Synthesis and two-photon optical characterization of D-π-D type Schiff bases

The title compounds, several Schiff bases with D-π-D type have been successfully synthesized from reaction of 4-(N-dialkylamino) benzaldehyde and hydrazine or p-phenylenediamine in ethanol. These compounds were characterized by IR, ¹H NMR, elemental analysis and electronspray mass spectrometry. One-photon fluorescence and two-photon fluorescence properties have been investigated. The two-photon absorption (TPA) cross section (σ) of these compounds was obtained by using the open-aperture Z-scan technique. Based on theoretical calculations and factual test, the influence that a series of substituted groups and the conjugated frame imposed on TPA cross section were systematically discussed.     

Exponential networked synchronization of master-slave chaotic systems with time-varying communication topologies

The networked synchronization problem of a class of master-slave chaotic systems with time-varying communication topologies is investigated in this paper. Based on algebraic graph theory and matrix theory, a simple linear state feedback controller is designed to synchronize the master chaotic system and the slave chaotic systems with a time- varying communication topology connection. The exponential stability of the closed-loop networked synchronization error system is guaranteed by applying Lyapunov stability theory. The derived novel criteria are in the form of linear matrix inequalities (LMIs), which are easy to examine and tremendously reduce the computation burden from the feedback matrices. This paper provides an alternative networked secure communication scheme which can be extended conveniently. An illustrative example is given to demonstrate the effectiveness of the proposed networked synchronization method.     

A new cellular automata model of traffic flow with negative exponential weighted look-ahead potential

With the development of traffic systems, some issues such as traffic jams become more and more serious. Efficient traffic flow theory is needed to guide the overall controlling, organizing and management of traffic systems. On the basis of the cellular automata model and the traffic flow model with look-ahead potential, a new cellular automata traffic flow model with negative exponential weighted look-ahead potential is presented in this paper. By introducing the negative exponential weighting coefficient into the look-ahead potential and endowing the potential of vehicles closer to the driver with a greater coefficient, the modeling process is more suitable for the driver's random decision-making process which is based on the traffic environment that the driver is facing. The fundamental diagrams for different weighting parameters are obtained by using numerical simulations which show that the negative exponential weighting coefficient has an obvious effect on high density traffic flux. The complex high density non-linear traffic behavior is also reproduced by numerical simulations.     

不对称双席夫碱过渡金属配合物的电子光谱和非线性光学性质的 理论研究

本文采用密度泛函理论中的M05方法对比研究了一类双席夫碱及其衍生物与金属Co、Ni和Cu配位后配合物的结构,非线性光学性质以及激发态性质. 结果表明,Co配合物的三重态,Ni配合物的二重态以及Cu配合物的单重态为最佳稳定结构. 通过最佳稳定结构计算得到的配合物非线性光学性质表明,三种金属配合物中Cu配合物表现出较高的一阶和二阶超极化率. 通过对其激发态性质分析表明在配体苯环上引入甲氧基使电子跃迁种类减少,导致超极化率下降,非线性光学性质减弱.     

三粒子纠缠W态隐形传态的正交完备基展开与算符变换

先是对利用单个两粒子及单个三粒子纠缠态作为量子信道实现三粒子纠缠W态的隐形传态方案进行讨论.然后由波函数的叠加原理与算符变换出发,将体系的总量子量按照Bell基展开实现量子隐形传态,给出了变换算符与实际操作算符之间的联系.进一步验证出变换算符可逆是成功实现三粒子纠缠W态隐形传态的必要条件的结论. 关键词： 三粒子纠缠W态 Bell基展开 变换算符 隐形传态     

基于小波包变换和数学形态学结合的光谱去噪方法研究

对反射光谱数据进行去噪是提高光谱信息准确度的前提。传统时域平滑和频域去噪方法存在诸多缺点,本文首次将广义形态滤波方法用于可见近红外光谱的去噪处理,并提出基于小波包变换和数学形态学结合的光谱去噪方法。使用USGS光谱库中的植被光谱进行实验,采用信噪比(SNR)、均方误差根(RMSE)、波形相似度(NCC)和平滑度(SR)四个指标来评估去噪效果。结果表明,小波包最佳基阈值法和广义形态滤波法都能较好地保持波形和平滑度,广义形态滤波法能较好地消除幅值较大的随机噪声,但其对连续随机噪声中幅值较小的噪声成分不能有效消除; 而小波包最佳基阈值法不能有效消除幅值较大的噪声成分; 二者结合的方法组合了这两者的优点,使得幅值较大、较小的噪声成分都能较好地消除,同时还提高了相似度和平滑度指标,充分表明小波包最佳基阈值与广义形态滤波结合的方法是一种更好的可见光近红外光谱去噪方法。     

大功率半导体激光器可靠性研究和失效分析

对自主研发的975 nm波长的COS封装的大功率半导体单管激光器进行了10,12,14 A的电流步进加速应力试验,应用逆幂律模型和指数分布的理论对试验结果进行了分析,计算出在8 A的电流下,器件的平均寿命为28 999 h。研究了器件的失效形式和老化前后的温升、偏振度的变化,结果表明:失效形式主要有体内退化、腔面退化、与焊接有关的退化;老化后的器件的结温上升增多,偏振度下降10%左右。     

Kinetics of protein-release by an aptamer-based DNA nanodevice

A recently introduced DNA nanodevice can be used to selectively bind or release the protein thrombin triggered by DNA effector strands. The release process is not well described by simple first or second order reaction kinetics. Here, fluorescence resonance energy transfer and fluorescence correlation spectroscopy experiments are used to explore the kinetics of the release process in detail. To this end the influence of concentration variations and also of temperature is determined. The relevant kinetic parameters are extracted from these experiments and the kinetic behavior of the system is simulated numerically using a set of rate equations. The hydrodynamic radii of the aptamer device alone and bound to thrombin are determined as well as the dissociation constant for the aptamer device-thrombin complex. The results from the experiments and a numerical simulation support the view that the DNA effector strand first binds to the aptamer device followed by the displacement of the protein.     

Time Series Prediction Based on Chaotic Attractor

A new prediction technique is proposed for chaotic time series. The usefulness of the technique is thatit can kick off some false neighbor points which are not suitable for the local estimation of the dynamics systems. Atime-delayed embedding is used to reconstruct the underlying attractor, and the prediction model is based on the timeevolution of the topological neighboring in the phase space. We use a feedforward neural network to approximate thelocal dominant Lyapunov exponent, and choose the spatial neighbors by the Lyapunov exponent. The model is testedfor the Mackey-Glass equation and the convection amplitude of lorenz systems. The results indicate that this predictiontechnique can improve the prediction of chaotic time series.     

反应堆孔道屏蔽计算的蒙特卡罗方法

建立临界源方向偏倚和指数变换相结合的耦合抽样方法,用于反应堆孔道的屏蔽计算.提出了算例问题的最佳源方向偏倚参数p₁和指数变换参数p₂,得到的耦合抽样方法更能有效降低计算结果的方差.校算了中国核动力院脉冲堆的切向孔道,其中耦合抽样方法的计算结果更接近于实验测量值.