Solution calorimetry of organic nonelectrolytes as a tool for investigation of intermolecular interactions

The paper is mainly the review and generalization of the previous publications of the authors. It demonstrates that solution calorimetry method gives the opportunities of more detailed understanding of various aspects of intermolecular interactions in solution. We are assured that prerequisite to such an understanding is the successive analysis of various solute–solvent systems from the simplest ones which include alkanes as a solute or as a solvent to the most complex systems with solvent self‐association via hydrogen bonding. Particular findings discussed in this paper are (i) an inconspicuous contribution of electrostatic solute–solvent interaction to the solvation enthalpy and, accordingly, the dominating contribution of dispersion interactions for nonspecifically solvated solutes; (ii) new, very general method for the extraction of specific interaction enthalpy from the enthalpy of solvation; (iii) new method of determination of self‐association enthalpies for the solvents associated via hydrogen bonding; (iv) new method for determination of cooperative hydrogen bonding enthalpies of proton acceptors with associated species of alcohols; (v) the unique method of experimental determination of the hydrophobic effect enthalpy. Copyright © 2007 John Wiley & Sons, Ltd.     

开挖过程的非线性理论分析

本文从岩土介质力学非线性和变形破坏过程自组织非线性的角度对开挖过程岩土体非线性行为进行了探讨。以此为依据,分析了岩土从微观破坏、滑移面形成、直至整体变形破坏全过程的自组织发生机理,在此基础上,建立了伴随开挖过程岩土体变形破坏的非线性动力学描述方程。     

Entire functions, analytic continuation, and the fractional parts of a linear function

The main result of the paper is as follows.Theorem. Suppose that G(z) is an entire function satisfying the following conditions: 1) the Taylor coefficients of the function G(z) are nonnegative: 2) for some fixed C>0 and A>0 and for |z|>R₀, the following inequality holds:

Low Rank Approximation of a Hankel Matrix by Structured Total Least Norm

The structure preserving rank reduction problem arises in many important applications. The singular value decomposition (SVD), while giving the closest low rank approximation to a given matrix in matrix L ₂ norm and Frobenius norm, may not be appropriate for these applications since it does not preserve the given structure. We present a new method for structure preserving low rank approximation of a matrix, which is based on Structured Total Least Norm (STLN). The STLN is an efficient method for obtaining an approximate solution to an overdetermined linear system AX B, preserving the given linear structure in the perturbation [E F] such that (A + E)X = B + F. The approximate solution can be obtained to minimize the perturbation [E F] in the L _p norm, where p = 1, 2, or . An algorithm is described for Hankel structure preserving low rank approximation using STLN with L _p norm. Computational results are presented, which show performances of the STLN based method for L ₁ and L ₂ norms for reduced rank approximation for Hankel matrices.     

M-estimators of structural parameters in pseudolinear models

Real valued M-estimators in a statistical model 1 with observations are replaced by -valued M-estimators in a new model with observations where are regressors, is a structural parameter and a structural function of the new model. Sufficient conditions for the consistency of are derived, motivated by the sufficiency conditions for the simpler parent estimator The result is a general method of consistent estimation in a class of nonlinear (pseudolinear) statistical problems. If F has a natural exponential density e^{x–b( x )} then our pseudolinear model with u = (g o )^–1 reduces to the well known generalized linear model, provided () = db()/d and g is the so-called link function of the generalized linear model. General results are illustrated for special pairs and leading to some classical M-estimators of mathematical statistics, as well as to a new class of generalized -quantile estimators.     

Oscillation and Nonoscillation Criteria for a Second Order Linear Equation

New oscillation and nonoscillation criteria are established for the equation

On the Dirichlet Problem in a Characteristic Rectangle for Fourth Order Linear Singular Hyperbolic Equations

In the rectangle D = (0,

On oscillatory solutions of fourth order ordinary differential equations

The paper deals with the oscillation of a differential equation L ₄ y + P(t)L ₂ y + Q(t)y 0 as well as with the structure of its fundamental system of solutions.     

A Characterization of Projective Spaces by a Set of Planes

This note deals with the following question: How many planes of a linear space (P, $\mathfrak{L}$ ) must be known as projective planes to ensure that (P, $\mathfrak{L}$ ) is a projective space? The following answer is given: If for any subset M of a linear space (P, $\mathfrak{L}$ ) the restriction (M, $\mathfrak{L}$ )(M)) is locally complete, and if for every plane E of (M, $\mathfrak{L}$ (M)) the plane $\bar E$ generated by E is a projective plane, then (P, $\mathfrak{L}$ ) is a projective space (cf. 5.6). Or more generally: If for any subset M of P the restriction (M, $\mathfrak{L}$ (M)) is locally complete, and if for any two distinct coplanar lines G1, G2 ∈ $\mathfrak{L}$ (M) the lines $\bar G_1 ,\bar G_2 \varepsilon \mathfrak{L}$ generated by G1, G2 have a nonempty intersection and $\overline {G_1 \cup {\text{ }}G_2 }$ satisfies the exchange condition, then (P, $\mathfrak{L}$ ) is a generalized projective space.     

A Characterization of Some Minihypers and its Application to Linear Codes

Any {f,r- 2+s; r,q}-minihyper includes a hyperplane in PG(r, q) if fr-1 + s 1 + q – 1 for 1 s q – 1, q 3, r 4, where i = (qi + 1 – 1)/ (q – 1 ). A lower bound on f for which an {f, r – 2 + 1; r, q}-minihyper with q 3, r 4 exists is also given. As an application to coding theory, we show the nonexistence of [ n, k, n + 1 – qk – 2 ]q codes for k 5, q 3 for qk – 1 – 2q – 1 < n qk – 1 – q – 1 when k > q – q - \sqrt q + 2$$ " align="middle" border="0"> and for when , which is a generalization of [18, Them. 2.4].