萘酞菁铅化合物的光限幅特性研究

应用调Q倍频ns/ps Nd：YAG脉冲激光,在波长为532nm,脉冲宽度为8ns,重复频率为1Hz的条件下,研究了溶于二甲基亚砜(DMSO)中的萘酞菁铅溶液的反饱和吸收和光限幅特性。实验表明,萘酞菁铅具有良好的光限幅特性,它的有效激发态吸收截面与基态吸收截面的比值约为15．21,大于萘酞菁铜。研究结果表明,萘酞菁铅的光限幅特性优于C60,激发态吸收是其主要的光限幅机理。实验结果证实了重原子效应可以通过增强系际跃迁而使三重态的反饱和吸收增强,从而提高光限幅的能力。     

Studies on two coordination polymers [M(μ4-pz25dc)]n (M = Cd or Zn, pz25dc = pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties

Two isomorphous new candidates [M(μ₄-pz25dc)]_n (M = Cd, 1; Zn, 2; pz25dc = pyrazine-2,5-dicarboxylato) for nonlinear optical (NLO) materials have been synthesized hydrothermally and characterized crystallographically as pillared-layer three-nodal frameworks with one four-connected metal nodes and two crystallographically different four-connected ligand nodes. Their optical non-linearities are measured by the z-Scan technique with an 8 ns pulsed laser at 532 nm. These two coordination polymers both exhibit strong NLO absorptive abilities [α₂ = (63 ± 6) × 10⁻¹² m W⁻¹1, (46 ± 6) × 10⁻¹¹ m W⁻¹2] and effective self-focusing performance [n₂ = (67 ± 5) × 10⁻¹⁸1, (13 ± 3) × 10⁻¹⁸ m² W⁻¹2] in 1.02 × 10⁻⁴1 and 1.05 × 10⁻⁴ mol dm⁻³2 DMF solution separately. The values of the limiting threshold are also measured from the optical limiting experimental data. The heavy atom effect plays important role in the enhancement of optical non-linearities and optical limiting properties.     

Reverse saturable absorption in nano colloidal Ge28Sb12Se60 chalcogenide glass

We report the preparation and investigation of nano colloidal solutions of Ge₂₈Sb₁₂Se₆₀ chalcogenide glass based on nonlinear optical transmission by the open-aperture Z-scan technique, using nanosecond laser pulses, at the excitation wavelengths of 532 nm. The Z scan spectra reveal a strong non linear absorption (reverse saturable absorption) for the nano colloid Ge₂₈Se₆₀Sb₁₂ solutions. Observation of optical limiting at excitation wavelength suggests the potential of these materials to be used as optical limiters.     

Asymptotic distributions of non-central studentized statistics

Let X1,...,Xn be independent and identically distributed random variables and Wn = Wn(X1,...,Xn) be an estimator of parameter θ.Denote Tn =(Wn - θ0)/sn,where sn2 is a variance estimator of Wn.In this paper a general result on the limiting distributions of the non-central studen-tized statistic Tn is given.Especially,when s2n is the jacknife estimate of variance,it is shown that the limit could be normal,a weighted χ2 distribution,a stable distribution,or a mixture of normal and stable distribution.Applicati...     

A note on incremental equations for a new class of constitutive relations for elastic bodies

Some new classes of constitutive relations for elastic bodies have been proposed in the literature, wherein the stresses and strains are obtained from implicit constitutive relations. A special case of the above relations corresponds to a class of constitutive equations where the linearized strain tensor is given as a nonlinear function of the stresses. For such constitutive equations we consider the problem of decomposing the stresses into two parts: one corresponds to a time-independent solution of the boundary value problem, plus a small (in comparison with the above) time-dependent stress tensor. The effect of this initial time-independent stress in the propagation of a small wave motion is studied for an infinite medium.     

Experimental and numerical analyses of high voltage 4H-SiC junction barrier Schottky rectifiers with linearly graded field limiting ring

This paper describes the successful fabrication of 4H-SiC junction barrier Schottky(JBS) rectifiers with a linearly graded field limiting ring(LG-FLR). Linearly variable ring spacings for the FLR termination are applied to improve the blocking voltage by reducing the peak surface electric field at the edge termination region, which acts like a variable lateral doping profile resulting in a gradual field distribution. The experimental results demonstrate a breakdown voltage of 5 kV at the reverse leakage current density of 2 mA/cm2(about 80% of the theoretical value). Detailed numerical simulations show that the proposed termination structure provides a uniform electric field profile compared to the conventional FLR termination, which is responsible for 45% improvement in the reverse blocking voltage despite a 3.7% longer total termination length.     

MoS_2溶液的波长选择性光限幅效应研究

采用N,N-二甲基甲酰胺(DMF)和四氢呋喃(THF)为溶剂,用离散法制备二硫化钼(MoS2)悬浮溶液,并用开孔Z扫描方法研究其在可见和近红外区域的非线性光学特性.结果显示,在强激光照射下,MoS2(in THF)悬浮溶液在可见波段(530 nm)透过率增强为常光透过率的1.54倍,表现为饱和吸收;在近红外波段(790 nm)透过率减弱为常光透过率的0.6倍,表现为反饱和吸收,具有很好的波长选择性光限幅效应.而作为对比的MoS2(in DMF)悬浮溶液在全波段透过率降低,呈现反饱和吸收特性,波长选择性不明显.机理解释可能为饱和吸收和热效应导致的自衍射两种机制联合作用.     

关于熵数、非紧性的测量和插值的一些注记(英文)

本文综述了关于熵数和非紧性的测量的插值性质,本文也描述了经典结果及几个非常新的结果。     

上转换太阳电池的数值模拟

采用细致平衡原理,将太阳,环境作为辐射体,只考虑电池辐射复合,建立了太阳电池的模型。通过模拟,得出单结太阳电池的极限效率为31%,当使用上转换器时,单结电池的极限效率增至47.3%;对于双结电池,当顶电池带隙宽度为1.7 eV,底电池带隙宽度从1.1 eV变化到1.5 eV,模拟的最大效率为39.9%,有上转换器最大时效率提高到了47.4%。     

Fullerene Derivatives Embedded in Hybrid Sol-Gel Glasses: Nonlinear Optical Properties and Optical Limiting Performances

Hybrid organic-inorganic materials are investigated as suitable materials for inclusion of fullerene derivatives and for fabrication of laser protection devices. A specific synthesis has been developed in order to optimize non-linear optical performances of fullerene derivatives. 3-glicydoxypropyltrymethoxysilane has been used as an inorganic and organic network former to obtain the host material. The sol-gel synthesis consists of the hydrolysis and condensation in acidic conditions of the inorganic network. Epoxy polymerization has been achieved by using zirconium or BF₃ alkoxides precursors. Bulk and multilayer materials doped with a fullerene derivative have been fabricated. They show good optical requirements: high fullerenes concentration, high microstructural homogeneity, high laser damage threshold and high optical limiting efficiency. Optical limiting (OL) mechanisms have been investigated. The most effective in the sol-gel materials is the reverse saturable absorption (RSA) one. However, different mechanisms, like non-linear (NL) scattering and NL refraction contribute to a different extent. Open- and closed-aperture OL and z-scan measurements on sol-gel samples show the contribution of NL scattering and NL refraction at 690 nm. Laser damage threshold has been characterized as a function of the structure of the samples and of the optical configurations (f/66 and f/5).