Room-Temperature Phosphorescence Invoked Through Norbornyl-Driven Intermolecular Interaction Intensification with Anomalous Reversible Solid-State Photochromism

Herein, norbornyl (NB), a bulky annular nonconjugated spacer, is melded into π systems to construct two groups of ladder-type room-temperature phosphorescence (RTP) luminogens. The effect of the NB on π-π interactions, packing modes and RTP performance is explored systematically. The experimental and computational results demonstrate the versatility of NB in reducing π-π distances and synergistically intensifying the intermolecular interactions, which not only induces intersystem crossing from S₁ to T_n but also diminishes the nonradiative decay of triplet excitons. Impressively, 1800-fold phosphorescence lifetime enhancement is achieved in comparison with the reference compounds without NB. The molecular packing and RTP performance can be further modulated by the length of the backbones and terminal end-groups. It is quite peculiar that NB-annulated phthalic acid exhibits reversible photochromism in the solid state, likely due to the formation of persistent radical pairs. Our study paves an ingenious avenue towards enhancing intermolecular interactions and provides significant implications for a better comprehensive understanding of the origin of their RTP and the inherent photophysical mechanism.     

ANALYSIS OF THE CHAOTIC DYNAMICS OF A HIGH-FLUX CFB RISER USING SOLIDS CONCENTRATION MEASUREMENTS

A high-flux circulating fluidized bed （CFB） riser （0.076-m I.D. and 10-m high） was operated in a wide range of operating conditions to study its chaotic dynamics, using FCC catalyst particles （dp= 67μm, ρp = 1500 kg·m^-3）. Local solids concentration fluctuations measured using a reflective-type fiber optic probe were processed to determine chaotic invariants （Kolmogorov entropy and correlation dimension）, Radial and axial profiles of the chaotic invariants at different operating conditions show that the core region exhibits higher values of the chaotic invariants than the wall region. Both invariants vary strongly with local mean solids concentration. The transition section of the riser exhibits more complex dynamics while the bottom and top sections exhibit a more uniform macroscopic and less-complex microscopic flow structure. Increasing gas velocity leads to more complex and less predictable solids concentration fluctuations, while increasing solids flux generally lowers complexity and increases predictability. Very high solids flux, however, was observed to increase the entropy.     

浊点萃取-石墨炉原子吸收光谱法测定食品包装材料中锑

以吡咯烷二硫代氨基甲酸铵(APDC)为络合剂,在pH5.0乙酸-乙酸钠缓冲溶液中,痕量锑(Ⅲ)与APDC生成络合物,加入表面活性剂TritonX-114用浊点萃取分离富集样品中痕量锑。分取部分表面活性剂相用0.1mol·L-1硝酸甲醇溶液溶解,所得溶液直接用石墨炉原子吸收光谱法进行测定。对影响浊点萃取的因素和共存离子的干扰等进行了试验并予以优化。方法的检出限(3σ/k)为0.37μg.L-1。应用所提出的方法测定了食品包装材料陶瓷样品中锑的含量,并用标准加入法进行方法的回收试验,测得回收率为99.3%。     

断裂表面的分形维数及其测量

本文介绍了作为表征断裂表面特征参数的分形维数的概念及其在非平面表面定量分析与微观断裂机制研究中的应用。具体介绍了测定断裂表面分形维数的各种实验方法,并对各种材料的实验结果和不同的观点进行了综述与讨论。     

Gelfand-Kirillov dimensions of the ℤ2-graded oscillator representations of \mathfrak{s}\mathfrak{l}(n)

We find an exact formula of Gelfand-Kirillov dimensions for the infinite-dimensional explicit irreducible sl(n,F)-modules that appeared in the Z²-graded oscillator generalizations of the classical theorem on harmonic polynomials established by Luo and Xu. Three infinite subfamilies of these modules have the minimal Gelfand-Kirillov dimension. They contain weight modules with unbounded weight multiplicities and completely pointed modules.     

Transformations preserving the Hausdorff-Besicovitch dimension

Continuous transformations preserving the Hausdorff-Besicovitch dimension (“DP-transformations”) of every subset of R ¹ resp. [0, 1] are studied. A class of distribution functions of random variables with independent s-adic digits is analyzed. Necessary and sufficient conditions for dimension preservation under functions which are distribution functions of random variables with independent s-adic digits are found. In particular, it is proven that any strictly increasing absolutely continuous distribution function from the above class is a DP-function. Relations between the entropy of probability distributions, their Hausdorff-Besicovitch dimension and their DP-properties are discussed. Examples are given of singular distribution functions preserving the fractal dimension and of strictly increasing absolutely continuous functions which do not belong to the DP-class.      

λ-重K_(1,4)-设计到λ-重K_(1,3)-最大填充的变形

令(X,B)为一个u阶的λ-重K_(1,4)-设计.对于每一个区组B=(a:b,c,d,e)∈B,若删去边{a,e},则得到一个K_(1,3)[a:b,c,d].令C为删去B中每一个区组的边{a,e}而得到的K_(1,4)的集合,F为被删去的边构成的集合.若F可以被重组成[λv(v-1)/24]个K_(1,3)的集合D,则(X,CUD)为一个v阶λ-重K_(1,3)-最大填充.称(X,C∪D)为λ-重K_(1,4-)设计(X,B)的变形.本文证明了v阶λ-重K_(1,4)-设计到u阶λ-重K_(1,3)-最大填充的变形存在的充要条件是λv(v-1)≡0(mod 8)且v≥5.     

Dimension of the global attractor for damped nonlinear wave equations

An estimate on the Hausdorff dimension of the global attractor for damped nonlinear wave equations, in two cases of nonlinear damping and linear damping, with Dirichlet boundary condition is obtained. The gained Hausdorff dimension is bounded and is independent of the concrete form of nonlinear damping term. In the case of linear damping, the gained Hausdorff dimension remains small for large damping, which conforms to the physical intuition.

     

Gr-凝聚环上分次Wn-模的自反性

引进了分次w