钢筋锈胀引发混凝土保护层开裂破坏的细观数值研究

钢筋锈蚀膨胀引起保护层混凝土开裂是影响钢筋混凝土结构耐久性和服役寿命的重要因素。考虑到混凝土细观结构组成对保护层破坏模式的影响,从细观角度出发,将混凝土看作由骨料、砂浆基质及两者间界面过渡区组成的三相复合材料,建立了描述钢筋锈胀力学行为的混凝土随机骨料模型。采用塑性损伤本构关系模型来表征砂浆基质和过渡区界面的力学行为,假定钢筋均匀锈蚀,对钢筋锈胀引起的混凝土保护层开裂破坏过程进行了细观数值研究。对比了宏观均匀模型与细观非均质模型下获得的保护层破坏模式,探讨了径厚比(c/d)、钢筋位置(中部和角区)及混凝土拉伸强度对保护层破坏模式及保护层胀裂时钢筋锈蚀水平的影响,得到了一些有益结论。     

Infrared Analysis of Elastomeric Composites under Uniaxial Extension

The orientational ordering taking place upon deforming uniaxially elastomeric networks is detected and quantified by infrared dichroism. The type of information gained from orientational measurements is discussed in the case of pure networks and also in rubber composites. This information, compared to that obtained from mechanical measurements, provided a better understanding of the molecular processes involved in rubber reinforcement.     

Application of the finite-element method to improve the quasi-exact reinforcement theory of fibrous polymeric composites

In the paper, the WL quasi-exact reinforcement theory of fibrous polymeric composites is improved. An optimum compatibility condition related to the transverse shear problem for a unit cell, which brings solutions closest to reality, is derived. This condition is formulated in the form of a linear combination of maximum radial and circumferential displacements. Optimum coefficients of this combination are determined by comparing analytical and numerical solutions for a test specimen in the form of a rectangular thin plate, which is in a plane strain state and is subject to selected loading schemes. The analytic solutions are obtained for a homogenized material by using the WL reinforcement theory. The numerical solutions are found for an actual heterogeneous composite material by using the finite-element method, and they verify the WL reinforcement theory, in particular, the admissibility of Hills assumption. An analysis performed for two composite materials shows that the improved WL reinforcement theory gives adequate displacement fields.Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 41, No. 1, pp. 79–92, January–Febrauary, 2005.     

宁波城区多层砖房搞抗震鉴定与加固

经过对宁波城区现有的多层砖房详细的调查与研究，进行了抗震能力的鉴定和地震震害的预测，并提出了抗震加固的措施。     

Laser irradiation of AISI 316L stainless steel coated with Si3N4 and Ti

AISI 316L stainless steel was laser surface treated with different compositions of Si₃N₄ and Ti under various laser-processing parameters to improve its surface hardness through reinforcement of Ti-based silicides. The laser-treated regions exhibited improved surface hardness (250–1000 HV), variations in the surface morphology (smooth and bowl like) and presence of cracks and pores depending upon the Si₃N₄–Ti composition and laser-processing parameters. The study shows that when the Si₃N₄–Ti composition is 75–25 wt% and laser parameters are 1.5 kW laser power and 1.0 m min⁻¹ scan speed, a laser-treated region with high hardness of about 800 HV and smooth surface morphology as well as free from pores and cracks is observed. The X-ray diffractometer (XRD) and Energy-Dispersive Spectroscopy (EDS) analyses show that the laser surface-treated region has reinforced phase of Ti₅Si₃ and retained austenitic structure. The reinforced phase gives rise to very high hardness (or wear resistance) and also a corrosion resistance.     

