Preparation of nanocrystalline Sn-TiO2−X via a rapid and simple stannous chemical reducing route

The Sn-TiO_2−X nanoparticles have been prepared via a rapid and simple stannous chemical reducing method. The as-prepared Sn-TiO_2−X nanoparticles were investigated by means of surface photovoltage spectroscopy (SPS), XPS, and DRS technology as well as photocatalytic degradation of RhB were studied under illumination. The experiment results revealed that the reduction of the TiO₂ particles raised their Fermi level, which can enhance the driven force of photoinduced electrons transferring from TiO₂ to adsorbed O₂ and SnO₂ on the surface of TiO₂. On the other hand, the amount of oxygen vacancies of the Sn-TiO_2−X increased after the stannous chemical reduction. The oxygen vacancies can also effectively inhibit the recombination of photoinduced electrons and holes pairs. These factors are favorable to the photocatalytic reaction.     

Effect of hydrogen reduction on microstructure and magnetic properties of mechanochemically synthesized Fe-16.5Ni-16.5Co nano-powder

Most recent findings on structural and magnetic properties of Fe-Ni-Co nano-powders produced by mechanical alloying and subsequent low-temperature hydrogen reduction are presented in this paper. At 300 rpm, with ball to powder weight ratio of 20, single phase nickel-cobalt ferrite is mechanically synthesized for 50 h. The as-milled powder is then subjected to 1 h hydrogen reduction at 700 °C. Hydrogen reduction results in the formation of Fe-16.5%Ni-16.5%Co nano-powders. The phases of the powders are identified by X-ray diffraction (XRD) utilizing Cu Kα radiation. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) are used to study the morphology and the average size of the nano-powder particles. Chemical analysis of the phases present in the reduced sample is determined by electron dispersive spectrometry (EDS). The magnetic properties of the powders are measured by a vibration sample magnetometer (VSM). Results indicate a noticeable change in the magnetic properties of the samples due to Ni_0.5Co_0.5Fe₂O₄ compositional change into Fe-16.5Ni-16.5Co nano-powder.     

The synthesis and kinetic growth of anisotropic silver particles loaded on TiO2 surface by photoelectrochemical reduction method

Silver nanorods with average diameters of 120-230 nm and aspect ratio of 1.7-5.0 were deposited on the surface of TiO₂ films by photoelectrochemical reduction of Ag⁺ to Ag under UV light. The composite films prepared on soda-lime glass substrates were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and atomic force microscopy (AFM). The results show that the TiO₂ film after UV irradiation in AgNO₃ solution is composed of anatase phase TiO₂ and metallic silver with face centered cubic structure. Other compounds cannot be found in the final films. The maximum deposition content of silver particles on the surface of TiO₂ film was obtained with the AgNO₃ concentration of 0.1 M. The kinetic growth rates of silver particles can be controlled by photocatalytic activity of TiO₂ films. The studies suggest that the growth rates of silver particles increase with the enhancement of photocatalytic activity of TiO₂ films. The maximum growth rate of silver particles loaded on TiO₂ films can be up to 0.353 nm min⁻¹ among samples 1#, 2# and 3#, while the corresponding apparent rate constant of TiO₂ is 1.751 × 10⁻³ min⁻¹.     

Low frequency in situ metrology of absorption and dispersion of sound absorbing porous materials based on high power ultrasonic non-linearly demodulated waves

The present work is related to acoustic in situ free-field measurements of sound absorption in porous materials, such as cellular plastic foams, glass-wool or recycled felt materials. The emphasis is given towards fine metrology of absorption in view of potential industrial applications. A powerful ultrasonic array working at 40 kHz is used. It enables to measure absorption acoustical data down to 100 Hz due to the exploitation of the non-linear ultrasonic demodulation phenomenon in air. Fine measurements of acoustic absorption are compared to numerical predictions based on the “equivalent-fluid” model (when the squeleton frame is motionless), and to some measurements performed on a Brüel and Kjaer impedance tube. Dispersion curves are also measured and compared to the numerical predictions for some automotive felt materials which are compressed at various ratios. Data obtained with a dedicated portable instrument are also discussed for the same type of materials and configurations.     

