半刚性钢框架的内力分析

采用二阶非线性分析方法分析和设计半刚性钢框架，包括连接的柔性以及构件的几何非线性的影响，提出了半刚性钢框架中梁柱单元刚度矩阵和半刚性梁的单元刚度矩阵；推导了半刚性梁在集中荷载，均布荷载，线性荷载作用下的固端弯矩的求解公式；连接的柔性对无支撑框架的侧移有很大的影响，设计时通过变化连接的刚度以平衡梁的跨中和端弯矩。     

金属基复合材料单向和循环变形行为的数值模拟研究

利用晶体细观力学模型，依据组元材料的单晶体变形性质，以Ａｌ－Ａｌ２Ｃｕ自生复合材料为模型材料，用数值法模拟其拉伸和循环拉伸变形过程，得到了与有关实验结果相符的应力－应变曲线，研究了增强相间距和循环加载过程对复合材料变形行为的影响，通过考虑变形过程中组元相及其界面的应力分布规律，分析研究了循环变形过程中基体Ｂａｕｓｃｈｉｎｇｅｒ效应对于复合材料微观变形与损伤机制的作用，结果表明，晶体细观力学模拟计算     

容量矩阵法在涡方法中的应用

本文将容量矩阵技术与快速Fourier变换相结合求解非矩形域的Poisson方程,再与格子涡方法相结合,发展了一套求解复杂外形的快速涡方法。作为算例,计算了有厚度平板和楔形体的分离流动,得到了满意的结果。特别是在垂直平板绕流中,模拟出了由于剪切层不稳定性引起的小涡结构。     

改进的小损伤结构动力学有限元建模方法

在遗传算法或神经网络方法识别结构损伤位置和程度时,都是基于少量的在线测量的损伤结构振动响应数据和大量的模型仿真数据来实现的,因而建立高效和精确的损伤结构动力学有限元模型,以便仿真获得损伤结构的大量动力学响应数据是十分重要的基础前提工作。本文针对ANSYS结构分析软件在建立结构小损伤有限元动力学模型存在两个关键问题,结构损伤处直接网格划分的计算结果误差和网格节省问题,以结构损伤振动检测的实际需要为出发点,提出了建立含小损伤结构的ANSYS动力学建模技术,研究了结构局部小损伤及其位置与所在处单元刚度矩阵变化的数量关系。     

Influence of relative humidity and loading frequency on the PA6.6 thermomechanical cyclic behavior: Part II. Energy aspects

In this study, we investigated the influence of relative humidity (RH) and loading rate on the energy response of PA6.6 matrix specimens. The latter were subjected to oligocyclic tensile-tensile tests at 3 different RH and 2 loading rates. Infrared thermography was used to obtain a direct estimate of heat sources using the heat diffusion equation. Using the mechanical and thermal responses discussed in the first part of this work, complete energy rate balances were drawn up. In particular, the time courses of deformation, and dissipated and stored energy rates are discussed. The strong influence of the loading frequency and RH on the energy storage mechanisms is also highlighted.     

预裂化理论研究:基质表面酸性位类型及不同类型酸性位接触顺序对裂化过程小分子烯烃收率的影响

在区分氢负离子转移反应与氢转移反应、非选择性氢转移反应与总的氢转移反应的情况下,通过合成物性相近但酸性不同的氧化铝,用以作为裂化催化剂基质材料,在固定床反应器上考察了催化裂化过程,基质酸性位类型及基质表面Lewis及Brönsted酸性位接触顺序对小分子烯烃(丙烯、丁烯)收率的影响。结果表明,催化裂化生成小分子烯烃过程中,分子筛与基质所呈现出的反应特点存在较大的区别,前者活性虽高,但总的氢转移反应活性过强。基质材料裂化活性虽低但其表面以氢负离子转移反应为主,反应路径角度更有利于小分子烯烃收率的提高。另外,基质表面存在Brönsted酸性位,或原料油首先与基质表面Lewis酸性位相接触再与Brönsted酸性位反应的预裂化过程,会在促进裂化反应发生的同时抑制总的氢转移反应,更有利于小分子烯烃收率的提高。     

Environmental effects on fibre reinforced polymeric composites: Evolving reasons and remarks on interfacial strength and stability

The interface between fibre and matrix of fibrous polymeric composites is most critical and decisive in maintaining sustainability, durability and also reliability of this potential material, but unfortunately a comprehensive conclusion is yet to meet the label of confidence for the engineering viability. Fiber reinforced polymer (FRP) composites are being accepted and also utilized as better and reliable alternative materials for repairing and/or replacing conventional materials, starting from tiny objects to mega structure in various engineering applications. The promise and potential of these materials are sometimes threatened in speedy replacement of conventional materials because of their inhomogeneities and inherent susceptibility to degradation due to moist and thermal environments. Environmental conditioning is traditionally believed to be a physical phenomenon but present literature has revealed that the interdiffusion between fiber and polymer matrix resin comprises of physical, chemical, mechanical, physico-chemical and mechano-chemical phenomena. The failure and fracture behavior at ambient conditions itself is a complex phenomenon till at present. The service conditions which are mostly hygrothermal in nature, along with a variation of applied loads make the mechanical behavior nearly unpredictable, far off from conclusions in evaluating the short term as well as long term durability and reliability of FRPs. It is essential to accurately simulate the initial and subsequent evolution process of this kind of damage phenomena, in order to explore the full potential of the mechanical properties of composite laminates. The present review has emphasized the need of complying scattered as well as limited literature on this front, and has focused on creating the urgency to highlight the importance of judicious uses of these materials with minimum safety factors with an aim to achieving lighter weight in enhancing specific properties.     

Tutorial review on validation of liquid chromatography–mass spectrometry methods: Part I

This is the part I of a tutorial review intending to give an overview of the state of the art of method validation in liquid chromatography mass spectrometry (LC–MS) and discuss specific issues that arise with MS (and MS/MS) detection in LC (as opposed to the “conventional” detectors). The Part I briefly introduces the principles of operation of LC–MS (emphasizing the aspects important from the validation point of view, in particular the ionization process and ionization suppression/enhancement); reviews the main validation guideline documents and discusses in detail the following performance parameters: selectivity/specificity/identity, ruggedness/robustness, limit of detection, limit of quantification, decision limit and detection capability. With every method performance characteristic its essence and terminology are addressed, the current status of treating it is reviewed and recommendations are given, how to determine it, specifically in the case of LC–MS methods.