Dual mode model for mixed gas permeation of CO2, H2, and N2 through a dry chitosan membrane

Dry chitosan is an excellent candidate for facilitated transport membranes that can be utilized in industrial applications, such as fuel cell operations and other purification processes. This article is the first to report temperature effects on transport properties of CO₂, H₂, and N₂ in a gas mixture typical of such applications. At a feed pressure of 1.5 atm, CO₂ permeabilities increased (0.381–26.1 barrers) at temperatures of 20–150 °C with decreasing CO₂/N₂ (19.7–4.55) and CO₂/H₂ (3.14–1.71) separation factors. The pressure effect on solubilities and permeabilities were fitted to the extended dual mode model and its corresponding mixed gas permeation model. The dual mode and transport parameters, the sorption heats and the activation energies of Henry's and Langmuir's regimes and their pre‐exponential parameters were determined. The Langmuir's capacity constants were utilized to estimate chitosan's glass transition temperature (CO₂: 172 °C, N₂: 175 °C, and H₂: 171 °C). The activation energies of diffusion in the Henry's law and Langmuir regimes were dependent on the collision diameter of the gases. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2620–2631, 2007     

Presentation functions,fixed points,and a theory of scaling function dynamics

Presentation functions provide the time-ordered points of the forward dynamics of a system as successive inverse images. They generally determine objects constructed on trees, regular or otherwise, and immediately determine a functional form of the transfer matrix of these systems. Presentation functions for regular binary trees determine the associated forward dynamics to be that of a period doubling fixed point. They are generally parametrized by the trajectory scaling function of the dynamics in a natural way. The requirement that the forward dynamics be smooth with a critical point determines a complete set of equations whose solution is the scaling function. These equations are compatible with a dynamics in the space of scalings which is conjectured, with numerical and intuitive support, to possess its solution as a unique, globally attracting fixed point. It is argued that such dynamics is to be sought as a program for the solution of chaotic dynamics. In the course of the exposition new information pertaining to universal mode locking is presented.     

Field Analysis of Pillbox Resonator with Radiation Loss Utilizing Finite-Element Beam Propagation Method Formulation

To deal with the radiation from an axially symmetric pillbox resonator embedded in LiNbO₃ substrate, an eigenvalue equation is derived from the expression of the finite-element beam propagation method in a cylindrical coordinate system. By solving the eigenvalue equation iteratively, the field distributions and the angular phase constants of the pillbox resonator are evaluated. The iterative scheme of solving the eigenvalue equation is an extension of our previous direct solution method which was described for a lossless case. The results obtained by this method are compared with those obtained analytically, and excellent agreement is found.     

Hyperidentities of some generalizations of lattices

In the paper we present bases and hyperbases of hyperidentities of some generalizations of the variety L of all lattices and the variety D of distributive lattices. We describe the form of hyperidentities of some varieties with two binary operations. Received January 22, 1997; accepted in final form January 7, 1998.     

The long time and Brownian limits for tagged particle motion in liquids

Formally exact theories of tagged particle motion in liquids are developed, based upon kinetic theory for hard spheres and mode coupling for smooth potentials. It is shown that the resulting equations are tractable in the long time and Brownian limits. The coefficient of the long time tail of the velocity correlation function is seen to differ from its low-density form by only the replacement of the low-density viscosity and diffusion constant by the true viscosity and diffusion constant. In the Brownian limit, the slip Stokes-Einstein law is obtained, with the true viscosity. The relation to other work is discussed.Supported by NSF Grant No. CHE81-11422 and by a Dreyfus Teacher-Scholar grant to TK.     

两自由度非对称三次系统非奇异时的非线性模态及叠加性

本文利用非线性模态子空间的不变性研究两自由度非对称三次系统在非奇异条件下的非线性模态及其模态叠加解有效性，重点考虑这种有效性与模态动力学方程静态分岔之间的关系·大量的数值结果表明，非线性模态解的有效性不仅与其局部性的限制有关，而且与模态动力学方程静态解分岔有关·     

Identifiability of the multinormal and other distributions under competing risks model

Let X₁, X₂ ,…, X_p be p random variables with joint distribution function F(x₁ ,…, x_p). Let Z = min(X₁, X₂ ,…, X_p) and I = i if Z = X_i. In this paper the problem of identifying the distribution function F(x₁ ,…, x_p), given the distribution Z or that of the identified minimum (Z, I), has been considered when F is a multivariate normal distribution. For the case p = 2, the problem is completely solved. If p = 3 and the distribution of (Z, I) is given, we get a partial solution allowing us to identify the independent case. These results seem to be highly nontrivial and depend upon Liouville's result that the (univariate) normal distribution function is a nonelementary function. Some other examples are given including the bivariate exponential distribution of Marshall and Olkin, Gumbel, and the absolutely continuous bivariate exponential extension of Block and Basu.     

Algebraically Decaying Modes in Many Dimensions: Application of Fubini’s Identity to Guided-Wave Optics

We show analytically that application of an identity in conformal invariant field theories to multidimensional guided-wave optics predicts a generic family of modes with algebraic (power-law) tails in the evanescent field.     

纯正半群上的同余扩张(一)

刻划半群上的同余及其扩张是半群的代数理论中的一个非常重要的课题．本文讨论了带上的同余的正规性和不变性以及在其Ｈａｌｌ半群上的扩张，从同余扩张的角度刻划了带上的同余的性质，给出了扩张的极大、极小同余的描述．     

某些四次多项式微分系统的定性研究

本文研究从化学反应动力学中提出的四次微分系统，得出其有限奇点的全局渐近稳定性和极限环的存在性与不存在性，用ＰＢ规范形方法讨论了Ｈｏｐｆ分叉