三氧化二铝-聚苯乙烯复合微球的制备

以Al2O3-PS复合材料为原料,采用乳液微封装法制备出掺杂Al2O3的PS空心微球。三相溶液分别是两个水相：蒸馏水（W1相）、5wt%PVA水溶液（W2相）和3wt%Al2O3-PS溶液（O相,苯和三氯甲烷混合物作溶剂）。所得微球表面粗糙度低于50nm。     

含氧空位的氟掺杂二氧化锰助力稳定锌离子电池

将无机盐NH₄F加入到MnO₂的前驱体溶液中,通过高效、简单的一步水热法制备了具有氧缺陷的F掺杂α-MnO₂纳米棒(记为F-MnO₂)。氧空位和F掺杂对提高F-MnO₂的导电性、促进离子扩散、提高倍率性能起着至关重要的作用。另外,由于F掺杂,形成了F—Mn键,这可以有效地抑制放电产物中Mn³⁺的Jahn-Teller畸变,从而提高结构的稳定性。得益于这些协同效应,组装的Zn||F-MnO₂全电池在0.5 A·g^-1下,首圈放电比容量高达274 mAh·g^-1,且具有较长的循环寿命和优异的倍率性能。同时,通过循环伏安(CV)和恒流充放电(GCD)曲线证明了F-MnO₂的储能机制为H⁺和Zn²⁺的共嵌入/脱出过程。     

Synthesis and Properties of Novel Luminescent Compounds Containing Triphenylamine and Bipyridine Units

Blue luminescent compounds T1-T4 containing triphenylamine donors,bipyridine acceptors and olefinic linkers were synthesized and characterized by 1H NMR,13C NMR and high resolution mass spectrometry(HR...     

Shape-Memory Effect in Polymer Composites with a Compactible Filler

The shape-memory effect has been investigated in formed porous polymers and composites under heating. An epoxy polymer, ultrahigh-molecular polyethylene, and polypropylene were used as the polymeric matrix and carbon materials of different bulk density were taken for the filler. An unconventional shape-memory effect, which is accompanied by an increase in volume, was created. Processing schemes by which this effect can be achieved are proposed. They make it possible to obtain products of varying configuration.     

Domain sensitivity for singular elliptic problems: Harmonic transformation approach

A method for computing the sensitivities of functionals depending on the solutions of elliptic equations defined over variable domains is presented. It is based on the material derivative approach and allows the uniform treatment of both singular and nonsingular cases. The novelty consists in defining the vector field connected with the domain transformation as the solution of an auxiliary elliptic equation. Such a choice does not restrict the range of admissible goal functionals and has many advantages from the numerical point of view. It allows one also to consider singular domain variations.     

Maximum norm stability of difference schemes for parabolic equations on overset nonmatching space-time grids

In this paper, theoretical results are described on the maximum norm stability and accuracy of finite difference discretizations of parabolic equations on overset nonmatching space-time grids. We consider parabolic equations containing a linear reaction term on a space-time domain which is decomposed into an overlapping collection of cylindrical subregions of the form , for . Each of the space-time domains are assumed to be independently grided (in parallel) according to the local geometry and space-time regularity of the solution, yielding space-time grids with mesh parameters and . In particular, the different space-time grids need not match on the regions of overlap, and the time steps can differ from one grid to the next. We discretize the parabolic equation on each local grid by employing an explicit or implicit -scheme in time and a finite difference scheme in space satisfying a discrete maximum principle. The local discretizations are coupled together, without the use of Lagrange multipliers, by requiring the boundary values on each space-time grid to match a suitable interpolation of the solution on adjacent grids. The resulting global discretization yields a large system of coupled equations which can be solved by a parallel Schwarz iterative procedure requiring some communication between adjacent subregions. Our analysis employs a contraction mapping argument.

Applications of the results are briefly indicated for reaction-diffusion equations with contractive terms and heterogeneous hyperbolic-parabolic approximations of parabolic equations.

     

New type of biosensor based on magnetic nanoparticle detection

A new type of biosensor has been developed based on detection of nanosized superparamagnetic particles that serve as labels in bioreactions. The method is based on non-linear magnetic material detection by a magnetic field having components at two frequencies f₁ and f₂. The response is measured at the combinatorial frequencies f_i=mf₁+nf₂, where m and n are integers, e.g., f_i=f₁±2f₂. Several highly sensitive readers of superparamagnetic particles have been designed and used for development of various formats of immunoassays, including those compatible with immunoconcentration and magnetic enrichment of antigens.     

Polymer-assisted complexing controlled orientation growth of ZnO nanorods

The growth of the oriented zinc oxide (ZnO) nanorods on silicon substrates based on a simple novel chemical transformation and thermal hydrolysis by using polyvinyl alcohol (PVA) as self-assembling complex polymer was introduced in this paper. All the polymers were removed after chemical oxidation and only the carbonized grid backbones remained that confines the ZnO nanorod’s diameter and enhance the absorption and diffusion of ZnO at the tips of the nanorods during growth. The ZnO nanorods are investigated by FTIR, XRD and FE-SEM. The results indicated that these nanorods have fine hexagonal wurtzite crystal structure and their diameter varies from 20 to 90 nm and the length up to about 1 μm. A polymer-localized ZnO growth model is proposed, which well explains the growth behavior of ZnO nanorods.This revised version was published online in August 2005 with a corrected issue number.     

Transient heat transfer in a spherical protective material, submitted to flux and mixed boundary conditions: an investigation on zirconia

An analytic solution is presented for describing combined radiation and conduction heat transfer in a spherical fiber thermal protection exposed to combined radiative and convective heating. The solution includes the equation of radiative transfer within the material, coupled to a transient energy equation that contains both radiative and convective terms. At elevated temperatures radiative transfer becomes important, and if several hot surfaces view each other, the radiation exchange process must be considered carefully. Some thermal protections are partially transparent to thermal radiation. Hence, an exchange process is complicated by radiation penetrating into and coming out of material. The radiation leaving an area depends on the temperature distribution inside that area and that is unknown and is affected by the exchange process to other areas. The analysis has allowed for unlimited spectral detail but assumes that the various material properties do not vary significantly with temperature. Transient temperature distributions are obtained for the boundary conditions of external radiation and convection. The present analysis includes the influence of reflectivity, surface radiative properties and spectral properties on the temperature distributions.