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991.
We report the results of our studies on the optical and thermal properties of two nonmesogenic compounds, namely, Cetyl-dimethyl-ethylammonium bromide (CDEAB) and Glacial acetic acid. The mixture exhibits very interesting schilieren texture of micellar nematic phase, SmA, SmC*, and SmE phases, respectively, at different concentrations of CDEAB sequentially when the specimen is cooled from its isotropic phase. The order parameter (S) of the micellar nematic phase is estimated with the help of temperature dependence of optical anisotropy from the measured values refractive index and density data. The temperature variation of order parameter of the experimental curve is very well fitted with the Mayer–Saupe theoretical curve. X-ray studies have been discussed. The formation of above phases has been confirmed by optical and DSC studies. 相似文献
992.
Clémence NikitineSéverine Comba Isabelle PitaultValérie Meille 《Journal of Molecular Liquids》2011,161(3):103-106
Viscosities of the ternary and binary mixtures of 1-octene, Rhodorsil H68, Rhodorsil 308V750 have been measured at different temperatures between 293.15 and 353.15 K and at atmospheric pressure. Two correlations were established to predict the viscosity of all mixtures. The first is a statistical expression deduced from an experimental design. The second is based on an additivity law and the temperature effect on binary mixtures. 相似文献
993.
E. Bringuier 《Physica A》2011,390(11):1861-1875
994.
Kim Jinsoo Jamil Muhammad Jung Jae Eun Jang Jae Eun Farzana Ahmad Jin Woo Lee Sang Woo Park Woo Min-Kyung Kwak Ji Yeon Jeon Young-Jae 《中国化学》2011,29(1):48-52
Molecular dynamics (MD) computer simulation techniques, as a powerful tool commonly utilized by the liquid crystal display (LCD) community, usually are employed for computing the equilibrium and transport properties of a classical many body system, since they are very similar to real experiments in many respects. In this paper we present molecular dynamics computer simulation results taken for a mixture of the two different kinds of nematic liquid crystals (LCs). We calculated rotational viscosity from Brownian behavior with friction of the mean director of the mixture comprising pentylcyanobiphenol (5CB) and decylcyanobiphenol (10CB) by using molecular dynamics computer simulation, where intermolecular potential parameter is Generalized AMBER force field (GAFF). Our computed results show a good agreement with the experimental results. 相似文献
995.
996.
针对目前傅里叶变换红外光谱分析还不能独立应用于气体成分多、部分成分具有同种分子基团、气体浓度变化范围大的复杂多组分混合气体的在线分析问题,文章以甲烷、乙烷、丙烷、异丁烷和正丁烷五种轻烷烃气体的混合气体的光谱分析为例,提出采用充分考虑气体温度、压力及干扰气的影响,采用特征提取、光谱畸变识别与修正、神经网络的鲁棒建模与分层建模的方法来实现具有相同分子基团的混合气体光谱分析。最后给出了五种轻烷烃气体的光谱与气相色谱的在线分析结果。分析结果对比曲线表明,两种仪器分析结果曲线几乎完全重合,这说明该文提出的光谱分析方法可以独立应用于具有相同分子基团的多组分气体混合气体现场在线分析,解决了科学研究和工程应用中气体组分复杂、气体浓度变化范围大的复杂多组分混合气现场分析难题。 相似文献
997.
基于线性光谱模型和支撑向量机的软硬分类方法 总被引:1,自引:0,他引:1
针对硬分类方法中无法解决的混合像元问题及软分类方法中全图共用一套端元进行混合像元分解所带来的弊端,提出了一种新的软硬分类方法。该方法通过分析目标地物在图像中的分布情况,自动计算判别阈值,将图像分为目标地物纯净区域、目标地物混合区域和非目标地物区域。对于目标地物纯净区域和非目标地物区域采用硬分类方法(支撑向量机)快速提取分类信息;对于目标地物混合区域采用软分类方法(端元可变的线性混合像元分解)提取目标地物丰度信息,最后得到目标地物软硬分类结果。通过对北京地区ALOS图像的应用试验,并将新方法与支撑向量机、线性光谱混合模型进行比较,新方法的RMSE值为0.203,总量精度达到95.48%,高于支撑向量机和线性光谱混合模型。实验结果表明,新方法能够有效解决混合像元问题,提高图像分类精度。 相似文献
998.
基于化学反应的非链式脉冲DF激光器是产生3.5~4.1μm波段的有效相干辐射光源,具有存储能量水平高等优点。这些优点使得该激光器倍受中红外领域激光研究者的重视。为了更好地提高非链式脉冲DF激光器的输出性能,研制高能量水平的DF激光器,本文详细介绍了自引发大体积放电技术、混合气体配比技术、循环冷却技术等DF激光器关键技术,重点介绍了自引发大体积放电技术。这几种技术将为研制高性能DF激光器提供理论指导。 相似文献
999.
Bo Zhang Vsevolods Kamenskihs Hoi Dick Ng John H.S. Lee 《Proceedings of the Combustion Institute》2011,33(2):2265-2271
In this study, direct initiation of spherical detonations in highly argon diluted mixtures is investigated. Direct initiation is achieved via a high voltage capacitor spark discharge and the critical energy is estimated from the analysis of the current output. Stoichiometric acetylene–oxygen mixtures highly diluted with 70% argon is used in the experiment. Previous investigations have suggested that detonations in mixtures that are highly diluted with argon have been shown to be “stable” in that the reaction zone is at least piecewise laminar described by the ZND model and cellular instabilities play a minor role on the detonation propagation. For the acetylene–oxygen mixture that is highly diluted with argon, the experimental results show that the critical energy where the detonation is “stable” is in good agreement with the Zel’dovich criterion of the cubic dependence on the ZND reaction length, which can be readily determined using the chemical kinetic data of the reaction. The experimental results are also compared with those estimated using Lee’s surface energy model where empirical data on detonation cell sizes are required. Good agreement is found between the experimental measurement and theoretical model prediction, where the breakdown of the 13λ relationship for critical tube diameter – and hence a different propagation and initiation mechanism – is elucidated in highly argon diluted mixtures and this appears to indicate that cellular instabilities do not have a prominent effect on the initiation process of a stable detonation. 相似文献
1000.
Thermo-Hydro-Mechanical (THM) coupling pro- cesses in unsaturated soils are very important in both theoretical researches and engineering applications. A coupled formulation based on hybrid mixture theory is derived to model the THM coupling behavior of unsaturated soils. The free-energy and dissipative functions for different phases are derived from Taylor's series expansions. Constitutive relations for THM coupled behaviors of unsaturated soils, which include deformation, entropy change, fluid flow, heat conduction, and dynamic compatibility conditions on the interfaces, are then established. The number of field equations is shown to be equal to the number of unknown variables; thus, a closure of this coupling problem is established. In addition to modifications of the physical conservation equations with coupling effect terms, the constitutive equations, which consider the coupling between elastoplastic deformation of the soil skeleton, fluid flow, and heat transfer, are also derived. 相似文献