全文获取类型
收费全文 | 48804篇 |
免费 | 3112篇 |
国内免费 | 3445篇 |
专业分类
化学 | 20072篇 |
晶体学 | 393篇 |
力学 | 3842篇 |
综合类 | 573篇 |
数学 | 10507篇 |
物理学 | 19974篇 |
出版年
2024年 | 72篇 |
2023年 | 438篇 |
2022年 | 1072篇 |
2021年 | 1064篇 |
2020年 | 1104篇 |
2019年 | 1131篇 |
2018年 | 980篇 |
2017年 | 1138篇 |
2016年 | 1276篇 |
2015年 | 1020篇 |
2014年 | 1606篇 |
2013年 | 2985篇 |
2012年 | 1887篇 |
2011年 | 2098篇 |
2010年 | 1688篇 |
2009年 | 2757篇 |
2008年 | 2989篇 |
2007年 | 3403篇 |
2006年 | 2855篇 |
2005年 | 2241篇 |
2004年 | 1876篇 |
2003年 | 2158篇 |
2002年 | 2572篇 |
2001年 | 1930篇 |
2000年 | 1843篇 |
1999年 | 1553篇 |
1998年 | 1520篇 |
1997年 | 874篇 |
1996年 | 837篇 |
1995年 | 719篇 |
1994年 | 778篇 |
1993年 | 566篇 |
1992年 | 644篇 |
1991年 | 430篇 |
1990年 | 411篇 |
1989年 | 315篇 |
1988年 | 279篇 |
1987年 | 276篇 |
1986年 | 247篇 |
1985年 | 224篇 |
1984年 | 228篇 |
1983年 | 139篇 |
1982年 | 187篇 |
1981年 | 181篇 |
1980年 | 119篇 |
1979年 | 149篇 |
1978年 | 126篇 |
1977年 | 118篇 |
1976年 | 74篇 |
1973年 | 57篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
231.
Reduction of tetranuclear heterometallic complex Mo2Mg2 was simulated using the B3LYP and PBE density functional methods. The results of geometry calculations of the initial complex
[MoVIO2Mg(MeOH)2(OMe)4]2 and a partially reduced MoV complex are in good agreement with experimental data. The reduced MoIII complex is characterized by a decrease in the binding energy of aqua ligands. Structural rearrangement of the complex with
release of a coordination position at the Mo atoms requires small energy expenditure. One can assume that the reduction of
the polynuclear complex causes overcrowding of its coordination sphere, which favors formation of dinitrogen complexes.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 441–457, March, 2008. 相似文献
232.
This paper studies the problem of uniformly dissipative solutions of somefifth order non-linear differential equations by the use of frequency domaintechnique. We use the generalized theorem of Yacubovich on dissipativity toobtain some new sufficient conditions of the existence of solutions that aredissipative for (1.1) and (1.2). 相似文献
233.
Titanium tetrachloride promoted reaction of silyl ketene acetals with epoxides, followed by acidic work-up, affords butanolides in moderate/good yields. With epihalohydrins the reaction is regioselective and occurs at the less substituted end of the epoxide; the γ-haloalkyl-γ-butanolides thus obtained can be further transformed into various products. 相似文献
234.
A new numerical method called linearized and rational approximation method is presented to solve non‐linear evolution equations. The utility of the method is demonstrated for the case of differentiation of functions involving steep gradients. The solution of Burgers' equation is presented to illustrate the effectiveness of the technique for the solution of non‐linear evolution equations exhibiting nearly discontinuous solutions. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
235.
This paper presents the applications of digital image correlation technique to the mesoscopic damage and fracture study of
some granular based composite materials including steelfiber reinforced concrete, sandstone and crystal-polymer composite.
