全文获取类型
收费全文 | 3828篇 |
免费 | 249篇 |
国内免费 | 340篇 |
专业分类
化学 | 1523篇 |
晶体学 | 13篇 |
力学 | 310篇 |
综合类 | 43篇 |
数学 | 1961篇 |
物理学 | 567篇 |
出版年
2023年 | 34篇 |
2022年 | 54篇 |
2021年 | 55篇 |
2020年 | 72篇 |
2019年 | 79篇 |
2018年 | 83篇 |
2017年 | 113篇 |
2016年 | 100篇 |
2015年 | 72篇 |
2014年 | 144篇 |
2013年 | 318篇 |
2012年 | 185篇 |
2011年 | 167篇 |
2010年 | 189篇 |
2009年 | 177篇 |
2008年 | 247篇 |
2007年 | 244篇 |
2006年 | 210篇 |
2005年 | 207篇 |
2004年 | 184篇 |
2003年 | 179篇 |
2002年 | 166篇 |
2001年 | 147篇 |
2000年 | 144篇 |
1999年 | 118篇 |
1998年 | 119篇 |
1997年 | 102篇 |
1996年 | 87篇 |
1995年 | 51篇 |
1994年 | 47篇 |
1993年 | 26篇 |
1992年 | 43篇 |
1991年 | 25篇 |
1990年 | 22篇 |
1989年 | 25篇 |
1988年 | 10篇 |
1987年 | 12篇 |
1986年 | 19篇 |
1985年 | 14篇 |
1984年 | 16篇 |
1983年 | 12篇 |
1982年 | 20篇 |
1981年 | 10篇 |
1980年 | 9篇 |
1979年 | 16篇 |
1978年 | 14篇 |
1976年 | 7篇 |
1975年 | 3篇 |
1973年 | 3篇 |
1936年 | 3篇 |
排序方式: 共有4417条查询结果,搜索用时 15 毫秒
101.
102.
研究了平均非扩张型映射T:‖Tx-Ty‖≤a‖x-y‖+b‖x-Tx‖+c‖x-Ty‖,(x,y∈K,a,b,c≥0,a+b+c≤1)的公共不动点的存在性和唯一性.得到平均非扩张型映射T1和T2满足T1T2=T2T1,则T1T2存在唯一的不动点,并且T1和T2存在唯一的公共不动点.本文结果是近期相关文献结果的推广. 相似文献
103.
A theoretical study of antioxidant activity of some Schiff bases derived from biologically important phenolic aldehydes and phenylenediamines 下载免费PDF全文
Romesh Borgohain Jyotirekha G. Handique Ankur Kanti Guha Sanjay Pratihar 《Journal of Physical Organic Chemistry》2018,31(2)
Because of their numerous biological as well as industrial importance, the study of Schiff bases is an emerging field for the researchers, in recent time. In this study, we have designed some Schiff bases derived from biologically important precursors. The antioxidant activities of the designed compounds are thoroughly studied theoretically using density functional theory taking various parameters like bond dissociation enthalpy, ionization enthalpy, proton dissociation enthalpy, and electron transfer enthalpy followed by the study of effects of solvent, spin density, and molecular orbital on antioxidant activity of the compounds. The comparison of antioxidant activity of the compounds with that of phenol and their parent aldehydes reveals the superior antioxidant activity of the designed compounds. This study contributes towards the information of an important bridge between bioorganic and computational chemistry. 相似文献
104.
Based on the generalized linear quantum transformation theory, we present a normal ordering evolution operator for onedimensional quant urn oscillator with time-dependent frequency and mass, then give the exact expression of the evolution matrix elements, wave function and expectation value of arbitrary observable. 相似文献
105.
V. Rusanov H. Winkler C. Ober A.X. Trautwein 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,12(2):191-198
M?ssbauer studies were performed on single crystals of guanidinium nitroprusside with different orientations of their principal
crystallographic axes (a, b, c) with respect to the incident radiation. The markedly anisotropic Lamb-M?ssbauer factor f
LM
, i.e.
f
LM
(a) = 0.118(8), f
LM
(b) = 0.174(8), f
LM
(c) = 0.202(8) is in contrast to that of nitroprussides with inorganic anions. The observed anisotropy is ascribed to the anisotropic
vibrational mean-square displacement of the nitroprusside anions as a whole which is due to the specific packing of both,
anions and cations, as well as the very weak chemical bonding between the ions, typical only for guanidinium nitroprusside.
The vibrational anisotropy of iron atoms in barium nitroprusside that has been observed by X-ray structural investigations
has a different origin and therefore does not result in an anisotropic Lamb-M?ssbauer factor. We have also investigated metastable
states in guanidinium nitroprusside that have been populated by means of incoherent irradiation from light-emitting diodes.
