Analysis of multiple mycotoxins in cereals under ambient conditions using direct analysis in real time (DART) ionization coupled to high resolution mass spectrometry

Direct analysis in real time (DART) ionization coupled to an (ultra)high resolution mass spectrometer based on orbitrap technology (orbitrapMS) was used for rapid quantitative analysis of multiple mycotoxins isolated from wheat and maize by modified QuEChERS procedure. After initial evaluation of ionization efficiencies for major groups of mycotoxins achievable with DART technology, sample preparation procedure and instrument parameter settings were optimized to obtain sensitive and accurate determination of most intensively ionizing toxins (deoxynivalenol, nivalenol, zearalenon, actyldeoxynivalenol, deepoxy-deoxynivalenol, fusarenon-X, altenuene, alternariol, alternariolmethylether, diacetoxyscirpenol, sterigmatocystin). The lowest calibration levels (LCLs) estimated for the respective analytes ranged from 50 to 150 μg kg⁻¹. Quantitative analysis was performed either with the use of matrix-matched standards or by employing commercially available ¹³C-labeled internal standards (available for deoxynivalenol, nivalenol and zearalenon). Good recoveries (100-108%) and repeatabilities (RSD 5.4-6.9%) were obtained at spiking level 500 μg kg⁻¹ with isotope dilution technique. Based on matrix-matched calibration, recoveries and repeatabilities were in the range 84-118% and 7.9-12.0% (RSD), respectively. The trueness of data obtained for deoxynivalenol and zearalenon in wheat/maize by DART-orbitrapMS was demonstrated by analysis of certified reference materials (CRMs). Good agreement of these results with data generated by validated ultra-high pressure liquid chromatography-time-of-flight mass spectrometry method was documented.     

变分同化结合广义变分最佳分析对微波散射计资料进行海面风场反演

针对微波散射计资料的海面风场反演,本文首先利用QuikSCAT卫星散射计的近实时资料,借助荷兰皇家气象学会的SeaWinds散射计数据处理模式,在不同风速和海域的情况下,采用多解方案结合二维变分同化方法进行风向的模糊去除,达到消除解的不唯一性的目的,且对4种反演结果（低速风、中速风、高速风和近海岸风）与美国国家海洋和大气管理局卫星资料中心的近实时风场数据的对比分析,说明了该技术的有效性.在此基础上,对反演得到的中速风场利用广义变分最佳分析方法进行了调整,调整后的风场结构有了进一步的改善.此方法可为我国散射计资料反演海面风场的研究提供新的思路和方法. 关键词： 多解方案 二维变分同化 广义变分最佳分析 正则化方法     

温度对微界面摩擦影响的研究

以微观界面摩擦为研究对象,分析了温度变化对材料摩擦性能的影响.基于Towle剪切强度-温度经验公式和晶格热动力学理论,推导出摩擦力与温度之间的理论计算公式.理论分析表明:当界面温度低于材料的德拜温度时,摩擦力随着温度的增加而降低.理论计算结果与原子力显微镜实验结果对比,发现二者趋势一致,表明本文提出的理论和方法可行. 关键词： 界面摩擦 真实接触面积 温度 摩擦力     

实际气体多变功计算模型研究

本文研究了两种实际气体多变功的直接积分数值求解模型,并编制了相应的计算程序.通过与平均过程指数法求得的多变功结果对比发现,直接积分求解模型较平均过程指数法计算得到的多变功具有更高的精度.当压比较高时,平均指数法得到的多变功误差明显增大甚至超过了4%,而直接积分模型计算得到的多变功在高压比下仍具有较高精度.     

范德瓦尔斯方程的分子平均场理论推导

利用气体分子动理论和分子平均场理论,导出了真实气体物态方程--范德瓦尔斯方程,并与统计力学严格的理论推导结果作比较,得到了反映真实气体分子作用域大小的一个较为具体的参考值.     

Semiderivative real filter for microoptical elements quality control

The article presents a proposal for a new method of automatic quality control of microlenses arrays, which is based on a semiderivative real filter. The use of the semiderivative filter for examining pure-phase objects involves modifying the spatial frequency. The basis of the proposed setup is a 4f correlator setup with coherent light. The phase object examined is placed in the input plane of the correlator. Next, the light passes through a filter located in the frequency plane, which gives an intensity signal. In the output plane a charge-coupled device (CCD) camera registers the light intensity, the range of which informs the shape of the phase object. The proposed method is shift invariant, so it allows for examination of single elements or a set of micro-optical elements simultaneously. Additionally, the same setup allows for measuring the phase of objects whose thickness is either considerably smaller or much bigger than 2π.     

Correlation Functions for <Emphasis Type="Italic">β</Emphasis>=1 Ensembles of Matrices of Odd Size

Using the method of Tracy and Widom we rederive the correlation functions for β=1 Hermitian and real asymmetric ensembles of N×N matrices with N odd. This research was supported in part by the National Science Foundation (DMS-0801243).     

FIXED POINTS FOR WEAKLY INWARD MAPPINGS IN BANACH SPACES (Ⅱ)

S. Hu and Y. Sun[1] defined the fixed point index for weakly inward mappings, investigated its properties and studied fixed points for such mappings. In this paper, following S. Hu and Y. Sun, we further investigate boundary conditions, under which the fixed point index for i(A,Ω, p) is equal to nonzero, where i(A,Ω, p) is the completely continuous and weakly inward mapping. Correspondingly, we can obtain many new fixed point the-orems of the completely continuous and weakly inward mapping, which generalize...     

Classification of three-dimensional zeropotent algebras over the real number field

A nonassociative algebra is defined to be zeropotent if the square of any element is zero. In this paper, we give a complete classification of three-dimensional zeropotent algebras over the real number field up to isomorphism. By restricting the result to the subclass of Lie algebras, we can obtain a classification of three-dimensional real Lie algebras, which is in accordance with the Bianchi classification. Moreover, three-dimensional zeropotent algebras over a real closed field are classified in the same manner as those over the real number field.     

Wild theories with o-minimal open core

Let T be a consistent o-minimal theory extending the theory of densely ordered groups and let $T^{\prime }$ be a consistent theory. Then there is a complete theory $T^{?}$ extending T such that T is an open core of $T^{?}$, but every model of $T^{?}$ interprets a model of $T^{\prime }$. If $T^{\prime }$ is NIP, $T^{?}$ can be chosen to be NIP as well. From this we deduce the existence of an NIP expansion of the real field that has no distal expansion.