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61.
I. Iovel L. Golomba J. Popelis S. Grinberga S. Belyakov E. Lukevics 《Chemistry of Heterocyclic Compounds》2002,38(10):1210-1229
We have studied condensation of 2-, 3-, 4-pyridinealdehydes and 6-methylpyridine-2-aldehyde with 2-aminopyridine and its 3-, 4-, and 6-methyl derivatives in benzene in the presence of molecular sieves. The reactions occur even at room temperature to form the corresponding pyridyl-pyridyl azomethines, and also aminals. We have determined the optimal conditions for carrying out the processes with the aim of obtaining both types of products. We consider the characteristics of the mass spectra for the synthesized aldimines. We present the X-ray diffraction results for the two aminals. 相似文献
62.
Takeda N Kajiwara T Suzuki H Okazaki R Tokitoh N 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(15):3530-3543
The first stable silylene-isocyanide complexes, [Tbt(Mes)SiCNAr] (5 c: Ar=Tip, 5 d: Ar=Tbt, 5 e: Ar=Mes*; Tbt=2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Mes=mesityl, Tip=2,4,6-triisopropylphenyl, Mes*=2,4,6-tri-tert-butylphenyl) were successfully synthesized by the reaction of a kinetically stabilized disilene, [Tbt(Mes)Si=Si(Mes)Tbt] (1), with bulky isocyanides, ArNC (3c-e). The spectroscopic data of 5 c-e and theoretical calculations for a model molecule indicated that 5 c-e are not classical cumulative compounds but the first stable silylene-Lewis base complexes. The reactions of 5 c-e with triethylsilane and 1,3-dienes gave the corresponding silylene adducts, and they underwent isocyanide-exchange reactions in the presence of another isocyanide at room temperature. These results indicate dissociation of complexes 5 c-e to the corresponding silylene 2 and isocyanides 3 c-e under very mild conditions. The reaction of 5 c with methanol gave the MeOH adduct 16, [Tbt(Mes)SiHC(OMe)NTip], which has a hydrogen atom on the silicon atom. This regioselectivity can be explained in terms of the contribution of zwitterionic resonance structures D and E, which have an anion on the silicon atom. This result indicates that 5 c is not a classical cumulene having Si=C double bonds that should react with methanol to give adducts bearing a methoxyl group on the silicon atom. Although the reactions of 5 c-e with electrophilic reagents such as methanol, hydrogen chloride, and methyl iodide gave the formal silylene adducts, the studies on the reaction mechanism by trapping experiments and the observation of the intermediate suggested that the reaction mainly or partially proceeds by initial nucleophilic attack of the silicon atom, as is the case in the formation of 16 in the reaction of 5 c with methanol. It was revealed that 5 c-e show the nucleophilicity of the silicon atom, most likely resulting from the contribution of the zwitterionic resonance structures D and E. 相似文献
63.
The dimensional analyses of the position and momentum variances‐based quantum mechanical Heisenberg uncertainty measure, as well as the entropic information measures given by the Shannon information entropy sum and the product of Fisher information measures are carried out for two widely used nonrelativistic isotropic exponential‐cosine screened Coulomb potentials generated by multiplying the superpositions of (i) Yukawa‐like, ?Z(e?μr/r), and (ii) Hulthén‐like, ?Zμ(1/(eμr ? 1)), potentials by cos(bμr) followed by addition of the term a/r2, where a and b ≥ 0, μ are the screening parameters and Z, in case of atoms, denotes the nuclear charge. Under the spherical symmetry, all the information measures considered are shown to be independent of the scaling of the set [μ, Z] at a fixed value of μ/Z, a, and b and the other parameters defining the superpositions of the potentials. Numerical results are presented, which support the validity of the scaling properties. © 2007 Wiley Periodicals, Inc. Int J Quantum Chem, 2007 相似文献
64.
Evdoxia Coutouli-Argyropoulou Christos Sideris 《Journal of organometallic chemistry》2006,691(18):3909-3918
Unsymmetrical 1,1′-disubstituted ferrocenes bearing an amino acid moiety and a conjugated electron density controlling substituent were synthesized conveniently starting from 1,1′-ferrocenedicarbaldehyde. The novel ferrocene amino acid derivatives were completely characterized from their MS, 1H NMR and 13C NMR spectra. Their electrochemical behavior was studied by cyclic voltammetry. Their formal redox potentials Ef were slightly influenced by the nature of the amino acid and mainly by the kind of the ethenyl substituent. Furthermore all the (Z)-isomers exhibited a slight anodic shift compared with the corresponding (E)-isomers. 相似文献
65.
