海泡石对膨胀阻燃聚丙烯燃烧和热分解的影响

将改性后的海泡石添加到聚磷酸铵(APP)和双季戊四醇(DPER)膨胀阻燃聚丙烯(PP/IFR)体系中,采用氧指数(LOI)、热重分析(TGA)、光电子能谱(XPS)、傅里叶变换红外(FTIR)光谱、锥形量热仪(CONE)和扫描电镜(SEM)考察其对膨胀阻燃体系的催化协效作用,探讨作用机理.LOI结果表明,改性的海泡石比纳米水滑石和有机改性的蒙脱土有更好的催化协效作用.CONE数据证实,海泡石可以降低膨胀阻燃聚丙烯体系的热释放速率和总的热释放量.通过观察SEM图片发现,海泡石可以改善膨胀炭层的形貌,提高炭层的隔热隔质性能.TGA结果表明,在氮气和空气气氛下,海泡石均可以提高膨胀炭层的热稳定性,增加高温时残余物的量,其主要作用对象为APP.FTIR和XPS测试发现加热过程中海泡石可以与APP发生化学反应,形成P—O—Si键,增加了APP高温时的稳定性.     

不同结构CoPt纳米棒磁学性能

运用电位置换结合化学还原方法制备了两种不同结构的CoPt纳米棒材料,一种为实心结构(CoPt-a),一种为空心结构(CoPt-b).采用透射电镜(TEM)和能量散射光谱(EDS)研究了其形貌和组成.在5和300K下测试了两种纳米棒的磁学性能.结果显示,CoPt-a和CoPt-b纳米棒在5K时的矫顽力分别为6.5和9.3A·m-1,温度升至300K时,两种结构CoPt纳米棒矫顽力均减小为0A·m-1.场冷曲线(FC)和零场冷曲线(ZFC)结果表明两种结构的CoPt纳米棒均表现出超顺磁性,阻塞温度(TB)分别为10.0和9.0K.两种CoPt纳米棒组成、结构等不同可能是引起其矫顽力、磁化强度和阻塞温度差异的主要原因.     

Ge_nEu(n=1-13)团簇的结构、电子及磁性质(英文)

利用密度泛函理论在广义梯度近似下研究了GenEu(n=1-13)团簇的生长模式和磁性.结果表明:对于GenEu(n=1-13)团簇的基态结构而言,没有Eu原子陷入笼中.这和SinEu以及其它过渡金属掺杂半导体团簇的生长模式不同.除GeEu团簇外,GenEu(n=2-13)团簇的磁矩均为7μB.团簇的总磁矩与Eu原子的4f轨道磁矩基本相等.Ge、Eu原子间的电荷转移以及Eu原子的5d、6p和6s间的轨道杂化可以增强Eu原子的局域磁矩,却不能增强团簇总磁矩.     

PdO0,±1, PdH0,±1及PdOH分子结构和电子性质的从头计算

利用多种从头计算方法对PdO0,±1, PdH0,±1以及PdOH的结构和电子性质进行了理论研究. 优化了PdO分子两个能量相近的态(3∏和3∑-), 结果表明PdO 的3∏态较3∑-态更为稳定, 在单双激发耦合簇理论(CCSD)水平下3∑-态的总能量比3∏态的高出0.286 eV. 在结构优化的基础上计算了PdO以及PdH的绝热电离能(AIE)和电子亲和能(AEA), 计算结果与实验值符合得很好. PdOH的基态为Cs对称性的角型结构Pd—OH(2A'态), 另外还优化得到两个2A'态的亚稳结构, 分别对应于Pd—OH和O—Pd—H, CCSD水平下两个亚稳态的总能量较基态分别高0.405和2.284 eV, 优化得到了连接这两个2A'态的过渡态, 并计算了相应的反应能垒.     

Variable selection using penalized empirical likelihood

This paper considers variable selection for moment restriction models.We propose a penalized empirical likelihood(PEL) approach that has desirable asymptotic properties comparable to the penalized likelihood approach,which relies on a correct parametric likelihood specification.In addition to being consistent and having the oracle property,PEL admits inference on parameter without having to estimate its estimator's covariance.An approximate algorithm,along with a consistent BIC-type criterion for selecting ...     

包含$l^{\beta}(0<\beta<1)$渐近等距翻版的有界线性算子空间

Assume X is a normed space,every x ＊ ∈ S（X＊） can reach its norm at some point in B（X）,and Y is a β-normed space.If there is a quotient space of Y which is asymptotically isometric to l β,then L（X,Y） contains an asymptotically isometric copy of l β.Some sufficient conditions are given under which L（X,Y） fails to have the fixed point property for nonexpansive mappings on closed bounded β-convex subsets of L（X,Y）.     

全函数空间和置换空间的一些性质

In this paper, an equivalent relation among the reflexivity, weak sequential completeness and bounded completeness in full function space is given. Some results on weakly sequential compactness of subset and the property （u） in substitution spaces are obtained.     

Curved ray tracing method for one-dimensional radiative transfer in the linear-anisotropic scattering medium with graded index

The curved ray tracing method (CRT) is extended to radiative transfer in the linear-anisotropic scattering medium with graded index from non-scattering medium. In this paper, the CRT is presented to solve one-dimensional radiative transfer in the linear-anisotropic scattering gray medium with a linear refractive index and two black boundaries. The predicted temperature distributions and radiative heat flux at radiative equilibrium are determined by the proposed method, and numerical results are compared with the data in references. The results show that the CRT has a good accuracy for radiative transfer in the linear-anisotropic scattering medium with graded index and the dimensionless emissive power and dimensionless radiative heat flux depend on the dimensionless refractive index gradient. It can also be seen that the dimensionless refractive index gradient has important effects on the temperature discontinuity at the boundaries.     

Intensity and spatial correlation properties of tightly focused partially coherent radially polarized vortex beams

By expanding the Debye theory into the tight focusing of partially coherent field, the intensity and spatial correlation properties of partially coherent radially polarized vortex beams are studied. Expressions are derived for the intensity distribution and the spectral degree of coherence in the focal region. It is found that the intensity and the transverse and longitudinal coherence degrees in the focal region change with the variation of the topological charge and coherence length of the vortex beam. In addition, the degree of coherence is shown to exhibit phase singularities.     

稀土氟化物纳/微米材料的水热合成、形成机理和发光性质

研究了稀土氟化物纳/微米材料的设计合成、形貌控制、形成机制以及发光性质.发展了一种简单、整体、没有模板、环境友好的水热方法合成系列稀土氟化物,即用有机添加剂柠檬酸钠(Na3C6H5O7·2H2O)作为配位剂和形貌控制剂,通过改变氟源(NaF,NH4F或NaBF4)和最初溶液的pH值,得到了具有不同成分、晶体结构、尺寸和...