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141.
In this report we review recent progress in the understanding of the role of chirality in the multi-electron emission. A brief account of the chiral single-electron photoemission is given. In this case the chirality of the experimental set-up is brought about by an initial orientation of the target or/and by specifying a certain projection of the photoelectron spin. The dependence of the photoelectron spectrum on the chirality of the experiment is probed by changing the initial orientation of the target or by inverting the photoelectron spin projection. In a further section we envisage the direct transition of chiral electron pairs from an isotropic bound initial state into a double-continuum state following the absorption of a circularly polarised photon. We work out the necessary conditions under which the spectrum of the correlated photoelectron pair shows a chiral character, i.e. a dependence on the chirality of the exciting photon. The magnitude and the general behaviour of the chiral effects are estimated from simple analytical models and more elaborate numerical methods are presented for a more quantitative predictions. As a further example for the chiral multi-electron emission we study the photoelectron Auger-electron coincidence spectrum. The Auger hole is created by ionising a randomly oriented target by a circular polarised photon. We investigate how the helicity the photon is transferred to the emitted photoelectron pair. The theoretical findings are analysed and interpreted in light of recent experiments. In a final section we focus on the emission of correlated electrons where the initial state is already oriented, e.g. via optical pumping by circularly polarised light. The initial orientation of the atom is transferred to the continuum states following the ionisation of the target by low-energy electrons. We formulate and analyse the theoretical concepts for the transition of the screw sense of the initially bound atomic electron to the continuum electron pair. Numerical methods for the calculations of the cross-sections for the electron-impact ionisation of oriented atoms are presented and their results are contrasted against recent experimental data. 相似文献
142.
Scenarios for Multistage Stochastic Programs 总被引:9,自引:0,他引:9
A major issue in any application of multistage stochastic programming is the representation of the underlying random data process. We discuss the case when enough data paths can be generated according to an accepted parametric or nonparametric stochastic model. No assumptions on convexity with respect to the random parameters are required. We emphasize the notion of representative scenarios (or a representative scenario tree) relative to the problem being modeled. 相似文献
143.
Thiago Manha Gasparini Rosário Elida Suman Bretas Aline Bruna da Silva Rinaldo Gregorio Jr. 《Journal of Polymer Science.Polymer Physics》2012,50(18):1304-1311
Mats of highly oriented poly(vinylidene fluoride) nanofibers were electrospun by means of a conventional electrospinning equipment; the orientation, however, was obtained using a disk collector rotating at a speed of 4000 rpm and a device that reduced the influence of air displacement during nanofiber orientation. Thermal transitions of the mats were determined by differential scanning calorimetry, the predominant crystalline phase by Fourier transform infrared spectroscopy and wide‐angle X‐ray scattering and the nanofiber orientation and morphology by scanning electron microscopy. Relative permittivity, loss index, stable remnant polarization, and coercive field of the mats were also determined and compared with those obtained for a mat electrospun at 2000 rpm and an oriented commercial film. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 000: 000–000, 2012 相似文献
144.
145.
This paper presents a general strategy for designing adaptive space–time finite element discretizations of the nonstationary Navier–Stokes equations. The underlying framework is that of the dual weighted residual method for goal‐oriented a posteriori error estimation and automatic mesh adaptation. In this approach, the error in the approximation of certain quantities of physical interest, such as the drag coefficient, is estimated in terms of local residuals of the computed solution multiplied by sensitivity factors, which are obtained by numerically solving an associated dual problem. In the resulting local error indicators, the effects of spatial and temporal discretization are separated, which allows for the simultaneous adjustment of time step and spatial mesh size. The efficiency of the proposed method for the construction of economical meshes and the quantitative assessment of the error is illustrated by several test examples. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
146.
给出一种可描述预延伸各向异性特性的背应力张量三维表达式,引入大变形弹塑性有限元驱动应力法,结合BPA8 链细观分子网络模型,模拟了预延伸各向异性非晶聚合物材料平面应变拉伸变形局部化力学行为.详细讨论了预延伸比(InitialDrawingRatio;IDR)和预延伸方向(InitialDrawingDirection;IDD)对变形抗力、颈缩规律、剪切带方向以及试件中心部位链延伸比的影响. 相似文献
147.
We studied the optimal quantum control of a molecular rotor in tilted laser fields using the time-sliced Herman–Kluk propagator for the evaluation of the optimal pulse and the light–dipole interaction as the control mechanism. The proposed methodology was used to study the effects of an optimal pulse on the evolution of a wave-packet in a double-well potential and in the effective potential of a molecular rotor in a collinear tilted fields setup. The amplitude and frequency of the control pulse were obtained in such a way that the transition probability between two rotational wave-packets was maximised. 相似文献
148.
Switching about a vertex in a digraph means to reverse the direction of every edge incident with that vertex. Bondy and Mercier introduced the problem of whether a digraph can be reconstructed up to isomorphism from the multiset of isomorphism types of digraphs obtained by switching about each vertex. Since the largest known nonreconstructible oriented graphs have eight vertices, it is natural to ask whether there are any larger nonreconstructible graphs. In this article, we continue the investigation of this question. We find that there are exactly 44 nonreconstructible oriented graphs whose underlying undirected graphs have maximum degree at most 2. We also determine the full set of switching‐stable oriented graphs, which are those graphs for which all switchings return a digraph isomorphic to the original. 相似文献
149.
Ian Y.Y. Bu 《Applied Surface Science》2011,257(14):6107-6111
Highly oriented and large scale p-type ZnO:Al:N films have been successfully synthesized by a simple, solution-based approach. In this approach, p-type doping of zinc oxide was achieved using combination of aqueous ammonia, zinc acetate and aluminium chloride. X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), photoluminescence and Hall measurements indicate that the structure of the ZnO:Al:N films were highly influenced by aqueous ammonia concentration. Excessive aqueous ammonia results in randomly oriented film with excessive precipitation. 相似文献
150.
Formation and Dissolution of Twin ZnO Nanostructures Promoted by Water and Control over Their Emitting Properties 下载免费PDF全文
Dr. Monica Distaso Dr. Mirza Mačković Prof. Erdmann Spiecker Prof. Wolfgang Peukert 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(26):8199-8209
By using ZnO as a model system, the formation of twinned nanostructures has been investigated under microwave irradiation, exploiting experimental conditions ranging from purely solvothermal when N,N‐dimethylformamide was used, to purely hydrothermal when water was the solvent. A progressive increase in size, elongation and roughness of the surface was observed with increasing water content in the solvent mixture. Particular attention was paid to the reactivity of the ZnO surfaces towards dissolution. Our results show that the formation of twinned nanorods is a dynamic process and that the coupling interphase itself is highly reactive. Consequently, the twinned rods undergo a number of complex dissolution processes that are responsible for the appearance of a wide distribution of defects either on the surface or inside the structure. Poly(N‐vinyl pyrrolidone) influences the photoluminescent properties of the as‐synthesised materials and allows control of the ratio of the intensity of the UV and visible emission. 相似文献