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71.
72.
建立了同时测定全血、尿液和肝组织等生物样品中18种氨基甲酸酯类农药的在线固相萃取/液相色谱-线性离子阱质谱(On-line SPE/LC-LIT/MS)分析方法。样品经乙腈处理,稀释和离心后直接进样。经Waters OasisHLB在线SPE柱富集纯化,以BETASIL C18柱为分析柱,甲醇-水(均含0.1%甲酸)为流动相进行梯度洗脱;使用电喷雾电离(ESI)正离子模式测定,扫描方式为选择反应监测(SRM)和连续反应监测(CRM)。18种农药在考察的质量浓度范围内线性关系良好(权重因子1/X),相关系数为0.994 3~0.999 4;在全血和尿液中的检出限为0.1~5 ng/m L,在肝组织中的检出限为0.1~5 ng/g;3个加标水平的回收率为90.2%~114.5%,相对标准偏差(n=4)为0.5%~7.5%。该方法简单准确,灵敏度高,能够满足生物样品中18种氨基甲酸酯类农药的快速分析要求。 相似文献
73.
YIN Xue-feng~ 《高等学校化学研究》2001,17(3):264-270
The suitability of 1-nitroso-2-naphthol(NN) as a complexing agent for on-line preconcentration of cobalt eluted on the C_(18) microcolumn by means of the FI-FAAS system was tested. Various parameters affecting the complex formation and its elution were optimized. A 2.3×10~(-3) mol/L reagent solution and the aqueous sample solution acidified with 0.1% (volume fraction) nitric acid were on-line mixed (6.4 mL/min) on a reaction coil set at (65±1)℃ and flowed through the microcolumn for 30 s. The pH of the mixed solution was adjusted to 3—4 with HNO_3(1 mol/L) or NaOH(1 mol/L). The adsorbed complexes in the microcolumn were eluted into the nebulizer of FAAS in 10 s with ethanol acidified with 1% HNO_3(3.0 mL/min). A good precision(1.6% for 100μg/L Co(Ⅱ), n=10), a high enrichment factor 17.2, with detection limit (3σ) 3.2μg/L, and sample throughput (90 h~(-1)) were obtained. The method was applied to the certified reference materials(CRMs), NBS-362 and NBS-364, for the determination of cobalt and the results were in good agreement with the certified values. 相似文献
74.
Shengyun Zhu Jiazheng Zhu Minamisono T. Matsuta K. Yongjun Xu Fukuda M. Mihara M. Zhiqiang Wang Sato K. Akai H. Chaofan Rong Chengjie Chu Jun Chen Hailong Luo 《Hyperfine Interactions》2001,136(3-8):149-153
An on-line time differential perturbed angular correlation technique has been developed with the light probe nucleus 19F. The first on-line TDPAC measurement was carried out to determine the field gradient in Cd and quadrupole moment of 19F (0.197 MeV: I
π = 5/2+, T1/2 = 89 ns).
This revised version was published online in September 2006 with corrections to the Cover Date. 相似文献
75.
褐煤是我国现阶段的主要用煤,但因为其较低的煤化程度,使用时会产生污染环境的二氧化碳和黑灰,而且烟尘中含有的金属离子会危害人体健康,所以开展对褐煤烟尘的研究非常有意义.而激光诱导击穿光谱技术(L IBS)具有快速、多元素同时分析的特点,适合用于煤烟的原位在线探测.实验制备了含铅浓度不同的三种褐煤样本(O,H,L),其中O... 相似文献
76.
T. Sasanuma A. Taniguchi M. Tanigaki Y. Ohkubo Y. Kawase 《Hyperfine Interactions》2004,159(1-4):251-255
The g-factor of the first excited state of 93Sr (E = 213 keV, T
1/2 = 4.6 ns) was measured by an on-line TDPAC technique with use of the strong hyperfine field in Fe metal. The Larmor frequency
ω
L = (2.60 ± 0.15) × 108 rad/s was obtained. The g-factor is derived as g = −0.227 ± 0.013 from g = −ℏω
L/B
hf
μ
N. If the spin of the first excited state of 93Sr is assumed to be 3/2, the g-factor is predicted by a simple core-excitation model as g = −0.22, which is in good agreement with the present experimental result. 相似文献
77.
研制了一种用于同位素分离在线穆斯堡尔谱学的平行板雪崩计数器,计数器仅重40g。用它测量由穆斯堡尔共振吸收后放出的内转换电子,采用85%^119Sn同位素增丰的SnO2作为阴极吸收材料,测得的穆斯堡尔谱的信噪比为11,是一种适合在线穆斯堡尔实验的计数器。对该计数器的性能进行了讨论。A Parallel Plate Avalanche Counter (PPAC) with weighted about 40 g was developed for isotope separator on-line Moessbauer Spectroscopy. It detects the internal conversion electrons emitted from the resonance Moessbauer nuclide. The signal-to-noise ratio of the spectra reaches 11 for 85% enriched ^119SnO2 cathode and absorber. It is an effective detector for on-line Moessbauer experiments. The perform ance of the counter was discussed in detail. 相似文献
78.
A 2.79 COMPETITIVE ON-LINE ALGORITHM FOR TWO PROCESSOR REAL-TIME SYSTEMS WITH UNIFORM VALUE DENSITY 总被引:1,自引:0,他引:1
YANGQIFAN 《高校应用数学学报(英文版)》1997,12(3):333-342
We consider the problem of competitive on-liae scheduling in two processor real-timesystems. In our model all tasks have common value density. Each task has a release time. an exe-cution time and a deadline. The scheduler is given no information about a task until it is released.And the value will be achieved if and only if the task is completed by its deadlirte. Moreover. wesuppose that migratbn is not allowed. The goal of the scheduler is to obtain as much value as pos-sible. In this paper we show that the competitive multipber of Safe-Risky-fixed Algorithm irt [4]is really 3 and presents a modified algorithm (Safe-Risky-unfixed Algorithm) that achieves a com-petitive mukiplier of 2. 79. 相似文献
79.
80.
同型平行机上在线排序问题的近似算法 总被引:1,自引:0,他引:1
本文研究同型平行机上的在线排序问题。通过平移工件的到达时间,提出了一类在线确定型算法SSPT。对目标为总完工时间的情形,证明了该算法竞争比不了于2且不超过(4-1/m),对目标为加工总长的情形,该算法的竞争比的上界为(3-1/m)。 相似文献