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31.
Multiple zigzag chains of length n and width m constitute an important class of regular graphene flakes of rectangular shape. The physical and chemical properties of these basic pericondensed benzenoids can be related to their various topological invariants, conveniently encoded as the coefficients of a combinatorial polynomial, usually referred to as the ZZ polynomial of multiple zigzag chains . The current study reports a novel method for determination of these ZZ polynomials based on a hypothesized extension to John–Sachs theorem, used previously to enumerate Kekulé structures of various benzenoid hydrocarbons. We show that the ZZ polynomial of the multiple zigzag chain can be conveniently expressed as a determinant of a Toeplitz (or almost Toeplitz) matrix of size consisting of simple hypergeometric polynomials. The presented analysis can be extended to generalized multiple zigzag chains , i.e., derivatives of with a single attached polyacene chain of length k. All presented formulas are accompanied by formal proofs. The developed theoretical machinery is applied for predicting aromaticity distribution patterns in large and infinite multiple zigzag chains and for computing the distribution of spin densities in biradical states of finite multiple zigzag chains . 相似文献
32.
Anthony J. D'Aristotile 《Journal of Theoretical Probability》1995,8(2):321-346
LetX be the collection ofk-dimensional subspaces of ann-dimensional vector spaceV
n overGF(q). A metric may be defined onX by letting
相似文献
33.
George Stell 《Journal of statistical physics》1995,78(1-2):197-238
Recent experimental investigations of criticality and phase separation in ionic fluids have revealed behavior of great theoretical interest. In seeking to understand the experiments, some of which appear to exhibit argonlike criticality and some of which exhibit classical (mean-field) criticality, a convenient starting point is the restricted primitive model (RPM) of symmetrically charged hard spheres, all of equal diameter , each sphere bearing a positive or negative charge of magnitudeq. There is overall charge neutrality, so that the expected number densities of the anions and cations are equal,
+=
-. Studies of RPM charge-charge and density-density correlation functions indicate that the fluctuation-suppressing mechanism that yields mean-field critical behavior in nonionic systems with long-range interparticle potentials is not operative in the RPM. On the basis of plausible assumptions, Ising-like behavior is instead expected. The above work is summarized. New work of Zhang and the author is outlined, showing that when one loses the RPM symmetry (through, e.g., different valence, diameter, or dipole moment of anions and cations) a strong coupling between charge-charge and density-density correlation ensues. The way in which this can be expected to give rise to mean-field or mean-field-like behavior is noted. Other new observations concern the mean-field analogy found by Høye and the author between the parameter 2/(d–2) (d is the dimensionality) in that model and the monomer number in high polymers, with respect to the coexistence-curve shape dependence on those parameters. 相似文献
34.
35.
André Draux 《Numerical Algorithms》1996,11(1):143-158
From some results concerning the formal orthogonal polynomials, already proved in [5], we develop new properties of generalized adjacent polynomials which correspond to a change in the weight function. A new structure of the singular blocks is given. These results have a direct application to Lanczos methods, theG and -algorithms. 相似文献
36.
Arno B. J. Kuijlaars. 《Mathematics of Computation》1996,65(213):151-156
It is shown that the zeros of the Faber polynomials generated by a regular -star are located on the -star. This proves a recent conjecture of J. Bartolomeo and M. He. The proof uses the connection between zeros of Faber polynomials and Chebyshev quadrature formulas.
37.
We consider the problem of interpolating scattered data in 3 by analmost geometrically smoothGC
2 surface, where almostGC
2 meansGC
2 except in a finite number of points (the vertices), where the surface isGC
1. A local method is proposed, based on employing so-called degenerate triangular Bernstein-Bézier patches. We give an analysis of quintic patches forGC
1 and patches of degree eleven for almostGC
2 interpolation. 相似文献
38.
The principles underlying a novel method intended for analyzing experimental data obtained when studying fluctuation processes are considered. The method in question is Chebyshev’s spectroscopy. The application of this method allows one to determine statistic characteristics of steady-state electrochemical noise against the background of severe deterministic interference without invoking the procedure of the fitting of the initial data. The potentialities of this novel method, which is intended for treating noise experiment, are demonstrated by examining model examples and analyzing the electrochemical noise generated by a lithium electrode placed in an aprotic organic electrolyte. 相似文献
39.
A closed‐form expression has been derived to obtain the N‐dimensional rectangular atomic wave functions. The wave functions can be obtained straightforwardly with the knowledge of the angular momentum quantum numbers and the dimension and there is no need to employ recursive methods as in previous works. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem 88: 263–274, 2002 相似文献
40.
利用Rivlin和Shapiro提出的符号理论,证明了文献[10]中提出的第一类双变量Chebyshev多项式恰为所谓的Steiner区域上具有特殊首项的最小零偏差多项式,并由此导出了几类具有一定代数精度的数值积分公式. 相似文献
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