全文获取类型
收费全文 | 3782篇 |
免费 | 318篇 |
国内免费 | 190篇 |
专业分类
化学 | 368篇 |
晶体学 | 6篇 |
力学 | 785篇 |
综合类 | 36篇 |
数学 | 1417篇 |
物理学 | 1678篇 |
出版年
2023年 | 27篇 |
2022年 | 43篇 |
2021年 | 73篇 |
2020年 | 82篇 |
2019年 | 81篇 |
2018年 | 79篇 |
2017年 | 80篇 |
2016年 | 104篇 |
2015年 | 125篇 |
2014年 | 167篇 |
2013年 | 280篇 |
2012年 | 151篇 |
2011年 | 169篇 |
2010年 | 136篇 |
2009年 | 195篇 |
2008年 | 231篇 |
2007年 | 262篇 |
2006年 | 210篇 |
2005年 | 166篇 |
2004年 | 163篇 |
2003年 | 171篇 |
2002年 | 135篇 |
2001年 | 135篇 |
2000年 | 178篇 |
1999年 | 131篇 |
1998年 | 110篇 |
1997年 | 96篇 |
1996年 | 61篇 |
1995年 | 57篇 |
1994年 | 48篇 |
1993年 | 56篇 |
1992年 | 40篇 |
1991年 | 40篇 |
1990年 | 20篇 |
1989年 | 17篇 |
1988年 | 24篇 |
1987年 | 26篇 |
1986年 | 16篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 4篇 |
1982年 | 10篇 |
1981年 | 11篇 |
1980年 | 6篇 |
1979年 | 13篇 |
1977年 | 8篇 |
1973年 | 12篇 |
1972年 | 4篇 |
1971年 | 2篇 |
1969年 | 3篇 |
排序方式: 共有4290条查询结果,搜索用时 312 毫秒
71.
Laurent Serlet 《Journal of Theoretical Probability》1996,9(3):561-578
We study super-Brownian motion inR
d
starting from a nontrivial finite measure and conditioned to nonextinction as defined by Evans. If (Y
t
)
t0
denotes this process, we provide a new approach to the immortal particle representation of (Y
t
)
t0
. We then show that the measureZ onR
d
defined byZ(B)=
o
1
Y
t
(B) dt is almost surely finite on compact sets whend5 and almost surely infinite on every ball whend4. 相似文献
72.
半晶性的聚对苯二甲酸乙二醇酯(PET)存在不同尺寸运动单元的多重形式的分子运动,而且PET等高聚物前结构欠序、晶界和杂质等缺陷还使电子价带与导带间的禁带中出现局域能级(陷阱),并成为捕获载流子的中心,从而影响载流子的输运性质。分子运动和陷阱 相似文献
73.
本文研究了 PVDF-P(VDF-HFE)以及 PVDF-P(VDF-TFE)共混体系的压电、介电、力学松弛谱。其松弛转变过程基本与 PVDF 的相似。α,β,γ压电松弛峰分别位于40~120℃,-40℃,-85℃附近。实验结果表明后一体系的压电性大于前一体系的。同时,PVDF-P(VDF-TFE)的压电性也大于PVDF-PMMA 共混体系的。选择第二组分时,以介电常数高,模量小而本身又具有压电性的,更有助于共混薄膜压电性的提高。在同样的极化条件下,经拉伸的 P(VDF-TFE)薄膜,其压电性大于未经拉伸的薄膜,这表明分子的取向对薄膜的压电性也有影响。TSC 表明,42℃的松弛峰与晶区表面捕获的空间电荷有关,对压电性也有一定的贡献。 相似文献
74.
