Biodegradable polymers based on renewable resources. VII. Novel random and alternating copolycarbonates from 1,4:3,6‐dianhydrohexitols and aliphatic diols

Novel copolycarbonates containing 1,4:3,6‐dianhydro‐D ‐glucitol or 1,4:3,6‐dianhydro‐D ‐mannitol units, with various methylene chain lengths, were synthesized by bulk and solution polycondensations, of several combinations of carbonate‐modified sugar derivatives and aliphatic diols. Bulk polycondensations of 1,4:3,6‐dianhydro‐2,5‐bis‐O‐(phenoxycarbonyl)‐D ‐glucitol or 1,4:3,6‐dianhydro‐2,5‐bis‐O‐(phenoxycarbonyl)‐D ‐mannitol with four α,ω‐alkanediols having methylene chain lengths of 4, 6, 8, and 10, respectively, at 180 °C afforded the corresponding copolycarbonates with number‐average molecular weight (M_n) values up to 19.₂ × 10³. ¹³C NMR analysis disclosed that these polymers had scrambled structures in which the sugar carbonate and aliphatic carbonate moieties were nearly randomly distributed along a polymer chain. However, solution polycondensations between 1,4:3,6‐dianhydro‐2,5‐bis‐O‐(p‐nitrophenoxycarbonyl)‐D ‐glucitol or 1,4:3,6‐dianhydro‐2,5‐bis‐O‐(p‐nitrophenoxycarbonyl)‐D ‐mannitol, and the α,ω‐alkanediols in sulfolane or dimethyl sulfoxide at 60 °C gave well‐defined copolycarbonates having regular structures consisting of alternating sugar carbonate and aliphatic carbonate moieties with M_n values up to 33.₈ × 10³. Differential scanning calorimetry demonstrated that all the copolycarbonates were amorphous with glass‐transition temperatures ranging from 1 to 65 °C, which decreased with increasing lengths of the methylene chain of the aliphatic diols. Additionally, all the copolycarbonates were stable up to 310–330 °C as estimated by thermogravimetric analysis. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2312–2321, 2003     

水资源可再生能力综合评价的遗传加权物元模型

为了科学地计算水资源可再生能力评价指标的权重 ,使评价方法具有可操作性 ,采用主、客观相结合的赋权基点法 ,以全局收敛的格雷码加速遗传算法为工具来确定权重 ,并结合物元分析理论 ,建立了一种新的评价模型——遗传加权物元模型 .文中给出了该模型实施的详细步骤 ,对黄河流域 9个行政分区的水资源可再生能力进行了综合评价 ,取得了较好的效果 .     

工业企业余热资源量计算的计算机辅助系统

现代流行的能源管理方面的软件多是利用字符型数据库系统进行对能源数据的统计分析并生成电子报表山。余热资源量的计算涉及不多。这项工作恰恰是能源管理系统中难度较大问题之一。其主要原因是能源转换和耗能设备种类繁多、运行工况复杂多变、现场能源监测数据不全、计算工作量大的缘故。对余热资源量的计算和分析要投入大量的精力和财力。因此，开发余热资源量的计算和统计分析的应用软件是非常必要的。11业余热载体的种类及其余热资源量的计算方法1．1工业余热资源分类工业余热资源按载热体形态可分为三大类：固态载体余热资源、液态载体…     

Development of novel phosphorus‐containing epoxy resins from renewable resources

Novel biobased epoxy resins were prepared from two fatty acid derivatives; epoxidized 10‐undecenoyl triglyceride and epoxidized methyl 3,4,5‐tris(10‐undecenoyloxy)benzoate, with 4,4′‐diaminodiphenylmethane as a crosslinking agent. The flame retardancy of these epoxy resins was improved by the addition of 10‐[2′, 5′‐bis(9‐oxiranyl‐nonayloxy)phenyl]‐9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide and by crosslinking with a phosphorus‐containing curing agent, bis(m‐aminophenyl)methylphosphine oxide. The thermal, thermomechanical, and flame‐retardant properties of the cured materials were measured with differential scanning calorimetry, thermogravimetric analysis, dynamic mechanical analysis, and the limiting oxygen index. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6717–6727, 2006     

运筹学中若干离散规划问题的相对差分搜索解法

运筹学中有很多离散规划问题。其中的线性规划通常用分枝定界法或割平面法，还有图上作业法求解。不论哪种方法工作量都不小，而且效率低；至于非线性规划大都是用动态规划法求解，也很麻烦、耗时。对于大规模问题，不论线性或非线性离散规划，现有解法都受到问题规模的限制；还有资源分配和背包问题至今没有见到解决方法。本文就是为了解决这些问题，提出了相对差分搜索算法。通过5个算例和其它文献中的一些算例计算验证了本法简单、快速、有效和精确，尤其不受问题规模的限制是其最大的优点。     

改性SST固化剂在高等级公路工程中的应用研究

介绍了国内外高等级公路工程中应用ＳＳＴ固化剂施工的基本情况，着重介绍自行开发的改性ＳＳＴ固化剂的改性技术、机理分析、工艺要领与工程质量数据，并作出了技术经济评估。     

GRASP and path relinking for project scheduling under partially renewable resources

Recently, in the field of project scheduling problems the concept of partially renewable resources has been introduced. Theoretically, it is a generalization of both renewable and non-renewable resources. From an applied point of view, partially renewable resources allow us to model a large variety of situations that do not fit into classical models, but can be found in real problems in timetabling and labor scheduling. In this paper, we develop some preprocessing techniques and several heuristic algorithms for the problem. Preprocessing significantly reduces the dimension of the problems, therefore improving the efficiency of solution procedures. Heuristic algorithms based on GRASP and Path relinking are then developed and tested on existing test instances, obtaining excellent results.     

Water resources planning based on complex system dynamics: A case study of Tianjin city

A complex system dynamic (SD) model focusing on water resources, termed as TianjinSD, is developed for the integrated and scientific management of the water resources of Tianjin, which contains information feedback that governs interactions in the system and is capable of synthesizing component-level knowledge into system behavior simulation at an integrated level, thus presenting reasonable predictive results for policy-making on water resources allocation and management. As for the Tianjin city, interactions among 96 components for 12 years are explored and four planning alternatives are chosen, one of which is based on the conventional mode assuming that the existing pattern of human activities will be prevailed, while the others are alternative planning designs based on the interaction of local authorities and planning researchers. Optimal mode is therefore obtained according to different scenarios when compared the simulation results for evaluation of different decisions and dynamic consequences.     

Analysis of the managing conditions of a linear-collector network of a solar power plant

Summary A model has been solved to evaluate the influence of different control options on the performances of a linear-collector solar power plant. The results represent a basis for the choice between the different options. This work has been performed in the framework of activities of the „Progetto Finalizzato Energetica” supported by the C.N.R.     

阿勒泰地区水资源开发利用中的环境问题研究

阿勒泰地区水土资源丰富，但水资源开发利用程度很低，本文针对因水资源利用无统筹规划和灌溉不善引起大面积土壤次生盐渍化、沼泽化及乌伦古湖缩小、水质咸化、湖周土地沙化等环境问题进行了阐述和分析，并为进一步合理开发利用阿勒泰地区的水资源，北水南调，引额济克工程提出了几点建议。