Association Behavior of 4-Acylpyrazolone Derivative and Tertiary Amine of High Molecular Weight in Antagonistic Synergistic Extraction of Palladium

To find an effective extraction and removal method for palladium(II), which is one of the main fission products from an acidic nuclear spent fuel solution, the extraction behavior of palladium(II) from a nitric acid medium by an acidic chelating extractant, 1-phenyl-3-methyl-4-trifluoroacetylpyrazolone-5-one (HPMTP) and a tertiary amine of high molecular weight, tri-n-octylamine (TOA), has been studied by spectrophotometry. A noticeable antagonistic extraction effect was observed in the extraction system under the given conditions. To understand this phenomenon, a preliminary investigation was performed to explain the mechanism of this reaction. According to the theory of corresponding solutions (TCS), the association reaction between HPMTP and TOA is proposed in the organic phase. An associated species, HPMTP·TOA, formed through hydrogen bonding in a chloroform medium might be the main reason why an antagonistic extraction effect occurred. The association constant between HPMTP and TOA was calculated to be 2.86±0.05.     

Convergence estimates of Galerkin-wavelet solutions to a Cauchy problem for a class of periodic pseudodifferential equations

A class of Cauchy problems for interesting complicated periodic pseudodifferential equations is considered. By the Galerkin-wavelet method and with weak solutions one can find sufficient conditions to establish convergence estimates of weak Galerkin-wavelet solutions to a Cauchy problem for this class of equations.

     

Gravitational Collapse of Self-Similar Perfect Fluid in 2 + 1 Gravity

Perfect fluid with kinematic self-similarity is studied in 2+1 dimensional spacetimes with circular symmetry, and various exact solutions to the Einstein field equations are given. These include all the solutions of dust and stiff perfect fluid with self-similarity of the first kind, and all the solutions of perfect fluid with a linear equation of state and self-similarity of the zeroth and second kinds. It is found that some of these solutions represent gravitational collapse, and the final state of the collapse can be either a black hole or a null singularity. It is also shown that one solution can have two different kinds of kinematic self-similarity.     

Li(AlxCo1-x)O2晶体中Co3+电子态的变化及对结构演化的影响

研究了应用于锂二次电池正极的新型高能量密度存贮材料Li(AlxCo1-x)O2 (x=01—05)的磁性.发现Al3+的掺杂可导致Co3+中d电子自旋态发生变化，即有部分d电子进入高自旋态.伴随Co3+中电子状态的改变，材料结构演化也发生了相应变化，表现为c/a比增大明显减缓，较好地解释了材料结构对Vegard定律的正偏离.这对材料的微观结构与性能设计具有重要意义. 关键词： 锂电池材料 Li（AlxCo1-x）O2 磁性 自旋态 结构演化     

二阶导数光谱-峰面积积分法同时测定芦荟中痕量铁(Ⅱ)和钴(Ⅱ)

在 1,10 -邻菲罗啉显色体系中 ,引入二阶导数光谱 -峰面积积分技术 ,建立了同时测定痕量铁 ( )和钴 ( )的新方法。该法可有效消除共存离子的干扰 ,提高了准确度和灵敏度。对铁和钴的表观摩尔吸光系数分别为 εFe5 .4 5× 10 6 L·mol-1·cm-1,εCo 1.1× 10 4 L· mol-1· cm-1;铁含量在 0 .0— 8.5 μg·m L-1,钴含量在 0 .0— 7.3μg· m L-1范围内遵守比耳定律。可用于芦荟中铁和钴的同时测定 ,结果令人满意     

一个来自振动理论反问题的矩阵方程

§ 1　ＩｎｔｒｏｄｕｃｔｉｏｎＬｅｔＲｎ×ｍｄｅｎｏｔｅｔｈｅｒｅａｌｎ×ｍｍａｔｒｉｘｓｐａｃｅ ,Ｒｎ×ｍｒ ｉｔｓｓｕｂｓｅｔｗｈｏｓｅｅｌｅｍｅｎｔｓｈａｖｅｒａｎｋｒ ,ＯＲｎ×ｎｔｈｅｓｅｔｏｆａｌｌｎ×ｎｏｒｔｈｏｇｏｎａｌｍａｔｒｉｃｅｓ,ＳＲｎ×ｎ(ＳＲｎ×ｎ≥ ,ＳＲｎ×ｎ>)ｔｈｅｓｅｔｏｆａｌｌｎ×ｎｒｅａｌｓｙｍｍｅｔｒｉｃ (ｓｙｍｍｅｔｒｉｃｐｏｓｉｔｉｖｅｓｅｍｉｄｅｆｉｎｉｔｅ ,ｐｏｓｉｔｉｖｅｄｅｆｉｎｉｔｅ)ｍａｔｒｉｃｅｓ.ＴｈｅｎｏｔａｔｉｏｎＡ>0 (≥ 0 ,<0 ,≤ 0 )ｍ…     

New Jacobian Elliptic Function Solutions of Modified KdV Equation: Ⅲ

More recently, sixteen families of Jacobian elliptic function solutions of mKdV equation have been foundby using our extended Jacobian elliptic function expansion method. In this paper, we continue to improve our methodby using another eight pairs of the closed Jacobian elliptic functions. The mKdV equation is chosen to illustrate theimproved method such that another eight families of new Jacobian elliptic function solutions are obtained again. Thenew method can be more powerful to be applied to other nonlinear differential equations.     

Rhythmic pattern formations in gels and Matalon—Packter law: A fresh perspective

The periodic precipitation pattern formation in gelatinous media is interpreted as a moving boundary problem. The time law, spacing law and width law are revisited on the basis of the new scenario. The explicit dependence of the geometric structure on the initial concentrations of the reactants is derived. Matalon—Packter law, which relates the spacing coefficient with the initial concentrations is reformulated removing many ambiguities and impractical parameters. Experimental results are discussed to establish the significance of moving boundary concept in the diffusion controlled pattern forming systems     

Positive set‐operators of low complexity

The powerset operator, ??, is compared with other operators of similar type and logical complexity. Namely we examine positive operators whose defining formula has a canonical form containing at most a string of universal quantifiers. We call them ?‐operators. The question we address in this paper is: How is the class of ?‐operators generated ? It is shown that every positive ?‐operator Γ such that Γ(??) ≠ ??, is finitely generated from ??, the identity operator Id, constant operators and certain trivial ones by composition, ∪ and ∩. This extends results of [3] concerning bounded positive operators.