Yu. N. Belokon' 《Russian Chemical Bulletin》1992,41(5):868-884
The complexes of glycine, -alanine, and -alanine with (S)-[N-(N-benzylprolyl)amino] benzophenone formed by Ni(II) and Cu(II) ions and Schiff bases enter into different nucleophilic and electrophilic reactions with the formation of diastereoisomeric complexes which decompose into proteinogenic and nonproteinogenic L-amino acids with a high chemical yield and elevated optical purity (70–90%). Optically pure amino acids can be obtained from diastereoisomerically pure complexes after the complexes are separated by recrystallization of the mixture of diastereoisomeric complexes formed. A new type of interphase catalysts of C-alkylation of achiral Schiff bases was proposed. The catalysts are positively charged Ni(II) and Cu(II) complexes of Schiff bases of chiral diamines. In some cases, these complexes have a higher activity and capacity to execute asymmetric alkylation than traditional chiral interphase catalysts based on cinchonidine.Based on materials in the section report by Yu. N. Belokon' to the 7th European Symposium on Organic Chemistry, ESOC-7.A. N. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, 117813 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 5, pp. 1106–1127, May, 1992. 相似文献
66.
N-Nitroso,N-sulfonyl, andN-acyl derivatives ofN-(amidomethyl)- andN-(imidomethyl)-glycine esters have been synthesized by the reactions of these esters with HNO2 or with sulfonylating and acylating reagents.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1299–1305, July, 1995. 相似文献
67.
G. A. Sharpataya K. S. Gavrichev A. V. Khoroshilov V. N. Plakhotnik V. M. Gurevich 《Journal of Thermal Analysis and Calorimetry》2005,81(2):339-346
Summary Cobalt(II), nickel(II) and copper(II) complexes of some aroylhydrazone Schiff’s bases derived from isoniazide (hydrazide of isonicotinic acid) with p-hydroxybenzaldehyde; 2,4-dihydroxybenzaldehyde or 2-hydroxy-1-naphthaldehyde are prepared and characterized. The study reveals that the ligands coordinate in the keto form. That transformed to the enol through the loss of HCl upon heating the solid complexes. The copper(II) complexes are thermochromic in the solid-state while the cobalt(II) complex, 3 of 2,4-dihydroxybenzaldehyde moiety is solvatochromic in hot DMF. The chromisms obtained were discussed in terms of change in the ligand field strength and/or coordination geometry. 相似文献
68.
CHANG Da-Wei 《理论物理通讯》2007,47(6):1143-1144
In this note, we would like to point out that (i) of Corollary 1 given by Zhang et al. (cf Commun. Theor. Phys. 39 (2003) 381) is incorrect in general. 相似文献
69.
Two new families of finite binary sequences are constructed using multiplicative inverse. The sequences are shown to have strong pseudorandom properties by using some estimates of certain exponential sums over finite fields. The constructions can be implemented fast since multiplicative inverse over finite fields can be computed in polynomial time. 相似文献
70.
The transition from the quantum to the classical world is not yet understood. Here, we take a new approach. Central to this is the understanding that measurement and actualization cannot occur except on some specific basis. However, we have no established theory for the emergence of a specific basis. Our framework entails the following: (i) Sets of N entangled quantum variables can mutually actualize one another. (ii) Such actualization must occur in only one of the 2N possible bases. (iii) Mutual actualization progressively breaks symmetry among the 2N bases. (iv) An emerging “amplitude” for any basis can be amplified by further measurements in that basis, and it can decay between measurements. (v) The emergence of any basis is driven by mutual measurements among the N variables and decoherence with the environment. Quantum Zeno interactions among the N variables mediates the mutual measurements. (vi) As the number of variables, N, increases, the number of Quantum Zeno mediated measurements among the N variables increases. We note that decoherence alone does not yield a specific basis. (vii) Quantum ordered, quantum critical, and quantum chaotic peptides that decohere at nanosecond versus femtosecond time scales can be used as test objects. (viii) By varying the number of amino acids, N, and the use of quantum ordered, critical, or chaotic peptides, the ratio of decoherence to Quantum Zeno effects can be tuned. This enables new means to probe the emergence of one among a set of initially entangled bases via weak measurements after preparing the system in a mixed basis condition. (ix) Use of the three stable isotopes of carbon, oxygen, and nitrogen and the five stable isotopes of sulfur allows any ten atoms in the test protein to be discriminably labeled and the basis of emergence for those labeled atoms can be detected by weak measurements. We present an initial mathematical framework for this theory, and we propose experiments. 相似文献