全文获取类型
收费全文 | 7230篇 |
免费 | 1058篇 |
国内免费 | 663篇 |
专业分类
化学 | 2875篇 |
晶体学 | 124篇 |
力学 | 1963篇 |
综合类 | 76篇 |
数学 | 960篇 |
物理学 | 2953篇 |
出版年
2024年 | 15篇 |
2023年 | 69篇 |
2022年 | 189篇 |
2021年 | 186篇 |
2020年 | 239篇 |
2019年 | 203篇 |
2018年 | 209篇 |
2017年 | 256篇 |
2016年 | 311篇 |
2015年 | 250篇 |
2014年 | 371篇 |
2013年 | 536篇 |
2012年 | 427篇 |
2011年 | 441篇 |
2010年 | 376篇 |
2009年 | 449篇 |
2008年 | 416篇 |
2007年 | 485篇 |
2006年 | 419篇 |
2005年 | 345篇 |
2004年 | 335篇 |
2003年 | 293篇 |
2002年 | 251篇 |
2001年 | 225篇 |
2000年 | 194篇 |
1999年 | 191篇 |
1998年 | 174篇 |
1997年 | 158篇 |
1996年 | 153篇 |
1995年 | 98篇 |
1994年 | 84篇 |
1993年 | 93篇 |
1992年 | 80篇 |
1991年 | 59篇 |
1990年 | 54篇 |
1989年 | 40篇 |
1988年 | 32篇 |
1987年 | 42篇 |
1986年 | 33篇 |
1985年 | 24篇 |
1984年 | 28篇 |
1983年 | 13篇 |
1982年 | 22篇 |
1981年 | 20篇 |
1980年 | 16篇 |
1979年 | 15篇 |
1978年 | 11篇 |
1976年 | 6篇 |
1973年 | 4篇 |
1957年 | 4篇 |
排序方式: 共有8951条查询结果,搜索用时 15 毫秒
51.
Yu. A. Titov N. S. Slobodyanik Ya. A. Kraevskaya N. N. Belyavina V. Ya. Markiv 《Theoretical and Experimental Chemistry》2007,43(6):380-384
The synthesis of three-layered titanates BaLn2Ti3O10 (Ln = La, Nd, Sm) in systems with coprecipitated hydroxocarbonates was studied. It was established that they are formed through
an intermediate phase with a defective perovskite structure followed by its transformation into the three-layered structure
by the ordering of vacancies and rare-earth element and barium atoms and subdivision into three-layered blocks.
__________
Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 6, pp. 349–353, November–December, 2007. 相似文献
52.
Total internal reflection fluorescence (TIRF) microscopy is used to measure the dissociation kinetic rate of fluorescein-labeled epidermal growth factor from its specific receptors on the surface of intact but mildly fixed A431 human epidermoid cells in culture. Prior applications of TIRF microscopy have been limited to nonreceptor binding or to model membrane systems. The evanescent field excites fluorescence selectively at the surface of the cell proximal to the coverslip. Prismless epiillumination TIR is employed to avoid space limitations and is achieved by passing the excitation laser beam through a high (1.4)-aperture objective so that the light is incident at the glass/water interface beyond the critical angle. Long-term focus is maintained by a special feedback system. Of the possible effects that can influence the time course of the postbleach fluorescence recoveries—the EGF/receptor dissociation ratek
2, the bulk solution diffusion rate of EGF, and the cell surface motion of the receptors—we infer that the dissociation ratek
2 dominates. Several fitting schemes are compared and indicate the presence of a multiplicity of values fork
2, ranging from about 0.05 to 0.004 s–1, with an average value of about 0.012 s–1. These results compare well with values previously obtained by radiolabel/washing techniques. The significance of the results in terms of kinetic models and the advantages of the TIRF technique for these sorts of measurements are discussed. 相似文献
53.
A dual-electrode approach for highly selective detection of glucose based on diffusion layer theory: experiments and simulation 总被引:1,自引:0,他引:1
A dual-electrode configuration for the highly selective detection of glucose in the diffusion layer of the substrate electrode is presented. In this approach, a glassy carbon electrode (GCE, substrate) modified with a conductive layer of glucose oxidase/Nafion/graphite (GNG) was used to create an interference-free region in its diffusion layer by electrochemical depletion of interfering electroactive species. A Pt microelectrode (tip, 5 microm in radius) was located in the diffusion layer of the GNG-modified GCE (GNG-G) with the help of scanning electrochemical microscopy. Consequently, the tip of the electrode could sense glucose selectively by detecting the amount of hydrogen peroxide (H2O2) formed from the oxidization of glucose on the glucose oxidase layer. The influences of parameters, including tip-substrate distance, substrate potential, and electrolyzing time, on the interference-removing efficiency of this dual-electrode approach have been investigated systematically. When the electrolyzing time was 30 s, the tip-substrate distance was 1.8 a (9.0 microm) (where a is the radius of the tip electrode), the potentials of the tip and substrate electrodes were 0.7 V and 0.4 V, respectively, and a mixture of ascorbic acid (0.3 mM), uric acid (0.3 mM), and 4-acetaminophen (0.3 mM) had no influence on the glucose detection. In addition, the current-time responses of the tip electrode at different tip-substrate distances in a solution containing interfering species were numerically simulated. The results from the simulation are in good agreement with the experimental data. This research provides a concept of detection in the diffusion layer of a substrate electrode, as an interference-free region, for developing novel microelectrochemical devices. 相似文献
54.
