全文获取类型
收费全文 | 1507篇 |
免费 | 178篇 |
国内免费 | 165篇 |
专业分类
化学 | 708篇 |
晶体学 | 17篇 |
力学 | 42篇 |
综合类 | 13篇 |
数学 | 524篇 |
物理学 | 546篇 |
出版年
2024年 | 4篇 |
2023年 | 21篇 |
2022年 | 30篇 |
2021年 | 40篇 |
2020年 | 56篇 |
2019年 | 64篇 |
2018年 | 41篇 |
2017年 | 55篇 |
2016年 | 37篇 |
2015年 | 49篇 |
2014年 | 73篇 |
2013年 | 161篇 |
2012年 | 102篇 |
2011年 | 79篇 |
2010年 | 69篇 |
2009年 | 85篇 |
2008年 | 87篇 |
2007年 | 77篇 |
2006年 | 94篇 |
2005年 | 78篇 |
2004年 | 73篇 |
2003年 | 67篇 |
2002年 | 46篇 |
2001年 | 46篇 |
2000年 | 45篇 |
1999年 | 51篇 |
1998年 | 33篇 |
1997年 | 25篇 |
1996年 | 21篇 |
1995年 | 20篇 |
1994年 | 12篇 |
1993年 | 14篇 |
1992年 | 6篇 |
1991年 | 9篇 |
1990年 | 7篇 |
1989年 | 8篇 |
1988年 | 9篇 |
1987年 | 7篇 |
1986年 | 6篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1981年 | 3篇 |
1980年 | 7篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1973年 | 1篇 |
排序方式: 共有1850条查询结果,搜索用时 62 毫秒
71.
Multistrain diseases, which are infected through individual contacts, pose severe public health threat nowadays. In this paper, we build competitive and mutative two‐strain edge‐based compartmental models using probability generation function (PGF) and pair approximation (PA). Both of them are ordinary differential equations. Their basic reproduction numbers and final size formulas are explicitly derived. We show that the formula gives a unique positive final epidemic size when the reproduction number is larger than unity. We further consider competitive and mutative multistrain diseases spreading models and compute their basic reproduction numbers. We perform numerical simulations that show some dynamical properties of the competitive and mutative two‐strain models. 相似文献
72.
73.
Yu Liu 《数学学报(英文版)》2019,35(8):1334-1356
In the previous article “Hearts of twin cotorsion pairs on exact categories. J. Algebra, 394, 245–284 (2013)”, we introduced the notion o 相似文献
74.
We obtain the energy spectrum and all the corresponding eigenfunctions of N-body Bose and Fermi systems with Quadratic Pair Potentials in one dimension. The original first excited state or energy level is disappeared in one dimension, which results from the operation of symmetry or antisymmetry of identical particles. In two and higher dimensions, we give the energy spectrum and the analytical ground state wave functions and the degree of degeneracy. By comparison, we refine Avinash Khare's results by making some items in his article precisely. 相似文献
75.
Formation and dissociation of protonated cytosine–cytosine base pairs in i-motifs by ab initio quantum chemical calculations 下载免费PDF全文
Formation and dissociation mechanisms of C-C+ base pairs in acidic and alkaline environments are investigated, employing ab initio quantum chemical calculations. Our calculations suggest that, in an acidic environment, a cytosine monomer is first protonated and then dimerized with an unprotonated cytosine monomer to form a C-C+ base pair; in an alkaline environment, a protonated cytosine dimer is first unprotonated and then dissociated into two cytosine monomers. In addition, the force for detaching a C-C+ base pair was found to be inversely proportional to the distance between the two cytosine monomers. These results provide a microscopic mechanism to qualitatively explain the experimentally observed reversible formation and dissociation of i-motifs. 相似文献
76.
This work aims at elucidating the mechanism of solvation of a radical ion pair (RIP) in a micro‐heterogeneous binary solvent mixture using magnetically affected reaction yield (MARY) spectroscopy. For the exciplex‐forming 9,10‐dimethylanthracene/N,N‐dimethylaniline system a comparative, composition‐dependent MARY line‐broadening study is undertaken in a heterogeneous (toluene/dimethylsulfoxide) and a quasi‐homogenous (propyl acetate/butyronitrile) solvent mixture. The half‐saturation field extrapolated to zero‐quencher concentration, B1/2, and the self‐exchange rate constants are analyzed in the light of solvent dynamical properties of the mixtures and a dielectric continuum solvation model. The dependence of B1/2 on the solvent composition is explained by cluster formation giving rise to shortened RIP lifetimes. The results are in qualitative agreement with the continuum solvation model suggesting that it could serve as a theoretical basis for quantitative modeling. 相似文献
77.
78.
4-Amino-, chloro-, and bromo-substituted salicylic acid-formaldehyde polymers and their metal chelates were screened for their antifungal activity. Various copolymers prepared from 4-chloro-(bromo)salicylic acid, formaldehyde, and other comonomers were also screened for their antifungal activity. All these polymers, copolymers, and polychelates were found active against several fungi Their fungicidal activities are compared with those of the corresponding monomers and monomeric chelates. 相似文献
79.
Shiliang He Hang Zhao Xiurong Guo Guang Xin Baozhan Huang Limei Ma Xinglong Zhou Rui Zhang Dan Du Xiaohua Wu Zhihua Xing Wen Huang Qianming Chen Yang He 《Tetrahedron》2013
J-AT nucleoside-based organogelators 1a and 1b were designed and synthesized. They were endowed with unparalleled superiority to natural nucleobase analogues 2–6 to gelate aromatic solvents due to their excellent self-assembly properties. The J-AT nucleoside-based organogelators showed a specific self-complementary base pair recognition characteristic. The gel stabilities of 1a and 1b were drastically influenced by adenine analogue 2, hardly affected by thymine analogue 3, uracil analogue 4, cytosine analogue 5, and mildly interrupted by guanine analogue 6. 相似文献
80.
Masashi Daido Yukio Kawashima Masanori Tachikawa 《Journal of computational chemistry》2013,34(28):2403-2411
The structure of Watson–Crick‐type adenine‐thymine and guanine‐cytosine pairs has been studied by hybrid Monte Carlo (HMC) and path integral hybrid Monte Carlo (PIHMC) simulations with the use of semiempirical PM6‐DH+ method in the gas phase. We elucidated the nuclear quantum effect and temperature dependency on the hydrogen‐bonded moiety of base pairs. It was shown that the contribution of nuclear quantum effect on the hydrogen‐bonded structure is significant not only at low temperature 150 K but also at temperature as high as 450 K. The relative position of hydrogen‐bonded proton between two heavy atoms and the nuclear quantum nature of the proton are also shown. Furthermore, we have applied principal component analysis to HMC and PIHMC simulations to analyze the nuclear quantum effect on intermolecular motions. We found that the ratio of Buckle mode (lowest vibrational mode from normal mode analysis) decreases due to the nuclear quantum effect, whereas that of Propeller mode (second lowest vibrational mode) increases. In addition, nonplanar structures of base pairs were found to become stable due to the nuclear quantum effect from two‐dimensional free energy landscape along Buckle and Propeller modes. © 2013 Wiley Periodicals, Inc. 相似文献