添加金属氧化物的V2O5/AC在烟气脱SO2及脱SO2后H2再生制备硫磺的活性研究

干法脱除烟气SO2的多种催化剂均可在H2气氛中再生,直接制备硫磺。该过程的实现不仅要求再生尾气循环,而且要求催化剂具有双重功能,即在脱硫过程中催化氧化SO2为H2SO4以及在再生过程中将催化还原释放出的SO2进一步转化为硫磺。添加有金属氧化物的V2O5/AC催化剂具备双重功能。着重考察了添加Ce、W、Fe、Co 等氧化物的V2O5/AC催化剂烟气SO2脱除能力及脱除SO2后经H2再生制备硫磺的能力,并对添加Co的催化剂进行了优化。结果表明,在这类催化剂中,对烟气脱SO2起主要催化氧化作用的是V2O5,对H2再生硫磺制备起作用的是添加的金属氧化物。除Ce2O3外,WO3、Fe2O3和CoO都提高了再生中的硫磺收率,CoO的作用最为显著。较合适的催化剂组成是1%V2O5和0.5%CoO。这些金属氧化物在AC上的担载方法,对烟气脱SO2和H2再生结果的影响不明显。硫磺的生成需要CoO向CoS2的转变,再生后催化剂上残余有部分CoS2,且残余硫量还与V2O5量有关。     

一步合成二甲醚催化剂烧结失活和原位再生的研究

采用共沉淀沉积法制备了CuOZnOAl2O3/γ Al2O3 HZSM 5复合催化剂,考察了其对CO加氢直接合成二甲醚的催化性能,研究了催化剂的失活和再生,并用H2-TPR、XRD、TPO、N2O化学吸附等表征方法对反应前后和再生后催化剂的物化性质进行了表征。结果表明,一步合成二甲醚催化剂的失活主要是由于活性位Cu晶粒的烧结长大;反应温度和原料气的组成是影响催化剂失活的因素,在低于220℃下,以N2/H2/CO/CO2为原料气会显著降低催化剂的失活速率。研究使用的氧化还原循环的再生方法能够使Cu晶粒发生再分散,并使失活的催化剂恢复了75%以上的活性。     

Effect of N2O pretreatment on fresh and regenerated Pd-Ag/α-Al2O3 catalysts during selective hydrogenation of acetylene

N₂O pretreatment has shown to result in enhancement of the performance of fresh commercial Pd-Ag/α-Al₂O₃ catalyst during selective acetylene hydrogenation. However, it showed no effect for the used and regenerated catalysts probably due to changes int he metal arrangement on the catalyst surface after regeneration.     

胡萝卜悬浮培养细胞和原生质体的玻璃化法超低温保存

采用玻璃化法成功地超低温保存了胡萝卡悬浮培养细胞及其原生质体，存活率分别为83．3％（TTC法检测）和47％（RDA法检测）。冻后细胞能恢复生长并再生植株。分析了玻璃化法超低温保存植物悬培养浮细胞和原生质体的主要影响因素。     

Sorption-enhanced steam reforming of hydrocarbons with autothermal sorbent regeneration in a moving heat wave of a catalytic combustion reaction

A novel technological concept of sorption-enhanced steam reforming of hydrocarbons is suggested. The peculiarity of the concept is the autothermal regeneration of the carbon dioxide scavenger in the moving super-adiabatic heat wave of an exothermic catalytic combustion reaction performed directly inside the adsorption-catalytic bed. The capability and high efficiency of the proposed technological approach are confirmed by process simulation. The approach proposed is shown to open a way for the creation of an inexpensive, reliable and energy-saving adiabatic packed bed methane processors of unlimited processing capacity.     

液体除湿空调再生性能的实验研究

在对液体除湿和再生机理研究的基础上,建立了太阳能液体除湿空调系统,其中的再生器采用逆流式填料塔,塔体采用不锈钢材质,有效克服了除湿溶液对它们的腐蚀。本实验采用氯化钙作为除湿剂重点研究了再生过程,分析了各种进口参数对再生效果的影响。结果表明:空气流量和含湿量以及除湿溶液的流量和再生温度对再生过程的传热和传质有不同程度的影响。     

All-optical regeneration of DQPSK/QPSK signals based on phase-sensitive amplification

An all-optical regeneration scheme for DQPSK and QPSK signals using phase-sensitive amplifiers (PSAs) is studied and its effectiveness is investigated through numerical simulations. By leveraging the ability of PSAs to provide phase and amplitude regenerative amplification, we show significant simultaneous suppression of both phase and amplitude noises of (D)QPSK signals under optimized conditions. The reduction in the phase noise variance of a noise-corrupted DQPSK signal obtained by one such regenerative amplification can be as large as ∼5.5 folds, showing its good potential for distributed optical regeneration of (D)QPSK signals.     

Multi-function Device Based on Two Terahertz Optical Asymmetric Demutiplexers

A multi-function device based on two terahertz optical asymmetric demultiplexers (TOAD) is proposed,which can be used simultaneously as demultiplexing,data regeneration,clock recovery and wavelength conversion unit. The device can work at an ultra-high speed optical time-division multiplexing (OTDM) system with relatively low speed components.     

基于光纤自相位调制多波长全光再生的色散管理优化

针对基于光纤自相位调制效应的多波长全光再生系统,分析了光纤平均色散对再生器品质因子改进量的影响,提出一种色散管理优化方法.由于波长间色散差异会导致再生系统性能的稳定性下降,通过选择色散补偿光纤和单模光纤的长度,使其合成的色散曲线与各波长分别达到最优再生性能时对应的色散曲线近似拟合,同时保证该色散曲线落在性能满意度高的色散区域,然后调整信号输入功率和滤波器的偏移量,可有效改善多波长再生性能的稳定性,实现再生器的色散管理优化.     

基于光子晶体光纤中的自相位调制的全光再生

利用高非线性光子晶体光纤中的自相位调制效应产生的超连续谱,理论上推导了超窄脉冲信号的再生机制。分别从频域和时域上形象的解释了脉冲再生的原理,该本再生方法可以适用于OTDM的信号再生。实验上对劣化了的脉冲宽度为1.7ps的携带信息的超窄脉冲信号进行了再生,再生之后的信号峰值均衡,消光比达到了15dB。再生前信号中心波长是1548.2nm,重复频率是9.96872GHz。实验中,在1554nm—1570nm和1530nm—1543nm范围内都可以得到10dB以上的再生质量。同时拟合了信号峰值功率和波长关系,得到的曲线和超连续谱曲线相吻合。