L. H. Johnston S. R. Raju G. R. Sudhakaran R. M. Lees 《International Journal of Infrared and Millimeter Waves》1982,3(4):517-527
Laser-Stark spectra have been observed for methyl alcohol using the 311 m line of the HCN laser. Partial assignments are presented for the three most distinctive structures in the spectra. The low field structure is clearly associated with a member of the J=2019qRa-type multiplet, and is tentatively identified as the k=13 A vt=0 transition. The other two structures originate from the 9382 E vt=0 transition, and from a member of the k= 65 A vt=1 Q branch, tentatively assigned as the J=32 member. 相似文献
55.
Summary The cross-linkings of the surface polymer layer on mono disperse, poly(maleic anhydride-styrene)-modified silica particles
by the reaction with diisocyanate were studied. The extent of cross-linking was estimated by the weight decrease by immersing
the particles in the buffer solution of pH 2.0, 4.0 and 9.0 at a room temperature for 24 h. The reaction of the polymer-modified
silica with 1,6-diisocyanatohexane afforded relatively stable composite particles which lost less than 5 wt% of the polymer
in aqueous solution in the pH range 2.0–9.0. The diisocyanate was a preferable cross-linker to 2,4-diisocyanatotoluene in
terms of stability in acidic or basic aqueous solution. The flexibility of the cross-linker molecule possibly plays an important
role in the cross-linking reaction. The carboxyl and amino groups were formed by treating the cross-linked composite particles
with diluted HCl solution; 5–6 and 0.5–1.1 μmol g-1, respectively. The cross-linked composite particles exhibited the characteristic property of ζ-potential, −44 to −47 mV and
−102 to −107 mV in a neutral aqueous solution and ethanol, respectively.
Received: 26 May 1997 Accepted: 4 August 1997 相似文献
56.
Seiichi Nakamura Jun Inagaki Tomohiro Sugimoto Yasuyuki Ura Shunichi Hashimoto 《Tetrahedron》2002,58(52):10375-10386
An efficient, highly stereoselective synthesis of the C10–C31 (BCDEF ring) portion of pinnatoxin A has been achieved utilizing tandem double hemiketal formation/intramolecular hetero-Michael addition to construct the 6,5,6-dispiroketal (BCD ring) system and subsequent intramolecular ketalization to form the 5,6-bicycloketal (EF ring) system as key steps. 相似文献
57.
《Arabian Journal of Chemistry》2022,15(3):103646
One of the most common problems in wounds is delayed healing and complications such as infection. Therefore, the need for novel materials accelerates the healing of wounds especially abdominal wounds after surgery besides high efficiency and safety is mandatory. The rate of wound healing, anti-inflammatory and biocompatibility of Zn-Al LDH (Zn-Al layer double hydroxide) alone and loaded with Curcumin (Zn-Al LDH/Curcumin) was screened via in-vivo assays through intramuscular implantation in rat abdominal wall with intact peritoneum cavity. The implanted drugs were formed through Curcumin loaded into LDH of Zn-Al with drug release of 56.78 ± 1.51% within 24 h. The synthesized nanocomposite was characterized by (TGA/DTA) thermal analysis, (XRD) X-ray diffraction, (FESEM) Field emission scanning electron microscopy, (HRTEM) high resolution transmission electron microscope, energy dispersive X-ray (EDX) and low-temperature N2 adsorption, pore volume and average pore size distribution. The integrity of blood circulation, inflammatory signs, wound healing rate, capacity of tissue integration, antigenicity and composite biocompatibility, auto fluorescence ability of collagen bundles and the tensile strength of the muscle were assessed histopathologically after 7 and 30 days’ post-implantation. Excellent wound healing ability was achieved with shortest length between the wound gap edges and higher tensile strength of the muscle. Besides emit florescence very well followed by good healing and tensile muscles strength in Curcumin while very low strength with scar formation in Zn-Al LDH/Curcumin in both acute and chronic wound. No signs of inflammation in Curcumin & Zn-Al LDH. No vessels obstruction or bleeding observed in both Zn-Al LDH and Curcumin more than Zn-Al LDH/Curcumin and control which examined through candling. Good healing & infiltrated immune cells in same groups through histopathological examination. This work supports the anti-inflammatory, wound healing and biocompatibility of both LDH and Curcumin with living matter, increasing their biomedical applications in this era with safety and increasing efficacy with prolonged drug release. 相似文献
58.
Anna W. Sobańska 《液相色谱法及相关技术杂志》2020,43(9-10):319-327
AbstractImpregnated thin-layer chromatography (TLC) layers based on silica gel are presented. Impregnating agents such as metal cations, inorganic ions, chelating agents, chiral selectors, surfactants, ion-pairing reagents, and ionic liquids are discussed. The role of impregnated TLC layers in medicinal chemistry is highlighted. The historical overview of TLC separations on physically coated layers is given and some future prospects ahead of this technique are discussed. 相似文献
59.
Yoshisuke Ueda 《Journal of statistical physics》1979,20(2):181-196
This paper deals with turbulent or chaotic phenomena which occur in the system governed by Duffing's equation, a special type of two-dimensional periodic system. By using analog and digital computers, experiments are carried out with special reference to the change of attractors and of average power spectra of the random processes under the variation of the system parameters. On the basis of the experimental results, an outline of the random process is made clear. The results obtained in this paper will be applied to various physical problems and will also serve as material for the development of a proper mathematics of this phenomenon. 相似文献
60.
薄层层析法分离菊芋汁中低聚糖 总被引:1,自引:0,他引:1
采用薄层层析法(TLC)分离菊芋汁中的低聚糖成分。固定相为硅胶板GF254,展层剂为V正丁醇∶V异丙醇∶V乙酸∶V水=7∶5∶2∶4,显色剂为苯胺(4 mL)-二苯胺(4 g)-磷酸(20 mL)(溶于200 mL丙酮中)试剂。该展层体系可用于快速层析分离菊芋汁中的混合低聚糖,经过两次展层可达到良好分离结果。 相似文献