Molecular weight control of polyacrylamide with sodium formate as a chain‐transfer agent: Characterization via size exclusion chromatography/multi‐angle laser light scattering and determination of chain‐transfer constant

We discuss the synthesis and characterization of polyacrylamide (PAM) homopolymers with carefully controlled molecular weights (MWs). PAM was synthesized via free‐radical solution polymerization under conditions that yield highly linear polymer with minimal levels of hydrolysis. The MW of the PAM homopolymers was controlled by the addition of sodium formate (NaOOCH) to the polymerization medium as a conventional chain‐transfer agent. MWs and polydispersity indices (PDIs) were determined via size exclusion chromatography/multi‐angle laser light scattering analysis; for polymerizations carried out to high conversion, PAM MWs ranged from 0.23 to 6.19 × 10⁶ g/mol, with most samples having PDI ≈2.0. Zero‐shear intrinsic viscosities of the polymers were determined via low‐shear viscometry in 0.514 M NaCl at 25 °C. Data derived from the polymer characterization were used to determine the chain‐transfer constant to NaOOCH under the given polymerization conditions and to calculate Mark–Houwink–Sakurada K and a values for PAM in 0.514 M NaCl at 25 °C. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 560–568, 2003     

RHIC能量多粒子产生的双源统计模型分析

用双源统计模型分析研究了SNN=130 GeV Au+Au反应中的多粒子产生并与单源统计模型的结果进行了比较.研究表明,该反应有一个高温且大体积的内源.这个源的温度比SPS能量的内源至少高15MeV,体积至少大2倍,文中给出了分析     

自适应桁架形状控制中主动杆多目标最优配置

导出自适应桁架结构静态形状控制方程，这些方程在线弹性范围内适用；一般主动杆件数远小于结构杆件数目，且主动杆件的配置问题取决于控制能量和杆件强度等因素，因此基于最短行程和最小导出内力指标和模态退火组合优化算法进行了主动杆件的多目标最优配置；通过算例分析验证了本文分析方法的可行性和有效性。     

非线性时滞差分方程的全局吸引性

得到了具有多重时滞非线性差分方程x(n 1)-x(n) ∑i=1^k pi(n)fi(x(gi(n)))=0,n=0,1,2,…的每个解趋于零的充分条件。     

多层金属爆炸焊接复板飞行姿态的计算方法

在两层金属爆炸焊接复板飞行姿态的理论计算基础上，运用质量守恒、动量守恒定理和契特公式推导了多层金属爆炸接复板飞行姿态的理论计算模型，经过实验验证，该计算模型和实验相符合，对于多层金属爆炸焊接工艺参数的设计具有很高的使用价值。     

Self‐Assembly of Amphiphilic Anthracene‐Functionalized β‐Cyclodextrin (CD‐AN) through Multi‐Micelle Aggregation

Multi‐micelle aggregation (MMA) mechanism is widely acknowledged to explicate large spherical micelles self‐assembly, but the process of MMA during self‐assembly is hard to observe. Herein, a novel kind of strong, regular microspheres fabricated from self‐assembly of amphiphilic anthracene‐functionalized β‐cyclodextrin (CD‐AN) via Cu(I)‐catalyzed azide‐alkyne click reactions is reported. The obtained CD‐AN amphiphiles can self‐assemble in water from primary core–shell micelles to secondary aggregates with the diameter changing from several tens nm to around 600–700 nm via MMA process according to the images of scanning electron microscopy, transmission electron microscopy, and atomic force microscopy as well as the dynamic light scattering measurements, followed by further crosslinking through photo‐dimerization of anthracene. What merits special attention is that such photo‐crosslinked self‐assemblies are able to disaggregate reversibly into primary nanoparticles when changing the solution conditions, which is benefited from the designed regular structure of CD‐AN and the rigid ranging of anthracene during assembly, thus confirming the process of MMA.

     

Fabrication of Photoelectrochemical Glucose Biosensor in Flow Injection Analysis System Using ZnS/CdS‐Carbon Nanotube Nanocomposite Electrode

In this work, a photoamperometric glucose biosensor based on glucose oxidase (GODx) was developed in flow injection analysis (FIA) system using ZnS‐CdS quantum dot (QD) modified multiwalled carbon nanotube/glassy carbon electrode (ZnS‐CdS/MWCNT/GCE). Cyclic voltammograms of the proposed electrode (GODx/ZnS‐CdS/MWCNT/GCE) showed a pair of well‐defined reversible redox peak attributing that direct electron transfer between the protein and electrode. The current of the reduction peak became more cathodic in the presence of O₂ due to the electrocatalytic activity of the electrode towards the reduction of dissolved O₂, but reduction current shifted to a less negative value upon addition of glucose in the solution. The obtained CV currents were affected by the irradiation of the electrode surface. Thus, the photoelectrochemical biosensing of glucose in the FIA system was studied by monitoring of the changes in the electrocatalyzed reduction peak current of dissolved O₂ at the proposed electrode dependent on glucose concentration. The proposed photoelectrochemical FIA method has a linear response to glucose ranging from of 0.01 to 1.0 mM with detection limit of 3.0 μM under optimized conditions. Photoelectrochemical biosensor was successfully fabricated in FIA system for selective, sensitive and repeatable detection of glucose and has been satisfactorily applied to determination of glucose in real sample.     

Optimizing garbage collection vehicle routing problem with alternative fuel-powered vehicles

Abstract

This paper considers the garbage collection problem in which vehicles with multiple compartments are used to collect the garbage. The vehicles are considered to be Alternative Fuel-powered Vehicles (AFVs). Compared with the traditional fossil fuel powered vehicles, the AFVs have limited fuel tank capacity. In addition, AFVs are allowed to refuel only at the depot. We provide a mathematical formulation and develop two solution approaches to solve the problem. The first approach is based on the saving algorithm, while the second is based on the ant colony system (ACS) metaheuristic. New problem instances have been generated to evaluate the performance of the proposed algorithms.     

Multi‐switching combination–combination synchronization of non‐identical fractional‐order chaotic systems

In this paper, multi‐switching combination–combination synchronization scheme has been investigated between a class of four non‐identical fractional‐order chaotic systems. The fractional‐order Lorenz and Chen's systems are taken as drive systems. The combination–combination of multi drive systems is then synchronized with the combination of fractional‐order Lü and Rössler chaotic systems. In multi‐switching combination–combination synchronization, the state variables of two drive systems synchronize with different state variables of two response systems simultaneously. Based on the stability of fractional‐order chaotic systems, the multi‐switching combination–combination synchronization of four fractional‐order non‐identical systems has been investigated. For the synchronization of four non‐identical fractional‐order chaotic systems, suitable controllers have been designed. Theoretical analysis and numerical results are presented to demonstrate the validity and feasibility of the applied method. Copyright © 2017 John Wiley & Sons, Ltd.     

Distributed subgradient method for multi‐agent optimization with quantized communication

This paper focuses on a distributed optimization problem associated with a time‐varying multi‐agent network with quantized communication, where each agent has local access to its convex objective function, and cooperatively minimizes a sum of convex objective functions of the agents over the network. Based on subgradient methods, we propose a distributed algorithm to solve this problem under the additional constraint that agents can only communicate quantized information through the network. We consider two kinds of quantizers and analyze the quantization effects on the convergence of the algorithm. Furthermore, we provide explicit error bounds on the convergence rates that highlight the dependence on the quantization levels. Finally, some simulation results on a l₁‐regression problem are presented to demonstrate the performance of the algorithm. Copyright © 2016 John Wiley & Sons, Ltd.