The deformation fields of the composite materials resulted from stress localization were obtained by the correlation computation
of the surface images with loading steps and thus the related damage prediction and fracture parameters were evaluated. The
correlation searching could be performed either directly based on the gray levels of the digital images or from the wavelet
transform (WT) coefficients of the transform spectrum. The latter was developed by the authors and showed higher resolution
and sensitivity to the singularity detection. Because the displacement components came from the rough surfaces of the composite
materials without any coats of gratings or fringes of optical interferometry, both surface profiles and the deformation fields
of the composites were visualized which was helpful to compare each other to analyze the damage of those heterogeneous materials.
The project supported by the National Natural Science Foundation of China (10125211 and 10072002), the Scientific Committee
of Yunnan Province for the Program of Steel Fiber Reinforced Concrete, and the Institute of Chemical Materials, CAEP at Mianyang 相似文献
236.
237.
Triterpenoid Constituents of Huperzia miyoshiana 总被引:1,自引:0,他引:1
Thirteen triterpenoids, including three new ones, miyoshianois A (1), B (2) and C (3), were isolated from Huperzia miyoshiana. The structures of these new compounds were established as 3-O-dihydroferuloyltohogenol (1), 16-oxo-3β,21β-dihydrox-y-serrat-14-en-24-ferulate (2) and 16-oxo-3a, 21β-dihydroxy-serrat-14-en-24-ferulate (3), respectively, on the basis of their spectroscopic analysis. 相似文献
238.
S. F. Chekmarev R. Mitri V. Bonaci-Koutecký 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):45-48
The ab initio molecular
dynamics (AIMD) [1] is combined with the heuristic, successive
confinement method of surveying a potential energy surface (PES)
[2], thereby offering a framework for the simulation study of
kinetics and equilibrium properties of metallic clusters. This
approach is applied to the study of Au4,
a cluster possessing a simple but specific PES, which consists
of very shallow and deep basins and due to this presents a
challenge to the conventional AIMD methods. Among other things,
the probabilities of the transitions between isomers have been
found, and on this basis, both the time-dependent and
equilibrium populations of the isomers have been calculated for
the conditions typical of the NeNePo experiments [3] in the
femtosecond pump-probe spectroscopy. 相似文献
239.
In this paper, we introduce a phenomenological measure of ordering in statistical systems. Using this characteristic, we construct a formal model of a system evolving according to the law of steepest ascent as the control parameter increases. 相似文献
240.
The effect of solar features on geospheric conditions leading to geomagnetic storms (GMSs) with planetary index,A
P ≥ 20 and the range of horizontal component of the Earth’s magnetic fieldH such that 250γ <H < 400γ has been investigated using interplanetary magnetic field (IMF), solar wind plasma (SWP) and solar geophysical data
(SGD) during the period 1978–99. Statistically, it is observed that maximum number of GMSs have occurred during the maximum
solar activity years of 21st and 22nd solar cycles. A peculiar result has been observed during the years 1982, 1994 when sunspot
numbers (SSNs) decrease very rapidly while numbers of GMSs increase. No distinct association between yearly occurrence of
disturbed days and SSNs is observed. Maximum number of disturbed days have occurred during spring and rainy seasons showing
a seasonal variation of disturbed days. No significant correlation between magnitude (intensity) of GMSs and importance ofH
α
, X-ray solar flares has been observed. Maximum number of GMSs is associated with solar flares of lower importance, i.e.,
SF during the period 1978-93.H
α
, X-ray solar flares occurred within lower helio-latitudes, i.e., (0–30)°N to (0–30)°S are associated with GMSs. NoH
α
, X-ray solar flares have occurred beyond 40°N or 40°S in association with GMSs. In helio-latitude range (10–40)°N to (10–40)°S,
the 89.5% concentration of active prominences and disappearing filaments (APDFs) are associated with GMSs. Maximum number
of GMSs are associated with solar flares. Coronal mass ejections (CMEs) are related with eruptive prominences, solar flares,
type IV radio burst and they occur at low helio-latitude. It is observed that CMEs related GMS events are not always associated
with high speed solar wind streams (HSSWSs). In many individual events, the travel time between the explosion on the Sun and
maximum activity lies between 58 and 118 h causing GMSs at the Earth. 相似文献