一种多频局域共振型声子晶体板的低频带隙与减振特性

设计了一种多频局域共振型声子晶体板结构, 该结构由一薄板上附加周期性排列的多个双悬臂梁式子结构而构成. 由于多个双悬臂梁式子结构的低频振动与薄板振动的相互耦合作用, 这种局域共振型板结构可产生多个低频弯曲波带隙(禁带); 带隙频率范围内的板弯曲波会被禁止传播, 利用带隙可以实现对薄板的多个目标频率处低频减振. 本文针对这种局域共振型板结构进行了简化, 并基于平面波展开法建立了其弯曲波带隙计算理论模型; 基于该模型, 结合具体算例进行了带隙特性理论分析. 设计、制备了一种存在两个低频弯曲波带隙的局域共振型板结构样件, 通过激光扫描测振仪测试证实该结构存在两个低频带隙, 在带隙频率范围的板弯曲振动被显著衰减.     

Kac-Moody-Virasoro symmetry algebra of a （2＋1）-dimensional bilinear system

Based on some known facts of integrable models, this paper proposes a new （2＋1）-dimensional bilinear model equation. By virtue of the formal series symmetry approach, the new model is proved to be integrable because of the existence of the higher order symmetries. The Lie point symmetries of the model constitute an infinite dimensional Kac- Moody Virasoro symmetry algebra. Making use of the infinite Lie point symmetries, the possible symmetry reductions of the model are also studied     

冷等离子体强化制备金属催化剂研究进展

冷等离子体属于非热平衡等离子体,具有较高的电子能量和较低的气体温度,是一种制备金属催化剂的绿色新方法.等离子体强化制备金属催化剂包含复杂的物理和化学多相反应.一方面,等离子体提供的高活性环境不但可以加速化学反应,使反应时间从数小时缩短至数分钟,还可以使热力学或者动力学上不可行的反应发生,实现非常规制备;另一方面,等离子体强化制备过程中,在介观尺度上等离子体对相接触行为的影响,可使获得的金属催化剂结构区别于传统方法制备的催化剂.本综述总结了冷等离子体制备金属催化剂的反应器结构、物理化学机理、获得金属催化剂的结构特性、制备面临的挑战,并对未来发展进行了展望.重点阐述了冷等离子体反应器、制备机制及其对金属催化剂结构和性能的影响.     

Birkhoff系统约化的Routh方法

研究Birkhoff系统的约化.首先,列出系统的运动微分方程及其循环积分;其次,构造Birkhoff系统的Routh函数组,利用循环积分约化Birkhoff系统的运动微分方程,并使约化后的动力学方程仍保持Birkhoff方程的形式;最后,举例说明结果的应用. 关键词： Birkhoff系统 约化 循环积分     

密布式多输入多输出声呐阵列目标波达方向估计

针对低信噪比条件下多输入多输出声呐受对称噪声分量影响导致测向性能降低的情况,提出了一种基于协方差矩阵重构方法的波达方向估计算法。首先,将噪声场分为对称噪声和非对称噪声两部分,利用协方差矩阵虚部与对称信号无关的性质,去掉协方差矩阵的实部来降低对称噪声对目标波达方向估计精度的影响,采用降维转换方法和矩阵虚部置换原理重构协方差矩阵的实部,避免了双频谱的干扰。然后利用Toeplitz方法对重构的协方差矩阵进行解相干修正,通过奇异值分解获得噪声子空间,最后对目标的波达方向进行估计,可实现微弱信号的准确测向。理论分析和实验结果表明,该方法明显抑制了对称噪声,提高了目标的波达方向估计性能,具有运算速度快、自由度高和目标分辨力强的特点。     

尾缘凹陷轴流风轮内流特性分析与降噪研究

为减少空调室外机用低压轴流风轮叶片的颤振,改善音质,降低噪音和电机功率。本文设计了尾缘凹陷新型三叶轴流风轮,同时除对前缘局部加厚处理外,对叶片其他区域整体减薄。文中采用Navier-Stokes方程对新风轮和原风轮的内流及气动特性进行了三维数值模拟,同时对两者的流量压力曲线和噪音频谱进行了实验研究。研究表明:对轴流风轮叶片尾缘进行凹陷设计,对前缘以外的区域减薄设计,能够减轻风轮重量,降低电机负荷同时减弱转子尾迹;对叶轮前缘进行局部加厚处理可以减小叶尖颤振,降低叶片旋转频率峰值噪音,从整体上降低噪音,改善音质。