Wertheim’s integral equation theory for associating fluids is reformulated for the study of the connectedness properties of
associating hard spheres with four bonding sites. The association interaction is described as a square-well saturable attraction
between these sites. The connectedness version of the Ornstein-Zernike (OZ) integral equation is supplemented by the PY-like
closure relation and solved analytically within an ideal network approximation in which the network is represented as resulting
from the crossing of ideal polymer chains. The pair connectedness functions and the mean cluster size are calculated and discussed.
The condition for the percolation transition and the analytical form of the percolation threshold are derived. The connection
of the percolation with the gas-liquid phase transition is discussed. 相似文献
We introduce new special ellipsoidal confocal coordinates in
n (n ≥ 3) and apply them to the geodesic problem on a triaxial ellipsoid in
3 as well as the billiard problem in its focal ellipse.
Using such appropriate coordinates we show that these different dynamical systems have the same common analytic first integral. This fact is not evident because there exists a geometrical spatial gap between the geodesic and billiard flows under consideration, and this separating gap just “veils” the resemblance of the two systems.
In short, a geodesic on the ellipsoid and a billiard trajectory inside its focal ellipse are in a “veiled assonance”—under the same initial data they will be tangent to the same confocal hyperboloid. But this assonance is rather incomplete: the dynamical systems in question differ by their intrinsic action angle-variables, thereby the different dynamics arise on the same phase space (i.e. the same phase curves in the same phase space bear quite different rotation numbers).
Some results of this work have been published before in Russian (Tabanov, 1993) and presented to the International Geometrical Colloquium (Moscow, May 10–14, 1993) and the International Symposium on Classical and Quantum Billiards (Ascona, Switzerland, July 25–30, 1994). 相似文献
In this paper, analytical solutions to time-fractional partial differential equations in a multi-layer annulus are presented. The final solutions are obtained in terms of Mittag-Leffler function by using the finite integral transform technique and Laplace transform technique. In addition, the classical diffusion equation (α=1), the Helmholtz equation (α→0) and the wave equation (α=2) are discussed as special cases. Finally, an illustrative example problem for the three-layer semi-circular annular region is solved and numerical results are presented graphically for various kind of order of fractional derivative. 相似文献
We present a rigorous and functorial quantization scheme for affine field theories, i.e., field theories where local spaces of solutions are affine spaces. The target framework for the quantization is the general boundary formulation, allowing to implement manifest locality without the necessity for metric or causal background structures. The quantization combines the holomorphic version of geometric quantization for state spaces with the Feynman path integral quantization for amplitudes. We also develop an adapted notion of coherent states, discuss vacuum states, and consider observables and their Berezin–Toeplitz quantization. Moreover, we derive a factorization identity for the amplitude in the special case of a linear field theory modified by a source-like term and comment on its use as a generating functional for a generalized S-matrix. 相似文献