Investigations on Pd:SnO2/porous silicon structures for sensing LPG and NO2 gas

P-type porous silicon (PS) structure has been prepared by anodic electrochemical etching process under optimized conditions. Photoluminescence studies of the PS structure show emission at longer wavelengths (red) for the excitation at 365 nm. Scanning electron microscope investigations of the PS surface confirm the formation of uniform porous structure, and the pore diameter have been estimated as 25 μm. Pd:SnO₂/PS/p-Si heterojunction with top gold ohmic contact developed by conventional methods has been used as the sensor device. Sensing properties of the device towards liquefied petroleum gas (LPG) and NO₂ gas have been investigated in an indigenously developed sensor test rig. The response and recovery characteristics of the sensor device at different operating temperatures show short response time for LPG. From the studies, maximum sensitivity and optimum operating temperature of the device towards LPG and NO₂ gas sensing has been estimated as 69% at 180 °C and 52% at 220 °C, respectively. The developed sensor device shows a short response time of 25 and 57 s for sensing LPG and NO₂ gases, respectively. Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006.     

COIL压力恢复系统气流主动冷却技术数值模拟

 引射式压力恢复系统是化学激光系统应用中的一个重要组成部分,为了提高引射器引射效率,减小整个系统尺寸,可以采用主动降低光腔出口气流温度的方法。通过数值模拟,开展了用热交换器降低光腔出口气流温度的研究。给出了混合气体的热物理性质、热交换器建模方法及数值模拟条件,比较了不同条件下热交换器性能的差异,发现由于出口气流密度很低,热交换器的总传热系数、压力损失比常规条件下有较大幅度的减小。此时适当增大椭圆管尺寸,采用高翅片换热管,可以有效地提高热交换器的换热能力。     

统计优化迭代法测量质子交换波导折射率分布

提出了一种用于拟合测量渐变波导的折射率分布的新的理论处理。该方法把统计优化手段导入循环迭代法 ,可适用于费米函数这一类曲线变化范围大、且有多个自变量的函数。实验上用焦磷酸质子交换制备了LiNbO3波导样品 ,用该方法对退火后的折射率分布作了测量拟合 ,折射率拟合值与实验值的均方差为± 8.2× 10 - 4。     

高炉冲渣水余热回收的可行性研究

根据高炉冲渣水的余热特点,提出了一个采用分离式热管换热器的余热回收的方案。文中对余热回收方案中换热设备的结构特点进行了描述。     

相变蓄热体的热工特性数值模拟

为了深入研究蓄热式换热器的蓄放能效果,提出了采用具有相变材料的蓄热体强化蓄放热,通过gambit软件建立了三维蓄热体相变传热过程的物理模型和数学模型,利用fluent软件模拟了具有相变材料的蓄热体与具有变截面管强化的蓄热体传热,得到了两者蓄放热过程温度场分布。根据模拟结果分析了相变材料及缩放结构对蓄热体蓄放热效果的影响,为优化设计蓄热式换热器提供了理论参考。     

水声信号稀疏重构高分辨角度-多普勒成像

针对傅氏空时二维谱估计分辨率低以及声呐空时采样数据样本数不足给角度-多普勒成像带来困难的问题,提出一种水声信号稀疏重构的高分辨角度-多普勒成像方法和抗混响空时滤波器的稀疏重构方法。该方法在声呐阵列单测量向量的极少观测样本条件下,建立阵列信号的空时稀疏表示模型,应用稀疏表示的匹配追踪算法和基追踪算法重构回波与混响的高分辨角度-多普勒像。并根据运动声呐回波与混响的空时分布规律及声呐待检测距离单元位置的先验信息,沿着混响空时分布脊线设计混响稀疏表示的专用空时导向向量字典,通过重构抗混响空时滤波器来抑制角度-多普勒平面的混响干扰。对运动声呐前视和侧视阵列的计算机仿真结果表明,在混响背景中,该方法采用声呐阵列单测量向量重构了低速运动目标多亮点回波的高分辨角度-多普勒像,频率分辨率突破傅里叶分辨率,角度分辨率突破阵列瑞利限,分辨率明显优于傅氏空时谱估计。     

鱼糜漂洗水中可溶蛋白的回收技术

对鱼糜漂洗水中可溶蛋白的综合回收技术情况进行了相关介绍, 主要包括絮凝沉淀法、等电点沉淀法、膜分离法、电阻加热法等, 这些技术的使用不仅实现了蛋白资源的再利用, 而且也减少了对环境的污染.     

脉冲功率晶闸管反向恢复特性

为建立有效的晶闸管模型来仿真晶闸管关断时过电压,减小晶闸管过压损坏的概率,以最大通流150 kA、耐压5.2 kV的脉冲晶闸管为研究对象,将其前置于脉冲形成单元回路中作为大功率开关使用,记录放电过程中晶闸管两端电压及电流。实验数据表明：恢复过程中的电流下降率、反向恢复电荷、反向恢复电流峰值随通态电流峰值的增大而增大,晶闸管关断时间随通态电流峰值的增大而减小。此外,在关断过程中,当电流下降率在-50~1000 A/s时,电流下降率与电流峰值为线性关系。因此,在大脉冲电流条件下,推导反向恢复过程参数与通态电流参数的关系时电流下降率可用与电流峰值的线性关系代替。基于Matlab仿真平台,建立了具有反向恢复过程的脉冲晶闸管模型。该模型仿真得到的晶闸管反向恢复电流峰值与实测结果较为吻合,反向恢复电压尚待进一步修正。     

空调冷凝热热回收技术研究现状及发展趋势

界定了空调冷凝热热回收系统的分类,总结了国内外空调冷凝热热回收技术的研究现状,提出了空调冷凝热热回收技术的发展趋势。     

Cooling overall spin temperature: protein NMR experiments optimized for longitudinal relaxation effects

In experiments performed on protonated proteins at high fields, 80% of the NMR spectrometer time is spent waiting for the ¹H atoms to recover their polarization after recording the free induction decay. Selective excitation of a fraction of the protons in a large molecule has previously been shown to lead to faster longitudinal relaxation for the selected protons [K. Pervushin, B. Vögeli, A. Eletsky, Longitudinal ¹H relaxation optimization in TROSY NMR spectroscopy, J. Am. Chem. Soc. 124 (2002) 12898–12902; P. Schanda, B. Brutscher, Very fast two-dimensional NMR spectroscopy for real-time investigation of dynamic events in proteins on the time scale of seconds, J. Am. Chem. Soc. 127 (2005) 8014–8015; H.S. Attreya, T. Szyperski, G-matrix Fourier transform NMR spectroscopy for complete protein resonance assignment, Proc. Natl. Acad. Sci. USA 101 (2004) 9642–9647]. The pool of non-selected protons acts as a “thermal bath” and spin-diffusion processes (“flip-flop” transitions) channel the excess energy from the excited pool to the non-selected protons in regions of the molecule where other relaxation processes can dissipate the excess energy. We present here a sensitivity enhanced HSQC sequence (COST-HSQC), based on one selective E-BURP pulse, which can be used on protonated ¹⁵N enriched proteins (with or without ¹³C isotopic enrichment). This experiment is compared to a gradient sensitivity enhanced HSQC with a water flip-back pulse (the water flip-back pulse quenches the spin diffusion between ¹H^N and ¹H^α spins). This experiment is shown to have significant advantages in some circumstances. Some observed limitations, namely sample overheating with short recovery delays and complex longitudinal relaxation behaviour are discussed and analysed.