Toda Chains in the Jacobi Method

We use the Jacobi method to construct various integrable systems, such as the Stäckel systems and Toda chains, related to various root systems. We find canonical transformations that relate integrals of motion for the generalized open Toda chains of types B _n, C _n, and D _n.     

Interpreting Observables in a Quantum World from the Categorial Standpoint

We develop a relativistic perspective on structures of quantum observables, in terms of localization systems of Boolean coordinatizing charts. This perspective implies that the quantum world is comprehended via Boolean reference frames for measurement of observables, pasted together along their overlaps. The scheme is formalized categorically, as an instance of the adjunction concept. The latter is used as a framework for the specification of a categorical equivalence signifying an invariance in the translational code of communication between Boolean localizing contexts and quantum systems. Aspects of the scheme semantics are discussed in relation to logic. The interpretation of coordinatizing localization systems, as structure sheaves, provides the basis for the development of an algebraic differential geometric machinery suited to the quantum regime.     

Partially Classical States of a Boson Field

Employing positive-definiteness arguments we analyse Boson field states, which combine classical and quantum mechanical features (signal and noise), in a constructive manner. Mathematically, they constitute Bauer simplexes within the convex, weak-*-compact state space of the C*-Weyl algebra, defined by a presymplectic test function space (smooth one-Boson wave functions) and are affinely homeomorphic to a state space of a classical field. The regular elements are expressed in terms of weak distributions (probability premeasures) on the dual test function space. The Bauer simplex arising from the bare vacuum is shown to generalize the quantum optical photon field states with positive P-functions.     

关于任意随机变量序列泛函的强极限定理

本文在k是固定的正整数，{fn}是R^k 1上的Borel可测函数列时，得到了任意随机变量序列{Xrn≥0}的泛函{fn(Xn-k,…,Xn)}的强极限定理，它是Chung的关于独立随机变量序列的强大数律的推广，作为推论，得到了k重非齐次马尔科夫链的一类强极限定理．     

Quantum Dynamics of Systems Connected by a Canonical Transformation

Quantum Hamiltonian systems corresponding to classical systems related by a general canonical transformation are considered. The differential equation to find the unitary operator, which corresponds to the canonical transformation and connects quantum states of the original and transformed systems, is obtained. The propagator associated with their wave functions is found by the unitary operator. Quantum systems related by a linear canonical point transformation are analyzed. The results are tested by finding the wave functions of the under-, critical-, and over-damped harmonic oscillator from the wave functions of the harmonic oscillator, free-particle system, and negative harmonic potential system, using the unitary operator to connect them, respectively.     

Variational Formulation of the Schrödinger Field

The variational formulation of the Schrödinger field was investigated and the applicability of the chain method was analyzed. Using Batalin-Fradkin-Tyutin formalism a gauge invariant theory was constructed.     

Lifetime analysis of quasibound states in coupled quantum wells

A simple time-dependent model is presented to investigate lifetimes of the quasibound states in coupled quantum wells (CQWs). The transfer matrix approach is employed to discretize the conduction-band profile of the heterostructure and form a dispersion equation whose zeros correspond to the complex eigenenergies. Both the bound and quasibound states are extracted numerically in the complex plane by Newton's method. The lower and higher well subbands are found to have negative and positive energy shift, respectively, as following the no level crossing theorem. Besides, the decay rate of the quasibound state is approximately proportional to the absolute energy shift. The quasibound states, which have larger energy shift, have shorter lifetime and decay more quickly. Furthermore, the differences in lifetime between the quasibound states in CQWs can be easily realized as all the wave functions are specially adjusted to form the relative probability density distributions.     

Remarks on Mohrhoff's Interpretation of Quantum Mechanics

In a recently proposed interpretation of quantum mechanics, U. Mohrhoff advocates original and thought-provoking views on space and time, the definition of macroscopic objects, and the meaning of probability statements. The interpretation also addresses a number of questions about factual events and the nature of reality. The purpose of this note is to examine several issues raised by Mohrhoff's interpretation, and to assess whether it helps providing solutions to the long-standing problems of quantum mechanics.     

Modeling of the Kinetics of Intramolecular Processes and Transient Spectra with Allowance for Nonradiative Transitions

It has been shown that the kinetics of intramolecular processes and time-resolved spectra with allowance for the quantum beats of the resonant states of isomers or isolated subsystems of levels of one isomeric form can be described with the use of a molecular model interpreting the effect of beats as a nonradiative transition. We have obtained an expression for the nonradiative transition probability, which is directly proportional to the beat frequency and depends oscillatorily on time, thus modeling the effect of beats. The parameter of the molecular system model is the beat frequency directly related to the parameter characterizing the intramolecular interisomeric interactions (the corresponding nondiagonal element of the energy matrix) rather than the value of the nonradiative transition probability. The character of the change in the level populations and, accordingly, in the band intensities in the spectra in the proposed model is in good agreement with the experiment, including the fine structure of the time dependences — oscillations of the line intensities. In analyzing the temporal experiment with a high resolution, it is necessary to take into account the instrument function leading to quantitative and qualitative changes in the time dependences. The traditional model of nonradiative transitions with a constant probability value has a very limited range of applicability — very high beat frequencies compared to the probability of optical transitions.     

Synthesis of β-phenyl-δ,ε-unsaturated amino acids and stereoselective introduction of side chain groups into [4,3,0]-bicyclic β-turn dipeptides

(2S,3S)- and (2R,3R)-2-amino-3-phenyl-5-hexenoic acids have been synthesized in large scale by using Ni(II)-complexes as a template. The amino acids were used in the synthesis of [4,3,0]-bicyclic β-turn mimetics by a convergent methodology. The unique advantage of this strategy is the convenience of introducing side chain groups with predetermined chiralities on both the five- and six-membered heterocyclic rings.