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961.
962.
Xin Li Dr. Shuo-Qing Zhang Li-Cheng Xu Prof. Dr. Xin Hong 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(32):13355-13361
Radical C−H bond functionalization provides a versatile approach for elaborating heterocyclic compounds. The synthetic design of this transformation relies heavily on the knowledge of regioselectivity, while a quantified and efficient regioselectivity prediction approach is still elusive. Herein, we report the feasibility of using a machine learning model to predict the transition state barrier from the computed properties of isolated reactants. This enables rapid and reliable regioselectivity prediction for radical C−H bond functionalization of heterocycles. The Random Forest model with physical organic features achieved 94.2 % site accuracy and 89.9 % selectivity accuracy in the out-of-sample test set. The prediction performance was further validated by comparing the machine learning results with additional substituents, heteroarene scaffolds and experimental observations. This work revealed that the combination of mechanism-based computational statistics and machine learning model can serve as a useful strategy for selectivity prediction of organic transformations. 相似文献
963.
Yiyi Ou Dr. Weijie Zhou Dr. Zece Zhu Dr. Fengkai Ma Dr. Rongfu Zhou Fang Su Dr. Lirong Zheng Prof. Li Ma Prof. Hongbin Liang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(52):24018-24024
Optical multiplexing based on luminescent materials with tunable color/lifetime has potential applications in information storage and security. However, the available tunable luminescent materials reported so far still suffer from several drawbacks of low efficiency or poor stability, thus restraining their further applications. Herein, we demonstrate a strategy to develop efficient and stable lanthanide coordination polymers (LCPs) with tunable luminescence as a new option for optical multiplexing. Their multicolor emission from green to red and naked-eye-sensitive green emission with tunable lifetime (from ca. 300 to ca. 600 μs) can be controlled by host differential sensitization and energy transfer between lanthanide ions. The quantum efficiencies of developed samples range from around 20 % to 46 % and the luminescence intensity/lifetime appear quite stable in polar solvents up to ten weeks. Furthermore, with the aid of inkjet printing and concepts of luminescence lifetime imaging and time-gated imaging, we illustrate their promising applications of information storage and security in spatial and temporal domains. 相似文献
964.
ABSTRACTWe demonstrate a spatially and electrically tunable random lasing based on polymer-stabilized blue phase liquid crystal (PS-BPLC)-wedged cell. The spatially tunable random lasers can be obtained from the laser dye-doped PS-BPLC-wedged cell through changing the pump positions, where the emission wavelength of the random laser can be tuned due to the thickness gradient of the wedged cell, which affects the scattering mean free path. Additionally, applying different electric fields can also tune the laser emission wavelength. The changing of refractive index due to the Kerr effect leads to a change in the scattering mean free path, resulting in shift of lasing wavelength. This PS-BPLC-wedged cell device has a great potential in applications of speckle-free imaging, document coding, biomedicine and other photonic devices. 相似文献
965.
Kirill T. Kalinin Dr. Nikita G. Sedush Petr V. Dmitryakov Prof. Sergei N. Chvalun 《ChemistryOpen》2020,9(10):1027-1032
The kinetic of D,L-lactide polymerization in presence of biocompatible zirconium acetylacetonate initiator was studied by differential scanning calorimetry in isothermal mode at various temperatures and initiator concentrations. The enthalpy of D,L-lactide polymerization measured directly in DSC cell was found to be ΔH=−17.8±1.4 kJ mol−1. Kinetic curves of D,L-lactide polymerization and propagation rate constants were determined for polymerization with zirconium acetylacetonate at concentrations of 250–1000 ppm and temperature of 160–220 °C. Using model or reversible polymerization the following kinetic and thermodynamic parameters were calculated: activation energy Ea=44.51±5.35 kJ mol−1, preexponential constant lnA=15.47±1.38, entropy of polymerization ΔS=−25.14 J mol−1 K−1. The effect of reaction conditions on the molecular weight of poly(D,L-lactide) was shown. 相似文献
966.
Sandra Mller Stefan Barwe Justus Masa Daniela Wintrich Sabine Seisel Helmut Baltruschat Wolfgang Schuhmann 《Angewandte Chemie (International ed. in English)》2020,59(4):1585-1589
Carbon corrosion at high anodic potentials is a major source of instability, especially in acidic electrolytes and impairs the long‐term functionality of electrodes. In‐depth investigation of carbon corrosion in alkaline environment by means of differential electrochemical mass spectrometry (DEMS) is prevented by the conversion of CO2 into CO32?. We report the adaptation of a DEMS system for online CO2 detection as the product of carbon corrosion in alkaline electrolytes. A new cell design allows for in situ acidification of the electrolyte to release initially dissolved CO32? as CO2 in front of the DEMS membrane and its subsequent detection by mass spectrometry. DEMS studies of a carbon‐supported nickel boride (NixB/C) catalyst and Vulcan XC 72 at high anodic potentials suggest protection of carbon in the presence of highly active oxygen evolution electrocatalysts. Most importantly, carbon corrosion is decreased in alkaline solution. 相似文献
967.
Aziz Ahmadi-khaneghah Alireza Pourali 《International Journal of Polymer Analysis and Characterization》2020,25(6):444-456
Abstract In this work, three epoxy resins including diglycidyl ethers of N,N′-bis(2-hydroxyethyl)pyromellitimide (DIDGE), bisphenol-A (BADGE), and polyethylene glycol (PEDGE) were isothermally cured by an amine curing agent possessing N,N′-disubstituted pyromellitimide units (denoted by DIDAM). DIDGE resin was synthesized from the reaction of N,N′-bis(2-hydroxyethyl)pyromellitimide with an excess of epichlorohydrin. Also, DIDAM curing agent was prepared from the reaction of pyromellitic dianhydride with an excess of ethylene diamine. Completion of the isothermal curing processes was approved by both Fourier transform-infrared spectroscopy and non-isothermal differential scanning calorimetry (DSC). The DSC traces showed only the phase transitions related to the thermal degradation of the resulting thermosets. According to the thermogravimetric analyses, the DIDGE/DIDAM thermoset showed higher thermal stability at temperatures above 425?°C than the other two thermosets. While BADGE/DIDAM and PEDGE/DIDAM thermosets showed about 70% weight loss in the thermal range of 400–850?°C, DIDGE/DIDAM thermoset was encountered with only about 40% weight loss. The glass transition temperatures (Tg ) of the resulting thermosets were determined using tan δ vs temperature plots obtained from dynamic mechanical thermal analysis. The Tg values of BADGE/DIDAM, DIDGE/DIDAM, and PEDGE/DIDAM thermosets were found to be 211?°C, 189?°C, and 81?°C, respectively. 相似文献
968.
运用边界积分法研究了四边简支、两对边固定另两对边简支、四边固定三种复杂边界条件下厚矩形板的受迫振动问题,求解过程清晰,从而给出了受迫振动控制方程和挠曲面方程。通过在Matlab平台上进行数值计算,得出了图表形式的计算结果,并与有限元模拟值进行对照。研究表明,边界积分法用于求解厚矩形板的受迫振动问题的准确性,本文推导的控制方程和挠曲面方程的正确性,进而对工程实际中的各种相关问题具有一定的现实意义,也为求解此类问题提供了一种新途径,可以直接运用到工程实际中。 相似文献
969.
我国计量技术规范《JJF1001—1998通用计量术语及定义》对真值、随机误差和系统误差给予了新的定义,对过去的定义作了原则上的改变.本文对新定义的科学性和合理性进行了讨论,并建议在大学物理实验教学和教材中采用. 相似文献
970.