全文获取类型
收费全文 | 272篇 |
免费 | 45篇 |
国内免费 | 20篇 |
专业分类
化学 | 112篇 |
晶体学 | 1篇 |
力学 | 48篇 |
综合类 | 11篇 |
数学 | 68篇 |
物理学 | 97篇 |
出版年
2023年 | 4篇 |
2022年 | 11篇 |
2021年 | 13篇 |
2020年 | 7篇 |
2019年 | 3篇 |
2018年 | 9篇 |
2017年 | 9篇 |
2016年 | 12篇 |
2015年 | 10篇 |
2014年 | 21篇 |
2013年 | 16篇 |
2012年 | 19篇 |
2011年 | 11篇 |
2010年 | 12篇 |
2009年 | 23篇 |
2008年 | 23篇 |
2007年 | 6篇 |
2006年 | 12篇 |
2005年 | 19篇 |
2004年 | 8篇 |
2003年 | 9篇 |
2002年 | 7篇 |
2001年 | 6篇 |
2000年 | 9篇 |
1999年 | 12篇 |
1998年 | 5篇 |
1997年 | 9篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1994年 | 1篇 |
1993年 | 5篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1981年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有337条查询结果,搜索用时 140 毫秒
1.
The Modeling of Velocity Enhancement in Polymer Flooding 总被引:1,自引:0,他引:1
In single-phase polymer flooding experiments it has repeatedly been observed that the average velocity of the polymer molecules is higher than the average velocity of the water molecules. This effect is incorporated in many conventional Enhanced Oil Recovery (EOR) simulators by the introduction of a constant velocity enhancement factor. In this paper we show that, in absence of dispersion, a constant enhancement factor in the mathematical model for two-phase polymer flow (Buckley--Leverett displacement) leads to ill-posedness of the model equations. We propose a saturation dependent enhancement factor, derived from a model based on percolation concepts, for which this problem does not occur. 相似文献
2.
Luca Lambertini Raimondello Orsini 《Central European Journal of Operations Research》2007,15(1):105-117
We reconsider the role of network externalities in a dynamic spatial monopoly where the firm must invest in order to accumulate
capacity, while consumers may have either linear or quadratic preferences. We (1) characterise saddle point equilibria, (2)
prove that the extent of market coverage is increasing in the network effect and (3) unlike the existing static literature
on the same problem, the monopolist may not make introductory price offers. Then, we briefly deal with the socially optimal
solution, showing that, in general, a planner would serve more consumers than a profit-seeking monopolist.
相似文献
3.
Arsenic-tolerant freshwater alga Chlorella vulgaris which had been collected from an arsenicpolluted environment were tested for uptake and excretion of inorganic arsenic. Approximately half the quantity of arsenic taken up by C. vulgaris was estimated to be adhered to the extraneous coat (10 wt %) of the cell. The remainder was bioaccumulated by the cell. Both adhered and accumulated arsenic concentrations increased with an increase in arsenic(V) concentration of the aqueous phase. Arsenic(V) accumulation was affected by the growth phse: arsenic was most actively accumulated when the cell was exposed to arsenic during the early exponential phase and then accumulation decreased with an increase in culture time exposed to arsenic. The alga grew well in the modified Detmer (MD) medium containing 1 mg As(III) dm?3 and the growth curve was approximated by a ‘logistic equation’. Arsenic(III) was accumulated up to the second day of the culture time and arsenic(III) accumulation decreased with an increase in the culture time after that. Arsenic accumulation was also largely affected by various nutrients, especially by managanese, iron and phosphorus compounds. A modified MD medium with the three nutrients was proposed for the purpose of effective removal of arsenic from the aqueous phase. Using radioactive arsenate (Na2H74AsO4), the arsenic accumulated was found to be readily excreted under conditions which were unfavourable for the multiplication of C. vulgaris. 相似文献
4.
Zhi‐Yong Huang Jin‐Can Shen Zhi‐Xia Zhuang Xiao‐Ru Wang Frank S. C. Lee 《应用有机金属化学》2004,18(6):255-261
Cinnabar, as one of the most widely used mineral drugs in traditional Chinese medicines, has been proven to have prominent curative effects in clinical use for more than 2000 years. But the safety and toxicity of the drug has been under constant debate in clinic usage. Metallothionein (MT) contains about 30% of cysteine in the molecule, and plays an important detoxification role against heavy metals. In this study, it was used as a biomarker to assess mercurial accumulation in rats fed orally with cinnabar. After feeding rats with cinnabar by gastric gavage at different dosages and at different times, the distribution of heavy metals (including mercury, copper and zinc) and MT was investigated among rat tissues, including liver, kidney, heart, brain, testis and blood. Metals and MT determinations were carried out using inductively coupled plasma mass spectrometry (ICP‐MS) and a modified mercury saturation assay technique respectively. The results indicated that mercury was easily accumulated in the tissues of rats exposed to cinnabar, especially in kidney. For example: at a feeding dosage of 5 g kg?1 (bw) for 4 weeks, the mercury concentrations in kidney were 13, 8.7, 21.6 and 26 times those in liver, testis, brain and heart respectively; and at 2.5 g kg?1 (bw) for 2 weeks, the mercury concentrations in kidney were 21, 2.1, 3 and 21 times those in liver, testis, brain and heart respectively. In addition, mercury in kidney and liver of all cinnabar groups was significantly higher than that of the control group (P < 0.01). A high positive correlation observed between MT concentrations and mercury levels in both liver and kidney (R2 = 0.9299, P < 0.02 for liver; R2 = 0.9923, P < 0.0008 for kidney) indicated that MT could be used as a biomarker for mercury in tissues. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
5.