Reinforcing Poly(ethylene) with Cellulose Nanocrystals

The fabrication of nanocomposites of low‐density polyethylene (LDPE), one of the world's most widely used polymers, and cellulose nanocrystals (CNCs), which represent the world's most abundant bio‐based nanofiller, is reported. While the hydrophobic polymer and the hydrophilic filler seem to be intrinsically incompatible, this article shows that it is possible to kinetically trap homogeneous nanocomposites by a templating approach. An organogel is first prepared by exchanging the solvent of an aqueous CNC dispersion against acetone, impregnating the resulting organogel, in which the CNCs form a percolating network with a hot LDPE solution in toluene, and compression‐molding the resulting materials into thin films. At a filler content of 7.6% v/v, the resulting materials display a three‐ to four‐fold increase in strength and stiffness compared with the neat LDPE, which confirms that the CNC network could be largely maintained. It is also possible to reprocess these nanocomposites and dilute them with LDPE using conventional melt‐processing techniques.

     

Properties of Thermoplastic Starch/Kenaf Composite

This paper reports on the physical and mechanical properties of the thermoplastic sago starch/kenaf fibre (TPSS/KF) composite. The composite was prepared through a compression molding technique at varying fibre contents of 0, 10, 20 and 30 wt.%, whilst the effect of the fibres incorporation was evaluated by physical and mechanical tests, as well as morphological analysis. Reduction of moisture content and denser composite were achieved with a higher fibre content. Meanwhile, the water absorption of the composite was lower than the thermoplastic with an increase in the kenaf fibre loading. Tensile testing improved strength and modulus with the increase of fibres content until an optimum was reached at 30 wt.% of fiber loading. Morphological analysis showed good wetting between the polymer matrix and fibres that provided the tensile improvement.     

Characterization of in situ synthesized TiB2 reinforcements in iron-based composite coating

TiB₂ reinforced iron-based composite coatings can be fabricated on the mild steel substrate with a powder mixture of Ti and B₄C by plasma transferred arc (PTA) powder surfacing process. Characterizations of the TiB₂ reinforcements in the coated surface were investigated in this paper. The experimental work enables the following findings to be obtained: (i) acicular shaped and blocky formed TiB₂ phases could be synthesized in situ using PTA powder surfacing process in the iron-based composite coating. (ii) Gradient distributions of TiB₂ reinforcements appeared in the composite coating from both the vertical and horizontal direction of the coating's cross-section. Significant changes of the size, shape and volume fraction for TiB₂ particles appeared in different regions of the surface coating, due to the effects of the dilution rate and mass density. (iii) Values of coating dilution could have profound impacts on the characterization of TiB₂ reinforcements in the coated surfaces. With the increase of coating dilution, TiB₂ grain tends to be acicular shaped at the edge of the surface coating, while it remains to be granular formed in the center of the composite coating.     

A generalized Pólya's urn with graph based interactions

Given a finite connected graph G, place a bin at each vertex. Two bins are called a pair if they share an edge of G. At discrete times, a ball is added to each pair of bins. In a pair of bins, one of the bins gets the ball with probability proportional to its current number of balls raised by some fixed power . We characterize the limiting behavior of the proportion of balls in the bins. The proof uses a dynamical approach to relate the proportion of balls to a vector field. Our main result is that the limit set of the proportion of balls is contained in the equilibria set of the vector field. We also prove that if then there is a single point with non‐zero entries such that the proportion converges to v almost surely. A special case is when G is regular and . We show e.g. that if G is non‐bipartite then the proportion of balls in the bins converges to the uniform measure almost surely.Copyright © 2013 Wiley Periodicals, Inc. Random Struct. Alg., 46,614–634, 2015     

弹性体拉伸取向和应变诱导结晶研究进展

橡胶拉伸取向和应变诱导结晶被公认为是天然橡胶和一些合成橡胶(如氯丁橡胶、丁基橡胶、氢化丁腈橡胶等)高效自增强的关键所在,研究该现象和行为规律对理解橡胶增强机理具有十分重要的意义.本文总结了常用于研究橡胶拉伸取向和应变诱导结晶的表征方法,对其原理、特点和适用范围进行了对比分析;综述了纳米填料(炭黑,二氧化硅,黏土,碳纳米...