⁻¹) were recovered in less than 70 min. Therefore, Me/Ti-PILC have a great potential as photocatalysts for the treatment of wastewaters and the recovery of phosphates.