WADOOD Y. HAMAD 《Cellulose (London, England)》1997,4(1):51-56
Wood-pulp fibres are recognized as concentrically-layered, laminated composite tubes of structural reinforcing material, the
cellulose microfibrils, embedded in a cementing matrix of hemicellulose and lignin. When the single fibres are subjected to
cyclic mechanical action, their morphological behaviour is characterized by the fatigue growth of micro-voids and surface
damage which individually and collectively give rise to stress concentrations, and eventually crack development. The progressive
damage phenomena, evinced by the surface imaging and optical sectioning techniques through utilizing confocal laser scanning
microscopy, are understood to be consequences of the cumulative material micromechanical degradation and subsequent microstructural
breakdown of the cellulose microfibrillar framework. This structural breakdown is believed to effect the fibrillation and
flexibilization of the fibres
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
6.
The strategy to identify cadmium deactivation mechanism in Arabidopsis thaliana has been developed using selective and sensitive hyphenated techniques. Cadmium concentrations, in main parts of the plant, were determined by ICP-MS and total amount was found as 0.43-0.44 μg g−1 in leaves and 3.3-3.4 μg g−1 in roots. Speciation of the metal complexes in cells was investigated by SEC-ICP-MS in order to estimate the accumulation process. Phytochelatins, desglycyl-phytochelatins and phytochelatins homologues lacking the N-terminal γ-linked glutamic acid were extracted from plant and were identified by RPLC-ESI-MS. Two-dimensional chromatography allowed to link the metal complexes separated by SEC with isoforms of phytochelatins analyzed by high resolution RPLC and confirm their significant responsibility for metal accumulation. The potential of the cadmium complexes speciation indicates that obtained results could be reliable source of knowledge to confirm the information coming from the well-known genomic sequence of Arabidopsis and to estimate the role of γ-glutamyl transpeptidase in metabolism of glutathione. 相似文献
7.
8.
9.
The oxygen permeability of films is relevant for packaging related and technical applications. An increasingly used test method for the measurement of oxygen permeability is the optical test method, because it allows a simple and cost-efficient measurement setup. This method is based on optical chemical sensors. However, not much is known about its validity. Therefore, method validation is necessary which is subject of this study. The optical method is compared with the carrier gas method for a variety of film samples. In the tested permeability range of 0.5–2500 cm3 (STP)·(m2 d bar)−1 both methods deviated less than 20% for zero and 50% relative humidity. 相似文献
10.
Simultaneous hyperaccumulation of arsenic and antimony in Cretan brake fern: Evidence of plant uptake and subcellular distributions 总被引:1,自引:0,他引:1
Arsenic (As) and antimony (Sb) show similar chemical properties and often present together in sulfide ores. Currently, phenomenon of co-contamination of As and Sb at some sites of the world has been increasingly emerged. The present study was conducted to explore the potential of Pteris cretica L. (Cretan brake fern), an arsenic (As) hyperaccumulator, to simultaneously accumulate As and Sb under hydroponic conditions. Arsenic was imposed at medium and high levels of 5 mg L− 1 and 20 mg L− 1, while Sb was imposed either single or co-presence with As at medium and high levels of 10 mg L− 1 and 20 mg L− 1, with no As and Sb addition as the control. The single and interactive effects of As and Sb on their uptake and subcellular distributions were analyzed. Cretan brake fern could accumulate high concentrations of As and Sb, with the highest concentrations of As and Sb been recorded as 1677.2 mg kg− 1 and 1516.5 mg kg− 1 in the fronds, respectively. Arsenic and Sb were found mainly in cytosol, while less in cell wall and cytoplasmic organelles. Sb uptake by Cretan brake fern was enhanced with increasing As levels, which was accompanied with an increase of Sb but a decrease of As in cytosol fractions. Arsenic uptake was slightly enhanced whereas suppressed when Sb was co-present in a medium and high level, respectively; however, in both conditions, As was found to be decreased in cytosol of the above ground parts as fronds and stems of Cretan brake fern. The results demonstrate Cretan brake fern can simultaneously hyperaccumulate As and Sb, thus is valued in phytoremediation of As and Sb co-contamination. 相似文献