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171.
A triangular lattice model for pattern formation by core-shell particles at fluid interfaces is introduced and studied for the particle to core diameter ratio equal to 3. Repulsion for overlapping shells and attraction at larger distances due to capillary forces are assumed. Ground states and thermodynamic properties are determined analytically and by Monte Carlo simulations for soft outer- and stiffer inner shells, with different decay rates of the interparticle repulsion. We find that thermodynamic properties are qualitatively the same for slow and for fast decay of the repulsive potential, but the ordered phases are stable for temperature ranges, depending strongly on the shape of the repulsive potential. More importantly, there are two types of patterns formed for fixed chemical potential—one for a slow and another one for a fast decay of the repulsion at small distances. In the first case, two different patterns—for example clusters or stripes—occur with the same probability for some range of the chemical potential. For a fixed concentration, an interface is formed between two ordered phases with the closest concentration, and the surface tension takes the same value for all stable interfaces. In the case of degeneracy, a stable interface cannot be formed for one out of four combinations of the coexisting phases, because of a larger surface tension. Our results show that by tuning the architecture of a thick polymeric shell, many different patterns can be obtained for a sufficiently low temperature. 相似文献
172.
ABSTRACT The microstructure evolution and property change of four kinds of low silicon cast aluminum alloy exposed to heat for 0–50?h at 200°C were studied by means of Brinell hardness test, tensile property test, friction and wear property test and XRD analysis. The results show that with increasing thermal exposure time, the tensile strength of each group of samples decreased and the amount of wear increased. The tensile strength of samples with more Si content decreased slowly. When the time increased to 50?h, the increase of wear loss was the largest. The hardness of samples after thermal exposure increases compared with that before thermal exposure. The residual stress of (311) diffraction crystal surface of AlSi3.5Mg0.66 under different thermal exposure time was measured. The type of residual stress changed from residual tensile stress to residual compressive stress after thermal exposure. There is an abnormal phenomenon that the hardness of the sample increased and the amount of wear increased, and it is evident that the distribution of residual stress was inhomogeneous after thermal exposure. It is found that with increasing thermal exposure time to 50?h, the average lattice distortion ε of the low-index crystal plane and the high-index crystal plane in the aluminum alloys gradually increased. 相似文献
173.
Panpan Xue Guang-Liang Li Junpeng Cao Kun Hao Tao Yang Wen-Li Yang Kangjie Shi 《理论物理通讯》2020,72(1):15001
New integrable B_2 model with off-diagonal boundary reflections is proposed. The general solutions of the reflection matrix for the B_2 model are obtained by using the fusion technique. Wefind that the reflection matrix has 7 free boundary parameters, which are used to describe the degree of freedom of boundary couplings, without breaking the integrability of the system. The new quantization conditions will induce the novel structure of the energy spectrum and the boundary states. The corresponding boundary effects can be studied based on the results in this paper. Meanwhile, the reflection matrix of high rank models associated with Bnalgebra can also be obtained by using the method suggested in this paper. 相似文献
174.
PTC特性的复合导电体系中炭粒子分布的逾渗模型与电阻率的计算 总被引:17,自引:0,他引:17
综述了炭黑填充型导电高分子复合体系的几种导电理论;讨论了导电载流子分布的各种假说及模型;比较了不同模型的理论预测与实验结果的差异性。 相似文献
175.
176.
合成了无水乳酸配合物(NH4)2[Sr(C3H5O3)4]。用X射线单晶衍射仪对该配合物的晶体结构进行了表征,确定了其组成、空间结构和配位方式。绘制了配合物的Hirshfeld表面和2D指纹图,揭示了分子间的相互作用以及该配合物具有多个配位位点和较强的配位活性。根据相关的晶体数据计算出了该配合物的晶格能及其对应阴离子的摩尔体积,计算得到该配合物的晶格能为2742.9 kJ·mol-1。用等温环境反应-溶解量热计测量了该配合物在298 K超纯水溶剂中的溶解焓。根据Pitzer电解质溶液理论,在298 K下获得了该配合物的无限稀释摩尔溶解焓△sHm∞和Pitzer参数,确定该配合物的△sHm∞为(114.01±0.04) kJ·mol-1。计算了该配合物的表观相对摩尔焓(ΦL)以及不同浓度下溶质和溶剂的相对偏摩尔焓(L1和L2)。最后,根据晶格能和△sHm∞设计了热化学循环,并计算出了阴离子的水合焓值。热重和微商热重曲线进一步揭示了该配合物的结构。 相似文献
177.
Yoshio Kobayashi Tsukasa Shirochi Takafumi Maeda Yusuke Yasuda Toshiaki Morita 《Surface and interface analysis : SIA》2013,45(9):1424-1428
This paper describes a metal–metal bonding technique using metallic Cu nanoparticles prepared in aqueous solution. A colloid solution of metallic Cu particles with a size of 54 ± 15 nm was prepared by reducing Cu2+ (0.01 M (CH3COO)2Cu) with hydrazine (0.6 M) in the presence of stabilizers (5 × 10?4 M citric acid and 5 × 10?3 M cetyltrimethylammonium bromide) in water at room temperature in air. Discs made of metallic materials (Cu, Ni/Cu, or Ag/Ni/Cu) were successfully bonded under annealing at 400 °C and pressurizing at 1.2 MPa for 5 min in H2 gas with help of the metallic Cu particle powder. Shear strength required for separating the bonded discs was 27.9 ± 3.9 for Cu discs, 28.1 ± 4.1 for Ni/Cu discs, and 13.8 ± 2.6 MPa for Ag/Ni/Cu discs. Epitaxial crystal growth promotes on the discs with a good matching for the lattice constants between metallic nanoparticles and metallic disc surfaces, which leads to strong bonding. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
178.
合成了四氯合镉酸正十一烷铵配合物(C11H23NH3)2CdCl4(s)[简写: C11Cd(s)]. 用X 射线单晶衍射技术、化学分析和元素分析确定其晶体结构和化学组成. 利用其晶体学数据计算出晶格能为: UPOT=908.18 kJ·mol-1. 利用精密自动绝热热量计测定了它在78~395 K 温区的低温热容, 结果表明, 该配合物在此温区出现两次连续的固-固相转变, 计算出两次相变的峰温、摩尔焓及摩尔熵分别为: Ttrs,1=(321.88±0.07) K, ΔtrsHm,1=(37.59±0.17) kJ·mol-1, ΔtrsSm,1=(117.24±0.12) J·K-1·mol-1, Ttrs,2=(323.81±0.30) K, ΔtrsHm,2=(12.42±0.02) kJ·mol-1 和ΔtrsSm,2=(38.36±0.09) J·K-1·mol-1. 用最小二乘法将实验摩尔热容对温度进行拟合, 得到热容随温度变化的多项式方程. 用此方程进行数值积分,得到此温区每隔5 K 的舒平热容值和相对于298.15 K 时的热力学函数值. 相似文献
179.
180.