Ab initio evaluation of oxidation numbers in some substituted benzenes

Giambiagi’s definition of oxidation number of an atom in a molecule has been applied successfully in theab initio SCF theory to calculate oxidation numbers using STO-3G and 4–31G basis sets for some substituted benzenes involving -F, -OH, -CH₃ and -NH₂ as substituents. The present study suggests that the oxidation numbers also seem to be indicative of their orientational behaviour like the net atomic charges.     

A Bahadur efficiency comparison between one and two sample rank statistics and their sequential rank statistic analogues

One and two sample rank statistics are shown in general to be more efficient in the Bahadur sense than their sequential rank statistic analogues as defined by Mason (1981, Ann. Statist.9 424–436) and Lombard (1981, South African Statist. J.15 129–152), even though the two families of statistics (those based on full ranks and those based on sequential ranks) have the same Pitman efficiency against local alternatives. In the process, general results on large deviation probabilities and laws of large numbers for statistics based on sequential ranks are obtained.     

Butler groups with a single τ-adic relation

It is proved that a τ-adic relation characterizing a Butler group is piecewise rational. Translated fromMatematicheskie Zametki, Vol. 60, No. 6, pp. 882–887, December, 1996.     

Central limit theorem and weak law of large numbers with rates for martingales in Banach spaces

This paper is concerned with large-$\text{O}$ error estimates concerning convergence in distribution as well as norm convergence for Banach space-valued martingale difference sequences. Indeed, two general limit theorems equipped with rates of convergence for such difference sequences are established. Applications of these lead to the central limit theorem and the weak law of large numbers with rates for Banach space-valued martingales.     

模糊最短路的一种算法

模糊最短路问题在许多领域有着广泛的应用,研究这一问题具有重要意义。根据多准则决策理论求非被支配路径集合,求最大效用模糊最短路以及利用模糊数排序方法求模糊最短路是常用的三种研究方法,本文利用OERI排序原理,使网络模糊边长具有线性可加性,对具有三角模糊数边权的网络给出了一种标号算法,该算法简单高效,且易于在计算机上实现,算法的时间复杂度为O(n^2)。     

The loss of tightness of time distributions for homeomorphisms of the circle

For a minimal circle homeomorphism we study convergence in law of rescaled hitting time point process of an interval of length 0$">. Although the point process in the natural time scale never converges in law, we study all possible limits under a subsequence. The new feature is the fact that, for rotation numbers of unbounded type, there is a sequence going to zero exhibiting coexistence of two non-trivial asymptotic limit point processes depending on the choice of time scales used when rescaling the point process. The phenomenon of loss of tightness of the first hitting time distribution is an indication of this coexistence behaviour. Moreover, tightness occurs if and only if the rotation number is of bounded type. Therefore tightness of time distributions is an intrinsic property of badly approximable irrational rotation numbers.

     

Rational Approximation of Analytic Functions Having Generalized Orders of Rate of Growth

Let f be holomorphic on a domain G C¯ and _n be the error in best approximation of f in the supremum norm on a compact set E G by rational functions of order n. We obtain results characterizing the degree of decrease of the best approximation _n in terms connected with the condenser (E,F), F=C¯ \ G¯, and the rate of growth of the maximum modulus of f(z). In particular, if f has a generalized order (, , f) in the domain G, thenlim sup_n (n)/ (log (1/log⁺((_{0 1} ....... _n)^1/n(n+1) ))) (, , f),where = exp (1/C(E,F)), C(E,F) is the capacity of the condenser (E,F).     

BERNOULLI CONVOLUTIONS ASSOCIATED WITH CERTAIN NON——PISOT NUMBERS

The Bernoulli convolution Vλ measure is shown to be absolutely continuous with L^2 density for almost all 1/2＜λ＜1, and singular if λ^-1 is a Pisot number. It is an open question whether the Pisot type Bernoulli conuolutions are the only singular ones. In this paper, we construct a family of non-Pisot type Bernoulli convo-lutions Vλ such that their density functions, if they exist, are not L^2. We also construct other Bernolulli convo-lutions whose density functions if they exist, behave rather badly.