Rapid Sample Pretreatment,Identification and Determination of Active Constitutents in Water‐soluble Radix isatidis Extract via MAE,ESI‐MS and RODWs‐HPLC

In this study, we successfully studied water‐soluble extract from Radix isatidis. Optimized conditions of MAE were listed, the sample can be extracted completely in 10 minutes under microwave power of 400W and solid/liquid ratio of 1:80. Active compounds in water‐soluble extract from R. isatidis were identified with HPLC‐DAD/ESI‐MS, these compounds followed by cytidine, uridine, guanosine, (R,S)‐goitrin and adenosine. RODWs–HPLC as a new sensitive chromatography were also first proposed and investigated, we favoringly used this method for simultaneous determination of these active constitutents in water‐soluble R. isatidis extract. Chromatographic separation was performed on a Diamonsil C18 column (5 μm, 150 mm × 4.6 mm) with a mobile phase gradient consisting of methanol and water at a flow‐rate of 1.0 mL/min, detection wavelengths 240, 250, 260 and 270 nm, the retention times of the tested five compounds were about 4.2, 5.8, 11.1, 14.2 and 20.8 min respectively, the limits of detection were 15, 12, 20, 5.8 and 24 ng/mL for cytidine, uridine, guanosine, (R,S)‐goitrin and adenosine respectively, their linear ranges were between 0.045 and 350 μg/mL with correlation coefficient (R) of 0.9998‐0.9999. The relative standard deviations (RSDs) of intra‐day and inter‐day assays were 0.30‐2.36% and 0.86‐2.54% respectively. Extraction recoveries were 94.25‐106.21%. This novel analytical method was shown to be simple, low‐cost, sensitive and reliable for multiple components in complex or undeveloped materials via MAE, ESI‐MS and RODWs‐HPLC.     

油脂低场核磁(LF-NMR)检测参数的优化试验

适当的低场核磁共振(LF-NMR)检测条件对于保障数据的可靠性具有重要意义.该文研究了大豆油LF-NMR检测过程中仪器参数、样品温度及体积等对检测结果稳定性及重现性的影响.结果表明,将2.5mL油脂样品置于核磁试管中,并在32℃恒温10 min,采样前稳定1min,在TR =2000 ms,τ=200μs,EchoCount=5000个,NS =4次,TD=500050,SW=250 kHz参数条件下采集信号,可保证检测结果稳定可靠.研究结果可为后期应用LF-NMR技术进行油脂品质检测提供适当的检测条件参考.     

低渗透油藏爆炸压裂产能分析及压裂改造区域优化设计

基于爆炸压裂裂缝分布规律,提出爆炸压裂缝网双重介质复合流动产能模型,应用Laplace变换Stehfest数值反演,得到了定压条件下封闭外边界低渗透油藏爆炸压裂生产井产能表达式。在模型正确性验证的基础上结合某低渗透油藏储层特征参数研究了爆炸压裂改造区域参数对封闭边界油藏产量的影响,同时对爆炸压裂改造改造体积优化设计进行了研究。研究结果表明,爆炸压裂改造区域半径主要影响生产中期产能,改造区域渗透率对生产早期和中期影响比较大,且对于实例油藏爆炸压裂改造比为0.1时效果最好。     

多工况多约束下离散变量桁架结构的拓扑优化设计

提出了一个多工况下受应力、位移约束的离散变量桁架结构的拓扑优化方法，给出了结构拓扑形式变更时的约束处理方法及杆件删除策略，使基结构设计空间的维数不断降低，达到最优拓扑，避免了奇异解的出现，在算例中指出了截面离散集和位移约束对最优拓扑的影响；算例给出了满意的拓扑优化解。     

捷联惯导姿态更新的四子样旋转矢量优化算法研究

介绍了捷联惯导姿态更新算法中的旋转矢量算法,分析了锥运动环境下数学平台的算法漂移,提出了通过求解矛盾方程组实现四子样旋转矢量算法优化处理的新方法,并对单子样、双子样、三子样、四子样的算法漂移作了对比计算。     

An Optimal Nonlinear Feedback Control Strategy for Randomly Excited Structural Systems

A strategy for optimal nonlinear feedback control of randomlyexcited structural systems is proposed based on the stochastic averagingmethod for quasi-Hamiltonian systems and the stochastic dynamicprogramming principle. A randomly excited structural system isformulated as a quasi-Hamiltonian system and the control forces aredivided into conservative and dissipative parts. The conservative partsare designed to change the integrability and resonance of the associatedHamiltonian system and the energy distribution among the controlledsystem. After the conservative parts are determined, the system responseis reduced to a controlled diffusion process by using the stochasticaveraging method. The dissipative parts of control forces are thenobtained from solving the stochastic dynamic programming equation. Boththe responses of uncontrolled and controlled structural systems can bepredicted analytically. Numerical results for a controlled andstochastically excited Duffing oscillator and a two-degree-of-freedomsystem with linear springs and linear and nonlinear dampings, show thatthe proposed control strategy is very effective and efficient.     

再制造中零件供应系统整合优化研究

再制造企业里,在决策购买新零件或修复旧零件时,经常面对有限的拆卸修复信息和不确定的订货提前期.为了得到科学的决策,人们试图尽早地掌握拆卸修复零件的确切信息,与有能力的供应商建立良好的关系,或在企业建立管理信息系统来统计分析废旧品的状态和数量等.根据市场需求和产品批发价,以满足市场需求所要购买新零件数和拆卸修复机器数为决策变量,并考虑拆卸修复成功的概率,建立企业期望利润的数学模型,求得可能情况下的最优解或现实满意解.洞察再制造企业取得最大利润的主要影响因数及这些因数间的关系,为制作生产计划提供理论依据.最后指出进一步的研究问题.     

问题变分不等式的一类各向异性Crouzeix-Raviart型有限元逼近

本文研究了Signorini变分不等式问题的一类各向异性Crouzeix-Raviart型非协调有限元逼近。通过一些新的技巧,得到了相应的最优误差估计。     

基于改进轮廓系数法的航空公司客户分群研究

鉴于航空公司在客户聚类分群中对聚类效果进行评价并确定最佳k值的轮廓系数法存在时间复杂度过高O(n2)以及准确率较低问题,文章首先采用对象与同簇或不同簇中心间距离计算来替换同类或异类对象间的距离计算,并通过聚类效果变化率确定轮廓系数调节位置及调节权重,提出一种改进的轮廓系数法;其次,基于预处理且特征选择后真实航空公司客户数据构建聚类模型,借助改进轮廓系数法确定最优客户分群,并构建用户画像;最后,针对不同航空公司分群客户进行特征描述并提出相应个性化服务措施,辅助航空公司为客户提供个性化产品与服务。实证研究结果表明:不同样本量下改进轮廓系数法的精确率和运行效率均有所提升;基于改进轮廓系数法的航空公司客户分群结果符合客观实际,所提服务措施为航空公司最大化客户需求、提高客户满意度提供借鉴。     

半线性Sobolev方程的H~1-Galerkin混合有限元方法

利用H~1-Galerkin混合有限元方法研究了一维半线性Sobolev方程,得到了半离散解的最优阶误差估计,优点是不需验证LBB相容性条件.