全文获取类型
收费全文 | 344篇 |
免费 | 25篇 |
国内免费 | 34篇 |
专业分类
化学 | 244篇 |
力学 | 14篇 |
综合类 | 5篇 |
数学 | 55篇 |
物理学 | 85篇 |
出版年
2023年 | 4篇 |
2022年 | 7篇 |
2021年 | 9篇 |
2020年 | 8篇 |
2019年 | 7篇 |
2018年 | 6篇 |
2017年 | 13篇 |
2016年 | 11篇 |
2015年 | 13篇 |
2014年 | 10篇 |
2013年 | 37篇 |
2012年 | 21篇 |
2011年 | 17篇 |
2010年 | 13篇 |
2009年 | 27篇 |
2008年 | 17篇 |
2007年 | 11篇 |
2006年 | 22篇 |
2005年 | 16篇 |
2004年 | 23篇 |
2003年 | 14篇 |
2002年 | 12篇 |
2001年 | 9篇 |
2000年 | 8篇 |
1999年 | 9篇 |
1998年 | 12篇 |
1997年 | 3篇 |
1996年 | 14篇 |
1995年 | 12篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1986年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有403条查询结果,搜索用时 31 毫秒
81.
Luca Campone Anna Lisa Piccinelli Rita Celano Imma Pagano Rosa Di Sanzo Sonia Carabetta 《Natural product research》2018,32(15):1803-1808
The occurrence of aflatoxin M1 in 69 milk samples collected in a south region of Italy in 2016 was evaluated. The samples were analysed using an automated method based on online SPE coupled with UHPLC tandem mass spectrometry. After a salt induced liquid–liquid extraction with acetonitrile to remove protein from milk, the extract was diluted with water and analysed using an automated online SPE MS/MS method. Among the analysed samples no one had AFM1 higher than the legally allowable limits whereas 71.4% of the other analysed samples were above the LOD of the method. The highest contamination level of AFM1 was found in pasteurised milk (44.39 ng kg?1). The results show the worrying and widespread of AFM1 contamination, highlighting the necessity of monitoring studies in order to evaluate the reduction of the maximum legal limit. 相似文献
82.
In this paper, 4-hydroxy-1-naphthalthiorhodanine (HNTR) was synthesized, and a new method for the simultaneous determination
of palladium, platinum and rhodium ions as metal-HNTR chelates was developed using rapid column high-performance liquid chromatography
combined with on-line enrichment. The palladium, platinum and rhodium ions were pre-column derivatized with HNTR to form colored
chelates. The Pb-HNTR, Pt-HNTR and Rh-HNTR chelates could be absorbed onto the front of the enrichment column when they were
injected into the injector and sent to the enrichment column [ZORBAX Stable Bound, 4.6 × 10 mm, 1.8 μm] with a buffer solution
of 0.05 mol L−1 sodium acetate-acetic acid (pH 4.0) as mobile phase. After enrichment, and by switching the six-ports switching valve, the
retained chelates were back-flushed by mobile phase and traveling towards the analytical column. Separation of these chelates
on the analytical column [ZORBAX Stable Bound, 4.6 × 50 mm, 1.8 μm] was satisfactory with 68% acetonitrile (containing 0.05 mol L−1 of pH 4.0 sodium acetate-acetic acid buffer salt and 0.1% of tritonX-100) as mobile phase. Palladium, platinum and rhodium
were separated completely within 2 min. The detection limits (S/N = 3) of palladium, platinum and rhodium are 1.2 ng L−1, 1.5 ng L−1 and 1.8 ng L−1, respectively. This method was applied to the determination of palladium, platinum and rhodium in water, urine and soil samples
with good results. 相似文献
83.
A. Kemmler H. L. Anderson K. Heldt D. Haberland B. Hinz 《Journal of Thermal Analysis and Calorimetry》1998,52(1):187-194
A computer program was developed for kinetic evaluations of calorimetric experiments to predict the further reaction run under adiabatic conditions. Kinetic modeling is based on elementary reaction steps whose rate laws form a set of differential equations. For the continuous parameter optimization time-temperature data and their derivatives are used. A special calorimeter of the ACTRON series with safety equipment was applied to investigate the kinetics of chemical reactions and to test kinetic on-line evaluations. In the paper, examples for the reaction of n-propanol with o-chlornitrobenzene and for the alcoholysis of phenyl isocyanate are given.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
84.
85.
86.
87.
Olga Kasian Simon Geiger Karl J.J. Mayrhofer Serhiy Cherevko 《Chemical record (New York, N.Y.)》2019,19(10):2130-2142
Electrocatalyst degradation due to dissolution is one of the major challenges in electrochemical energy conversion technologies such as fuel cells and electrolysers. While tendencies towards dissolution can be grasped considering available thermodynamic data, the kinetics of material's stability in real conditions is still difficult to predict and have to be measured experimentally, ideally in‐situ and/or on‐line. On‐line inductively coupled plasma mass spectrometry (ICP‐MS) is a technique developed recently to address exactly this issue. It allows time‐ and potential‐resolved analysis of dissolution products in the electrolyte during the reaction under dynamic conditions. In this work, applications of on‐line ICP‐MS techniques in studies embracing dissolution of catalysts for oxygen reduction (ORR) and evolution (OER) as well as hydrogen oxidation (HOR) and evolution (HER) reactions are reviewed. 相似文献
88.
89.
90.
ACE: Organic(Achieving Chemistry Excellence: Organic Chemistry)是具有智能反馈功能的在线有机化学习题平台。学生利用系统中的画图软件在线完成每个练习题后,平台会判断学生的回答是否正确,即时给出评价与提示,引导学生找到解决问题的思路。对于复杂的机理与合成题,ACE可以接受多种合理的回答。教师可以通过查看平台的统计数据,随时了解学生对知识点的掌握情况。ACE设有论坛,便于教师和学生互动。教学实践证明,ACE的开放有效地提高了学生对有机化学的学习兴趣,培养了学生严谨的科学态度。 相似文献