Details of Structure Formation During the Induction Period of Spinodal-Type Polymer Crystallization

An unexpected type of primary crystal nucleation is described, involving spinodal decomposition (SD) type microphase separation due to the orientation fluctuations of rigid segments prior to crystal nucleation. This type of mechanism was found by the present authors about 10 years ago, and recently, it was theoretically revealed by Olmsted et al. to be one of three types of primary crystal nucleation: the well-known homogeneous crystal nucleation directly from the liquid–crystal coexistence domain, which occurs at higher temperatures above the binodal temperature T _b , crystal nucleation after binodal microphase separation between T _b and spinodal temperature T _s , and that after SD below T _s . The detailed experimental results for the spinodal-type crystal nucleation, especially the temperature dependence of characteristic wavelength in SD, are explained as well.     

一种基于奇异谱的语音激活检测方法

为了提高语音激活检测在低信噪比环境中的检测性能,提出了一种基于奇异谱的语音激活检测方法。首先用多窗口方法计算每一帧语音信号的相关矩阵;然后对相关矩阵进行奇异值分解;利用奇异值可以反映有用信号和噪声分布情况的特性,将每一帧语音信号经过加权处理后的最大奇异值与自适应阈值进行比较进行语音激活检测。该方法原理简单,易于硬件实现,通过实验仿真表明,在低信噪比环境下,和基于对数能量方法相比,本文方法也能够很好的区分语音段和非语音段,有良好的检测性能。     

高压下固相硝基甲烷分解的分子动力学计算

基于ReaxFF, 采用NVT系综和Berendsen方法对0–7 GPa时和2500 K时固相硝基甲烷的 分解过程进行分子动力学计算, 通过分析硝基甲烷发生分解反应生成的碎片数量随时间的变化, 对不同压强下硝基甲烷的分解机理进行研究. 计算结果表明在0–3 GPa时, 初始分解路径为C–N键断裂和硝基甲烷的异构化; 在4–7 GPa 时, 初始分解路径为分子间质子转移和C–N, N–O键的断裂; 在硝基甲烷的第二阶段反应中存在H₂O, NO, NO₂, HONO, 硝基甲烷分子自身的催化反应. 硝基甲烷在高温高压下发生热分解反应生成碳团簇, 且团簇中碳原子的数量和碳团簇的空间构型随着压强的变化而变化. 关键词： ReaxFF 分子动力学 热分解 压强效应 碳团簇     

变工况下旋转机械故障跟踪的相空间曲变方法

为实现在工况变化条件下对旋转机械的故障预测, 提出使用相空间曲变和平滑正交分解理论在变工况条件下跟踪旋转机械的故障演化过程. 首先在对目标系统的观测时间序列相空间重构的基础上, 通过量化相空间曲变构建信号损伤演化的跟踪函数, 为弥补累积模型误差和相空间点局部分布概率差异造成的误差, 将时间序列和相空间进行分割, 并以此构建跟踪矩阵; 再利用平滑正交分解方法将跟踪矩阵中分别由实际损伤劣化和工况变化造成的演化趋势进行分离, 根据平滑正交特征值提取出其中能够反映实际故障演化趋势的平滑正交分量; 最后以变转速情况下轴承外环故障退化的仿真信号为例验证算法的有效性. 计算结果表明: 本文提出的算法能够对旋转机械故障的演化趋势实现有效跟踪, 基本排除转速波动造成的工况变化影响. 关键词： 相空间曲变 平滑正交分解 变工况 故障跟踪     

在SQUID心磁测量中基于奇异值分解和自适应滤波的噪声消除法

采用矩阵奇异值分解(singular value decomposition, SVD)的方法，对高温射频超导量子干涉仪(HTc rf-SQUID)采集到的单通道心磁信号进行处理.证明了对于近似周期性的心磁信号，在无参考噪声的情况下矩阵奇异值分解的方法与自适应窄带陷波相结合有较好的消除广谱噪声的效果. 关键词： 高温射频超导量子干涉仪 心磁信号 奇异值分解 噪声消除     

A kind of distortion of mean velocity profile in pipe Poiseuille flow and its stability behaviour

This paper presents a kind of distortion of Hagen-Poiseuille velocity profile in pipe Poiseuille flow. This distortion can be regarded as a general expression of the influence on the mean flow by nonlinear interaction of various components of axisymmetric perturbations. Through the investigation of the stability behaviour of this velocity profile, this paper obtains unstable result induced by axisymmetric perturbations for the first time, and thus presents a new possible approach which leads to instability of Hagen-Poiseuille flow.     

Schmidt modes and entanglement

Motivated by their frequent use in quantum mechanical studies of entanglement, we give a brief overview of Schmidt modes and Schmidt decompositions of two-particle wave functions. We discuss methods of their derivation and include a little-known approach used in the original work by E. Schmidt [Math. Annalen, 63 (1906), 433]. This employs the bipartite wave function itself rather than the more complicated two-party reduced density matrix. As an illustration, Schmidt modes for two-photon polarisation qutrits are derived in a general form. The derivation is accompanied by a series of simple examples with special choices of parameters. Relationships between Schmidt modes, polarisation Stokes vectors and entanglement are also discussed.     

Electron spin resonance in pyrolyzed lignin

An investigation has been made into electron spin resonance (ESR) occurring in the ranges of carbons prepared from periodate lignin by vacuum pyrolysis. Line shape, line width, g-factors, saturation effects, and free spin concentration have been measured and the effect of oxygen on these parameters has been examined. A g-shift and lines with inhomogeneous broadening have been observed. In the presence of oxygen the lower-temperature carbons showed an unexpected increase in the detectable free spin concentration. The discussion includes factors affecting the nature of the free spins in the pyrolyzed material.     

Adomian Decomposition Method Using Integrating Factor

This paper proposes a new Adomian decomposition method by using integrating factor.Nonlinear models are solved by this method to get more reliable and efficient numerical results.It can also solve ordinary differential equations where the traditional one fails.Besides,the complete error analysis for this method is presented.     

丙烯腈-尿素包合物的形成过程及特征

利用差示扫描量热法(DSC)和X射线衍射(XRD)研究了在不同丙烯腈/尿素投料比情况下的丙烯腈-尿素包合物的形成过程和组成. 实验结果表明DSC是一种研究包合物的客主比及分解热的有效方法. 测定了丙烯腈-尿素包合物的客主比和分解热分别为1.17和5361.53 J/mol. 同时发现丙烯腈-尿素包合物的形成依赖于冷冻时间,在足够长的冷冻时间之后丙烯腈-尿素包合物的组成达到稳定状态. 实验结果表明,丙烯腈分子可能是采用堆叠的方式排布在尿素晶道结构中. XRD结果表明只要丙烯腈分子进入尿素晶格中,丙烯腈-尿素包合物的结构便形成了,并且这种结构与形成过程终了时的结构是一致的. 只要丙烯腈是足量的,包合物中的丙烯腈分子排列会随冷冻时间的延长而增长,直到尿素的晶道结构被丙烯腈分子填满.