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961.
962.
S. Dirè P. Egger M. L. Di Vona M. Trombetta S. Licoccia 《Journal of Sol-Gel Science and Technology》2004,32(1-3):57-61
The preparation of nanostructured organic-inorganic materials by assembling of nanobuilding blocks allows controlling the extent of phase interaction, which in its turn governs structure-properties relationships. We present here the synthesis of siloxane-based nanobuilding blocks prepared by reacting diphenylsilanediol with vinyltriethoxysilane and triethoxysilane. The reaction products were obtained by non-hydrolytic condensation between silanediol and ethoxide groups in inert atmosphere, in the presence of pyridine, triethylamine or butyl lithium. Different synthetic conditions were examined by means of ATR-FTIR and NMR spectroscopies, showing the formation of siloxane bonds. In the case of triethoxysilane the reaction carried out in the presence of pyridine leads to Si–H bond preservation in the final product. Air stable products with improved Si–O–Si hydrolytic stability can be obtained by removal of the base after the reaction completion. The condensation products can be described as a mixture of siloxane rings involving difunctional and trifunctional silicon units. 相似文献
963.
S. Stupnikova E. Petushkova D. Muceniece V. Lūsis 《Chemistry of Heterocyclic Compounds》2007,43(1):41-49
The recyclization of 1,4-dihydropyridines in aqueous-alcoholic hydrochloric acid medium proceeds with cleavage of a C-N bond
and pyridine ring opening. Cyclohexenone derivatives are formed as a result of the subsequent intramolecular crotonic condensation
of the acyclic intermediate. The leaving carbonyl substituents depart simultaneously with recyclization, depending on the
acidity of the reaction medium.
Dedicated to Prof. Dr. E. Lukevics on the occasion of his 70th birthday.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 49–58, January, 2007. 相似文献
964.
A novel method for DNA detection is proposed that is based on the enhancement of resonance light scattering (RLS) of Ru(bpy)2PIP(V)2+ at pH 2.7. Under optimum conditions, good linear relationships were obtained in the wide concentration range of 16–5120 ng mL−1. The linear equation is I
RLS = 13.15 + 171.4 c (μg mL−1), the correlation coefficient (r) is 0.9999. The detection limit of calf thymus DNA is 5.02 ng mL−1. Plasmid DNA extracted from bacillus subtilis was determined by the method with satisfactory results. 相似文献
965.
Yong Zhao Xianliang Sheng Jin Zhai Lei Jiang Chunhe Yang Zhongwei Sun Yongfang Li Daoben Zhu 《Chemphyschem》2007,8(6):856-861
Titanium dioxide (TiO(2)) photoelectrodes with micro/nano hierarchical branched inner channels have been prepared by an electrohydrodynamic (EHD) technique and assembled to form dye-sensitized solar cells (DSSCs). Excellent penetration of ionic-liquid electrolytes and enhanced light harvesting in the longer wavelength region are realized within the composite-structure electrode, thus a better fill factor (ff) of 75.3 % and higher conversion efficiency (eta) of 7.1 % are obtained for viscous ionic-liquid electrolytes compared to pure nanostructured films. Hierarchical branched channels in the photoanodes can efficiently improve the transport properties of redox-active species in viscous electrolytes, which is demonstrated by electrical impedance spectroscopy (EIS). The incident monochromatic photon-to-electron conversion efficiency (IPCE) shows that enhanced light scattering in the composite film is of benefit for light harvesting and thus for solar energy conversion efficiency. 相似文献
966.
ZHANG Jing HUANG Ru-dan ZHU Oin-lei HU Chang-wen 《高等学校化学研究》2007,23(4):483-485
Introduction In recent years,considerable attention has been paid to supramolecular networks based on metal organic building blocks because of their potential applications in diverse fields,such as,catalysis,optics,sensors, magnetism,and molecular recognition[1-3].On the ba- 相似文献
967.
The treatment of tert-alkyl phenyl thioketones with Lawesson’s reagent (LR) gave two diastereomeric 1,3,2-dithiaphosphetane 2-sulfides in high yields. The structure of one of the major diastereomers was determined by X-ray crystallography. The reaction of 2-adamantanethione with LR yielded the corresponding spiro-1,3,2-dithiaphosphetane 2-sulfide derivative in 87% yield. 相似文献
968.
(R)-4-Menthenone in the synthesis of optically pure sex pheromone of the peach leafminer moth (Lyonetia clerkella) 总被引:1,自引:0,他引:1
Kharisov R. Ya. Latypova E. R. Talipov R. F. Muslukhov R. R. Ishmuratov G. Yu. Tolstikov G. A. 《Russian Chemical Bulletin》2003,52(10):2267-2269
The synthesis of (14S)-methyloctadec-1-ene, sex pheromone of the peach leafminer moth (Lyonetia clerkella), is described to demonstrate a new potential of the synthetic use of (R)-4-menthenone. 相似文献
969.
Björn O. Roos Valera Veryazov Per-Olof Widmark 《Theoretical chemistry accounts》2004,111(2-6):345-351
New basis sets of the atomic natural orbital (ANO) type have been developed for the atoms Li–Fr and Be–Ra. The ANOs have been obtained from the average density matrix of the ground states and the lowest excited states of the atom, the positive ion, and the dimer at its equilibirium geometry. Scalar realtivisitc effects are included through the use of a Douglas–Kroll Hamiltonian. Multiconfigurational wave functions have been used with dynamic correlation included using second-order perturbation theory (CASSCF/CASPT2). The basis sets are applied in calculations of the ground-state potentials for the dimers. Computed bond energies are accurate to within 0.05 eV for the alkaline dimers and 0.02 eV for the alkaline-earth dimers (except for Be2).Acknowledgments.ensp;B.O.R. would like to express his gratitude to Prof. Jacopo Tomasi for all the inspiration that his scientific work has given him through the years and continues to do in particular through the work on solvent effects on molecular properties. This work has been supported by a grant from the Swedish Science Research Council, VR.Contribution to the Jacopo Tomasi Honorary Issue 相似文献