微波辐射下双(2-苯并咪唑基)丙烷的合成与结构表征 总被引:8,自引:2,他引:8
与传统加热相比较,微波辐射促进的有机合成反应具有加热时间短、节能、产率高、不使用或少使用溶剂而对环境友好和节约成本等优点[1]。苯并咪唑类化合物具有广泛的生物活性而被应用到仿生有机合成、遗传学染色体研究及单层膜合成与形态研究的领域[2~4]。苯并咪唑类化合物的传统合成方法是:在HC1、多聚磷酸(PPA)、H3BO3等酸性催化剂使用下加热回流有机酸与邻苯二胺的混合物,然而反应通常需要较高的压力、温度或较长的时间,副反应多[5]。本研究在微波辐射下,以戊二酸和邻苯二胺为原料、PPA为催化剂合成了双(2-苯并咪唑基)丙烷,用正交试… 相似文献
75.
76.
Y. Yavin 《Journal of Optimization Theory and Applications》1984,44(1):159-179
Consider the random motion in the plane of a pointM, whose velocityv=(v
1,v
2) is perturbed by an 2-valued Gaussian white noise. Only noisy nonlinear observations taken on the point location (state) are available toM. The velocityv is of the formv(y)=
u
(u
1,u
2)
y
(du), wherey denotes the value of the observed signal,U is the range of the velocity, and, for eachy,
y
is a probability measure on (U). Using the available observations, the pointM wishes to steer itself into a given target set by choosing a randomized strategy ={
y
:y 2}. Sufficient conditions on weak optimal randomized strategies are derived. An algorithm for computing weak suboptimal randomized strategies is suggested, and the strategies are computed for a variety of cases.This work was partially supported by a grant from Control Data. 相似文献
77.
Ch. Linga Raju K.V. Narasimhulu N.O. Gopal J.L. Rao B.C.V. Reddy 《Journal of Molecular Structure》2005,754(1-3):100-105
Electron paramagnetic resonance (EPR) studies have been carried out on VO2+ ions doped in single crystals of ferroelectric material, potassium thiourea bromide (PTB) at room temperature and in the temperature range 103–343 K on X-band MW frequency. An isotropic octet spectrum characteristic of VO2+ ion was obtained due to the fast re-orientation of the VO2+ in PTB lattice, which exhibits glassy nature at certain range around room temperature. The temperature dependant EPR spectra of VO2+ ions in this host lattice has been attributed to the occurrence of multiple phase transitions due to the combined environment effects of KBr and thiourea materials in the single crystal. From the optical absorption spectrum, the crystal field splitting parameter Dq, tetragonal parameters Ds and Dt have been evaluated and discussed. 相似文献
78.
Kazuhiro Matsuo 《Journal of statistical physics》1978,18(6):535-555
A projection operator method is presented, which provides the most efficient way for calculating the stationary behavior of nonlinear Brownian motion. A continued-fraction expansion of the Fourier-Laplace transform of the displacement correlation function or the spectral density is used. This method utilizes a successive optimization procedure on the nonlinear terms and includes the method of statistical linearization as the lowest order approximation. A systematic way to calculate the continued fraction numerically up to sufficient order for convergence is developed, which enables us to obtain the spectral density of a system previously uncomputable.Numerical computations of the spectral density of a nonlinear oscillator with a double-well potential are presented and compared with the results obtained by statistical linearization.This work was supported in part by the National Science Foundation under Grant CHE 75-20624. 相似文献
79.
A mathematical framework for translational Brownian motion on hypersurfaces is presented, using an imbedding of the surface and Ito diffusions in the ambient space. This includes a survey of Ito calculus and differential geometry. Computational methods for time correlation functions relevant to spin relaxation studies on curved interfaces are given, and explicit calculations of time correlation functions and order parameters for a Rippled surface are presented. 相似文献
80.
Accurate lower and upper bounds for the nonrelativistic lowest energies1
E
0 and3
E
0 of the singlet and triplet-system of the4He-Isotop are calculated with the linearized method of variance minimization. The same was done for1
E
1 the energy of the first excitedS-state 21
S.
The results especially for1
E
0 and3
E
0 in a.u. are −2.90330769975 ≤1
E
0 ≤ −2.90330769218 −2.17493242637 ≤3
E
0 ≤ −2.17493242459 i.e. the values are determined with an absolute error smaller than 0.00167 cm−1 for1
E
0 and 0.00039 cm−1 for3
E
0. 相似文献