溶剂热法制备钴微球及其表征

<正>0引言过渡金属钴以及它的一些氧化物,以其特殊的电、磁和光学性能被广泛应用到信息存储[1]、催化剂[2]、磁光材料[3]、铁磁流体[4]以及生物医学[5]等诸多领域。前人曾经用羰酰钴热解法[6-7]、γ射线照射法[8]、光刻气相沉积法[9]、电化学沉积法[10]和金属盐溶液的     

磁性壳聚糖去除水中腐殖酸的研究

采用高温水热法合成了磁性壳聚糖,并研究了其对水中腐殖酸(HA)的吸附、脱附行为。表征结果表明,磁性壳聚糖粒径大小为200～300nm,氨基含量1.29mmol·g-1,BET比表面积36.00m2·g-1,饱和磁化强度为38.78emu·g-1,易于磁性分离。HA在磁性壳聚糖上的吸附等温线可用Freundlich方程模拟,吸附动力学符合拟二级动力学方程。HA的吸附量随溶液pH值的升高而降低,随不同阳离子浓度增加而增加,不同类型的阳离子对HA吸附效果影响的大小顺序为:Ca2+Mg2+Na+K+。经5个脱附再生循环,磁性壳聚糖仍能保持79.8%的吸附量,表明该吸附剂再生性好,可循环使用。     

二氧化钛纳米棒在空心微球表面的定向生长

通过表面预处理和水热法开展了用二氧化钛包覆空心微球的研究, 用扫描电子显微镜(SEM)和X射线衍射仪(XRD)等表征了所得产品, 并探索了各种反应参数对产物形貌和结构的调控作用. 实验结果表明, 空心微球的表面溶胶-凝胶预处理至关重要. 采用表面溶胶-凝胶技术预处理空心微球表面, 然后在一定条件下进行水热反应, 我们在空心微球表面上成功地包覆了垂直于微球表面并紧密排列的锐钛矿型二氧化钛纳米棒. 该材料质轻、耐腐蚀, 有望成为一种新型光催化剂, 应用于治理水体表面的大面积污染.     

非离子乳化剂细乳液聚合制备草莓型PSt/SiO2纳米复合微球

通过细乳液聚合,使用非离子乳化体系辛基酚聚氧乙烯醚(CA-897),在纳米二氧化硅水分散介质中,以1-乙烯基咪唑(1-VID)作为辅助单体制备了苯乙烯为核,纳米二氧化硅为壳的草莓型PSt/SiO2有机-无机复合微球.实验范围内得到的复合微球的平均粒径和最终SiO2含量分别介于140～180 nm和19 wt%-31wt...     

以聚乙二醇为模板剂制备MoS2空心微球

以聚乙二醇(PEG)为模板剂, 采用软模板法制备出MoS2空心微球, 并采用X射线衍射仪(XRD)、红外光谱仪(IR)和扫描电子显微镜(SEM)对产物进行表征. 结果表明, 所制备的MoS2为粒径约2-7 μm的空心微球, 但结晶程度较差, 需通过退火工艺进行改善; 聚乙二醇与MoS2发生了较为强烈的有机-无机杂化作用, 其浓度和分子量对产物形貌调控均有重要影响. 同时, 结合红外光谱分析, 对MoS2空心微球的形成机理进行了初步的探讨.     

相位匹配下锥形光纤激发出的回廊模谐振

分别计算不同直径下锥形光纤基模和玻璃微球谐振腔内最低阶径向回廊模的传播常量,利用相位匹配条件,作出了锥形光纤与石英玻璃微球腔的直径对应关系曲线.在此基础上,选择锥腰直径2.8 μm左右的低损耗锥形光纤与直径143.1 μm球形度很好的玻璃微球腔进行近场耦合以激发球内的最低阶径向回廊模谐振,在锥形光纤的两端进行通光测试,在输出端获得了等间距分布的窄线宽滤波谱线,其吸收峰位置与利用Mie理论计算的球内最低阶径向回廊模谐振峰位置相一致.     

石英玻璃微球吸收光谱上的结构共振

通过CO2激光器熔融不同直径的熔锥光纤以得到相应直径的石英玻璃微球,利用此微球和熔锥光纤,构造了球微腔耦合系统。实验中利用光腰直径为3.1μm的熔锥光纤与直径为143.1μm的石英玻璃微球进行耦合,通过最大分辨力为1pm的可调谐半导体激光器对该耦合系统进行光谱扫描,发现石英玻璃微球的吸收光谱中出现分立的结构共振峰。利用光学微球腔理论讨论了石英玻璃微球吸收光谱中的结构共振,并用米氏散射理论公式对一阶TE模共振峰的位置以及它们的间隔进行了计算,共振峰位置实验结果与理论结果的误差仅为0.03%,表明实验与计算结果相符。     

Preparation of nano-hydroxyapatite/poly(<Emphasis Type="SmallCaps">l</Emphasis>-lactide) biocomposite microspheres

Nano-hydroxyapatite (HA)/poly(l-lactide) (PLLA) composite microspheres with relatively uniform size distribution were prepared by a solid-in-oil-in-water (s/o/w) emusion solvent evaporation method. The encapsulation of the HA nanopaticles in microshperes was significantly improved by grafting PLLA on the surface of the HA nanoparticles (p-HA) during emulsion process. This procedure gave a possibility to obtain p-HA/PLLA composite microspheres with uniform morphology and the encapsulated p-HA nanoparticle loading reached up to 40 wt% (33 wt% of pure HA) in the p-HA/PLLA composite microspheres. The microstructure of composite microspheres from core-shell to single phase changed with the variation of p-HA to PLLA ratios. p-HA/PLLA composite microspheres with the diameter range of 2–3 μm were obtained. The entrapment efficiency of p-HA in microspheres could high up to 90 wt% and that of HA was only 13 wt%. Surface and bulk characterizations of the composite microspheres were performed by measurements such as wide angle X-ray diffraction (WAXD), thermal gravimetric analysis (TGA), environmental scanning electron microscope (ESEM) and transmission electron microscopy (TEM).     

量子点@SiO_2微球的水相合成及其在流式分析技术中的应用

通过表面配体交换将巯基硅烷包覆在量子点(QDs)表面,并与过量的硅烷共水解制备出包覆QDs的荧光硅球。该方法通过化学键合避免了QDs的泄露以及QDs荧光性质的改变,而且微球表面富集大量的巯基,为后续的反应提供活性位点。研究了反应时间、温度和搅拌速度对荧光微球形成的影响,优化条件得到了尺寸均一、单分散性的荧光微球。将荧光微球用于流式细胞分析检测,微球的数量和荧光强度能够满足流式分析检测的需要,适合制备成编码微球。     

Application of magnetic poly(styrene-glycidyl methacrylate) microspheres for immunomagnetic separation of bone marrow cells

Surface-functionalized magnetic poly(styrene-glycidyl methacrylate) (PS-GMA) microspheres were prepared and coupled with Sca-1 antibody for cell selection from murine bone marrow mononuclear cells (MNCs). Biotinylated Sca-1 antibody could be directly coupled to avidin-bound magnetic microspheres. Alternatively, oxidized goat anti-mouse antibody was covalently bound onto the amino group-containing magnetic microspheres in a site-directed manner, and the resultant conjugate was coupled with non-modified Sca-1 antibody. Using the indirect antibody-bound magnetic microspheres, the purity of isolated Sca-1⁺ cells increased with bead-to-cell ratio. Using a bead-to-cell ratio of 10 beads/cell, a purity of 85% Sca-1⁺ cells corresponding to a 17-fold enrichment was achieved.