Mathematical Modelling of Glyphosate Molecularly Imprinted Polymer-Based Microsensor with Multiple Phenomena

The massive and careless use of glyphosate (GLY) in agricultural production raises many questions regarding environmental pollution and health risks, it is then important to develop simple methods to detect it. Electrochemical impedance spectroscopy (EIS) is an effective analytical tool for characterizing properties at the electrode/electrolyte interface. It is useful as an analytical procedure, but it can also help in the interpretation of the involved fundamental electrochemical and electronic processes. In this study, the impedance data obtained experimentally for a microsensor based on molecularly imprinted chitosan graft on 4-aminophenylacetic acid for the detection of glyphosate was analyzed using an exact mathematical model based on physical theories. The procedure for modeling experimental responses is well explained. The analysis of the observed impedance response leads to estimations of the microscopic parameters linked to the faradic and capacitive current. The interaction of glyphosate molecules with the imprinted sites of the CS-MIPs film is observed in the high frequency range. The relative variation of the charge transfer resistance is proportional to the log of the concentration of glyphosate. The capacitance decreases as the concentration of glyphosate increases, which is explained by the discharging of the charged imprinted sites when the glyphosate molecule interacts with the imprinted sites through electrostatic interactions. The phenomenon of adsorption of the ions in the CMA film is observed in the low frequency range, this phenomenon being balanced by the electrostatic interaction of glyphosate with the imprinted sites in the CS-MIPs film.     

甲烷部分氧化制合成气的钙钛矿型致密透氧膜反应器的数值模拟(英文)

采用等温理论模型,以甲烷催化氧化制合成气为模型反应,模拟非担载钙钛矿型致密透氧膜反应器的性能。分别研究了Ｌａ_０．２Ｂａ_０．８Ｆｅ_０．８Ｃｏ_０．２Ｏ_(３－δ)、Ｌ３０．２Ｓｒ０．８Ｆｅ０．８Ｃｏ０．２Ｏ３－δ和ＳｒＦｅＣｏ０．５Ｏｘ三种透氧速率不同的膜材料、膜反应器的尺寸以及反应工艺条件对ＣＨ４转化率、ＣＯ选择性和Ｈ２／ＣＯ摩尔比的影响,对膜反应实验具有指导意义。     

数理统计在地球化学样品分析质量控制中的应用

使用Excel2013和Minitab两种常用软件对地球化学样品中CaO含量分布情况进行了研究,运用描述性统计、正态分布、背景值与异常方法对实验室分析的广西某地地球化学样品的分析数据进行了质量评价,结果表明:综合运用计算机软件和数理统计方法,能快速找到分析数据的详细信息和数据特征,判别地球化学样品实验室分析数据的准确性,找出元素的背景值和异常值并剔除异常值,比较发现,样品中CaO含量分析数据对数转换后比原始数据的分布更趋于正态分布,相比于X射线荧光光谱方法,用电感耦合等离子体发射光谱法测定的结果更符合正态分布。方法对地球化学调查样品的分析数据质量评价作了有益的尝试,揭示了数理统计方法是地球化学样品分析质量控制的有效手段。     

复杂边界条件下渗流场流线分布研究

流线分布研究已受到油藏工程师们的普遍关注。本文从无限大油藏稳态渗流场基本解出发,结合边界元方法求解出复杂边界条件下稳态渗流场的势分布,以此为基础提出了流线场的生成办法,并给出了应用实例。本文方法的优点在于求解过程中将问题的维数降低了一维,减少了计算量;计算精度较高且具有一定的普遍应用性;适应于求解任意形状的包括定压、定流量或混合边界在内的组合边界问题。实例表明,利用本文方法产生的流线分布因能够较为直观地反映出油藏流体在注采井间的运动轨迹,为优化井网和注入方案提供了重要依据。     

数学建模活动对培养人才的作用

文章论述建模活动对培养人才的作用 ,对专科院校高等数学教学改革具有启发性 .     

中医方药量化研究中“相对药量”的数学模型体系

建立中医方药量华研究的"相对药量"概念模型体系;方法:运用微分方程理论;提出五种情况下,中药常用量范围内相对药量概念的数学模型,分别为直线模型、指数函数模型、对数函数模型、二次函数模型(开口向上和向下两种),并说明该模型体系的和理性与适应性;结论:相对药量概念核心体系的建立,增加了中医方药"相对药量"可比性的全面性,这对进一步研究单位药乃至方剂中各药在性、味、归经等方面的影响程度及其规律性,将起到至关重要的作用.     

从对比中更好地把握微积分的教学改革

美国微积分教学改革的许多方面值得借鉴.从对比的角度反思微积分教改的不足和差距,以便更好地把握今后的教改工作,明确在点点滴滴的教学过程中,应当实实在在地做些什么、怎么做.     

数学建模思维方法论

数学建模过程是一个复杂的思维过程,全国大学生数学建模竞赛又加以竞赛的形式,有其特殊性,其中如何研究问题、如何做出成果、如何争取获奖,本文探讨其思维规律、方法技巧.     

Chemometric Optimization of Biologically Active Compounds Extraction from Grape Marc: Composition and Antimicrobial Activity

The article focuses on the optimization of the extraction process of biologically active compounds (BAC) from grape marc—a by-product of the wine industry. The influence of temperature, specifically 30 °C, 45 °C and 65 °C, and ethanol concentration in solutions, specifically 0–96% (v/v) on the extraction yield of polyphenols, flavonoids, tannins and anthocyanins, were investigated. The composition of individual polyphenols, anthocyanins and organic acids, antioxidant activity (DPPH and ABTS) and CIELab chromatic characteristics of the grape marc extracts (GME), were characterized. The microbiostatic and microbicidal effects in direct contact of GME with pathogenic microorganisms, Bacillus subtilis, Staphylococcus aureus, Escherichia coli, Klebsiella pneumoniae, were determined in vitro. The influence of extraction parameters on the total polyphenol content (TPC), total flavonoid content (TFC), tannin content (TC), total anthocyanin content (TAC) and their interdependencies were studied using information analysis. A mathematical model was developed on cubic spline functions. The analysis of individual compounds showed the presence of a wide range of flavonoids (procyanidin B2, procyanidin B1, hyperoside and quercetin), flavones (catechin), hydroxybenzoic acid derivatives (gallic, protocatechuic, p-hydroxybenzoic acids, m-hydroxybenzoic acid, syringic acid), hydroxycinic acid derivatives and ferulic acid methyl ester. The malvidol-3-glucoside was the main anthocyanin identified in the extract. A high amount of tartaric acid was also found. GME showed significant antimicrobial activity against Gram-positive bacteria and lower activity against Gram-negative bacteria.