With a specific orientation of the guanidinium nitroprusside single crystal a population of the metastable states up to 26%
could be achieved. Populations of comparable size on lithium, sodium and potassium nitroprussides have only been reached using
coherent laser irradiation.
Received 15 December 1998 and Received in final form 3 March 1999 相似文献
106.
Ben-Xian Xiao Xin-Yue Gao Dr. Wei Du Prof. Dr. Ying-Chun Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(7):1607-1613
Numerous protocols have been developed for the functionalization of aromatic substances. Among them, the strategy by which aromatic substrates are activated in situ to generate dearomatized intermediates is highly efficient but challenging, especially in the field of asymmetric catalysis. In this Concept article, the application of some well-established chiral Lewis base catalysis, including primary/secondary amines and N-heterocyclic carbenes, that can covalently form catalyst-tethered dearomatized ortho/para-quinodimethane species with diverse heteroaryl and aryl carbonyl substrates is summarized in a number of asymmetric cycloaddition and addition reactions with diverse reagents generally having electrophilic properties. As a result, a variety of enantioenriched aromatic products with higher molecular complexity are constructed effectively through a rearomatization process. 相似文献
107.
Prof. Marcus W. Drover Maeve C. Dufour Lindsay A. Lesperance-Nantau Rayni P. Noriega Dr. Kirill Levin Prof. Robert W. Schurko 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(49):11180-11186
Herein, we establish the preparation, characterization, and reactivity of a new diphosphine ligand, 1,2-bis(di(3-dicyclohexylboraneyl)propylphosphino)ethane (P2BCy4), a scaffold that contains four pendant boranes. An entryway into the coordination chemistry of P2BCy4 is established by using nickel, providing the octaboraneyl complex [Ni(P2BCy4)2]—this species contains a boron-rich secondary coordination sphere that reacts readily with Lewis bases. In the case of 4,4′-bipyridine, an air-sensitive coordination polymer is obtained. Characterization of this material by solid-state NMR and EPR spectroscopy reveals the presence of a charge-transfer polymer, which forms as a function of intramolecular Ni→4,4′-bpy electron transfer (ET), providing an array of oxidized nickel sites and reduced 4,4′-bpy radical anion sites. Notably, the related intermolecular reaction between the model fragments [Ni(dnppe)2] (dnppe=1,2-bis(di-n-propylphosphino)ethane) and a bis(boraneyl)-protected 4,4′-bpy, provides no ET. Overall, the P2BCy4 fragment provides a unique opportunity for Lewis base activation, in one case allowing for the facile construction of monomers for incorporation into redox-active macromolecules. 相似文献
108.
Nikolaos V. Tzouras Dr. Fady Nahra Dr. Laura Falivene Prof. Dr. Luigi Cavallo Marina Saab Prof. Dr. Kristof Van Hecke Dr. Alba Collado Dr. Christopher J. Collett Prof. Dr. Andrew D. Smith Prof. Dr. Catherine S. J. Cazin Prof. Dr. Steven P. Nolan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(20):4515-4519
We have been puzzled by the involvement of weak organic and inorganic bases in the synthesis of metal–N-heterocyclic carbene (NHC) complexes. Such bases are insufficiently strong to permit the presumed required deprotonation of the azolium salt (the carbene precursor) prior to metal binding. Experimental and computational studies provide support for a base-assisted concerted process that does not require free NHC formation. The synthetic protocol was found applicable to a number of transition-metal- and main-group-centered NHC compounds and could become the synthetic route of choice to form M–NHC bonds. 相似文献
109.
Qin Zhu Lu Lin Rulin Qiu Prof. Dr. Jun Zhu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(24):5381-5387
Aromaticity is one of the most basic concepts in organic chemistry. The planar Möbius aromatic metallapentalynes and metallapentalenes have attracted considerable attention in the past few years. However, the aromaticity of metallapentalenes containing heteroatoms (such as B, N, and O), termed as hetero-metallapentalenes, is rarely studied. Herein, the stability and aromaticity of a series of hetero-metallapentalenes are theoretically investigated. The results reveal lower aromaticity in metallaborapentalene, comparable aromaticity in metallazapentalene, and nonaromaticity in metalloxapentalene relative to that of metallapentalene. Moreover, the effect of Lewis bases on the aromaticity and stability of metallaborapentalene is discussed. These results provide useful information for experimental chemists to realize more hetero-metallapentalenes. 相似文献
110.
A class of twisted special Lagrangian submanifolds in T~*R~n and a kind of austere submanifold from conormal bundle of minimal surface of R~3 are constructed. 相似文献