全球治理困境与国家“再现”的最终逻辑

在全球治理危机频现和大国战略竞争加剧的背景下,“国家中心主义”回归引发了人们对经济全球化走势的担忧。本轮国家中心主义回归的逻辑是：此前自由主义全球化的过度发展导致国家功能隐退;而当全球治理状况恶化时,国家的重要性再度凸现,成为各国社会谋求自我体系安全的唯一“阀门”,民族主义、保护主义思潮亦大行其道。从中期看,未来的全球体系重建过程将充满国家中心主义与自由主义两种理性的持续角力,国家与市场的作用都将在“拉锯战”相互影响与重塑。从远期看,新型全球化将是国家与市场关系再平衡的产物,国家仍是兼具服务本民族发展及其外部性的主要工具。国家处理内外发展与治理多重挑战的“灵活度”即为评判其核心竞争力的最终标准。     

聚氨酯结构与径向分布的分子动力学模拟

采用分子动力学方法计算得到DHI-乙烯醇聚合体系统的结构和径向分布函数.讨论了系统结构和径向分布函数与温度和压力之间的关系.结果表明粘合系统的空间分布一般地随着温度和压力的增加而收窄,对增加聚氨酯系统的粘合性具有积极的意义.     

Impulsive control of nonlinear systems with time-varying delays

A whole impulsive control scheme of nonlinear systems with time-varying delays, which is an extension for impulsive control of nonlinear systems without time delay, is presented in this paper. Utilizing the Lyapunov functions and the impulsive-type comparison principles, we establish a series of different conditions under which impulsively controlled nonlinear systems with time-varying delays are asymptotically stable. Then we estimate upper bounds of impulse interval and time-varying delays for asymptotically stable control. Finally a numerical example is given to illustrate the effectiveness of the method.     

复Clifford分析中的超单演函数

该文研究复Clifford分析中的超单演函数,即方程z_n Df(z)+(n-1)Qf′=0的解. 记f(z)=Pf(z)+Qf(z)e_n,f(z)∈C^2(Ω),f(z): Ω → C^{n+1},Ω C^{n+1}，得出超单演函数的几个性质.     

空位对纤锌矿型AlN自发极化影响的最大局域化Wannier函数方法研究

采用基于密度泛函理论的第一性原理平面波超软赝势方法,计算了纤锌矿型AlN中引入不同电荷态的N空位和Al空位时结构中最大局域化Wannier函数,并根据Wannier函数的空间分布及空间分布的几何中心位置,对空位引起的晶体电子结构变化及[0001],[ˉ1010],[ˉ12ˉ10]晶向上的自发极化进行了研究.结果表明,利用最大局域化Wannier函数分析电子结构具有直观的特点,清晰地表明N—Al键具有较强的离子性.研究发现,N空位结构中悬挂键上电荷向空位处转移,而Al空位结构中悬挂键上电荷则远离空位,沿悬挂键方向移动到N原子一侧.同时发现,空位的引入破坏了[ˉ1010],[ˉ12ˉ10]晶向上的中心对称结构,产生了极化,且极化强度随着空位电荷态的增加而增大.在[0001]晶向上,随着N空位电荷态的增加,空位周围电子结构发生了剧烈变化,使得自发极化发生了逆转,极化强度随着电荷态的增加而增大;而在Al空位中,随着电荷态的增加,自发极化沿原方向显著增加,但没有发生极化反转.     

Asymptotic expansions of Kummer hypergeometric functions with three asymptotic parameters a,b and z

In a recent paper (Temme, 2021) new asymptotic expansions are given for the Kummer functions $M(a,b,z)$ and $U(a,b+1,z)$ for large positive values of $a$ and $b$, with $z$ fixed and special attention for the case $a～b$. In this paper we extend the approach and also accept large values of $z$. The new expansions are valid when at least one of the parameters $a$, $b$, or $z$ is large. We provide numerical tables to show the performance of the expansions.     

Optimal uniform approximation on angles by entire functions

The paper discusses the best or optimal uniform approximation problem by entire functions on a closed angle Δ. This problem has been studied by M.V. Keldysch in [4], under the assumption that the functions ? subject to approximation are holomorphic in a larger angle containing Δ and there is no restriction on the growth of ? at infinity. In [8], the problem was investigated for a wider class of functions ? continuously complex differentiable on Δ, with sharper estimates on the growth of approximating entire functions, linked with the growth of ? on Δ and the differential properties of ? on the boundary of Δ. In this paper, we improve some of the results on entire approximation on angles, using new approximation ideas partially presented in [9] and [10].     

Trace formulas for additive and non-additive perturbations

Trace formulas for pairs of self-adjoint, maximal dissipative and accumulative as well as other types of resolvent comparable operators are obtained. In particular, the existence of a complex-valued spectral shift function for a pair {H^′,H}$\{H^{\prime },H\}$ of maximal accumulative operators has been proved. We investigate also the existence of a real-valued spectral shift function. Moreover, we treat in detail the case of additive trace class perturbations. Assuming that H   and H^′=H+V$H^{\prime }=H+V$ are maximal accumulative and V is trace class, we prove the existence of a summable   complex-valued spectral shift function. We also obtain trace formulas for pairs {H,H^?}$\{H,H^{?}\}$assuming only that H and  H^?$H^{?}$are resolvent comparable. In this case the determinant of the characteristic function of H is involved in trace formulas.     

Relevance between the Chemical Structure Modifications and Physicochemical Descriptors of Chemical Reactivity for Series of Nitroxide Radicals

This work presents an experimental and theoretical study to address the chemical reactivity of series of nitroxide radicals. For that purpose two physicochemical properties: the half-wave potential and the hyperfine coupling constants of the nitrogen nuclei, were analyzed. Experimental values are compared with electronic structure calculations at the BHandHLYP/6-311++G(2d,2p) level. E_1/2 values were in good agreement with the adiabatic ionization potential when including the solvent effects by the Cramer and Truhlar Solvation Model. Preeliminar experimental electron spin deslocalization studies suggest that structural hindrance plays an important role in their deslocatization mechanism.