High‐temperature oxidation behavior of Ni‐based superalloys with Nb and Y and the interface characteristics of oxidation scales

Ni‐based superalloys with niobium (Nb) or/and yttrium (Y) were prepared by vacuum melting. The oxidation kinetics of these alloys was studied by thermogravimetry at 800 °C for 100 h in static air. Morphology of oxides was studied using SEM, and the composition was analyzed by X‐ray diffraction. Energy‐dispersive X‐ray spectrometer was employed to examine the linear element distribution of the cross section of the oxidation films. Results showed that the oxidation kinetics all followed a parabolic law at different stages. The oxide films were mainly comprised of Cr₂O₃, NiCr₂O₄, Al₂O₃ and TiO₂. All the oxide films exhibited layered structure owing to different oxidation stages. With the addition of Nb or Y, the high‐temperature oxidation resistance of the superalloy was improved significantly and the surface morphology of the oxidation film was ameliorated. The comprehensive effect of Nb and Y was remarkable in improving the high‐temperature oxidation resistance of Ni‐based alloys. Copyright © 2014 John Wiley & Sons, Ltd.     

The preparation of covalent triazine‐based framework via Friedel‐Crafts reaction of 2,4,6‐trichloro‐1,3,5‐triazine with N,N′‐diphenyl‐N,N′‐di(m‐tolyl)benzidine for capturing and sensing to iodine

The covalent triazine‐based framework (TDPDB) has been prepared by Friedel‐Crafts polymerization reaction of N,N′‐diphenyl‐N,N′‐di(m‐tolyl)benzidine (DPDB) with 2,4,6‐trichloro‐1,3,5‐triazine (TCT) catalyzed by methanesulfonic acid. The yield of the reaction (94.85%) is very high. TDPDB was provided with Brunauer‐Emmett‐Teller specific surface area of 592.18 m² g^?1 and pore volume of 0.5241 cm³ g^?1. TDPDB demonstrated an excellent capacity for capturing iodine (3.93 g g^?1) and an outstanding ability to fluorescent sensing to iodine with Ksv of 5.83 × 10⁴ L mol^?1. It also showed high fluorescent sensing sensitivity to picric acid.     

Synthesis of bio‐based internal and external cross‐linkers based on tannic acid for preparation of antibacterial superabsorbents

Recent researches focus on the synthesis of new cross‐linkers from natural resources. In the current work, functionalized tannic acid was employed as a replacement of petroleum‐based cross‐linkers because of its outstanding biochemical properties. Alkene‐ and epoxy‐functionalized tannic acids were synthesized as internal and external cross‐linkers, respectively. Cross‐linker structures were characterized with Ft‐IR and ¹HNMR analysis. Different amounts, as well as different numbers of alkene functional group, were incorporated during the superabsorbent synthesis. Moreover, the internal cross‐linked superabsorbent was surface cross‐linked with different amounts of epoxy‐functionalized tannic acid and increased the absorbency under load about 10 g g^?1. Free absorption properties in water and saline solution, absorbency under load, and rheological properties of superabsorbents were investigated. In addition, the antibacterial activity of the internal and external cross‐linked superabsorbent was studied against Escherichia coli and Staphylococcus aureus bacteria via different methods and compared with that of conventional superabsorbent.     

Amphiphilic Copolymers Shuttle Drugs Across the Blood–Brain Barrier

Medical treatment of diseases of the central nervous system requires transport of drugs across the blood–brain barrier (BBB). Here, it is extended previously in vitro experiments with a model compound to show that the non‐water‐soluble and brain‐impermeable drug domperidone (DOM) itself can be enriched in the brain by use of an amphiphilic copolymer as a carrier. This carrier consists of poly(N‐(2‐hydroxypropyl)‐methacrylamide), statistically copolymerized with 10 mol% hydrophobic lauryl methacrylate, into whose micellar aggregates DOM is noncovalently absorbed. As tested in a BBB model efficient transport of DOM across, the BBB is achievable over a wide range of formulations, containing 0.8 to 35.5 wt% domperidone per copolymer. In neither case, the polymer itself is translocated across the BBB model. In vivo experiments in mice show that already 10 min after intraperitoneal injection of the polymer/domperidone (PolyDOM) formulation, domperidone can be detected in blood and in the brain. Highest serum and brain levels of domperidone are detected 40 min after injection. At that time point serum domperidone is increased 48‐fold. Most importantly, domperidone is exclusively detectable in high amounts in the brain of PolyDOM injected mice and not in mice injected with bare domperidone.

     

考虑对象属性信息的复杂网络社团结构发现算法

针对社团结构发现算法仅考虑对象间相互关系的密集程度,忽视对象间属性特征差异的不足,提出考虑属性信息的复杂网络社团结构发现算法.算法引入属性特征相似度、基于属性特征相似度的有权网络、内聚度3个核心概念,迭代选取使内聚度指标上升最快的合并操作,自底向上实现社团聚集.由于考虑了属性信息,算法输出的社团结构具有更高准确度,更具应用价值.     

Hamiltonian spatial structure for three-dimensional water waves in a moving frame of reference

Summary The governing equations for three-dimensional time-dependent water waves in a moving frame of reference are reformulated in terms of the energy and momentum flux. The novelty of this approach is that time-independent motions of the system—that is, motions that are steady in a moving frame of reference—satisfy a partial differential equation, which is shown to be Hamiltonian. The theory of Hamiltonian evolution equations (canonical variables, Poisson brackets, symplectic form, conservation laws) is applied to the spatial Hamiltonian system derived for pure gravity waves. The addition of surface tension changes the spatial Hamiltonian structure in such a way that the symplectic operator becomes degenerate, and the properties of this generalized Hamiltonian system are also studied. Hamiltonian bifurcation theory is applied to the linear spatial Hamiltonian system for capillary-gravity waves, showing how new waves can be found in this framework.     

Direct estimates on intersection probabilities of random walks

A study is made of intersection properties of independent random walks ind-dimensional lattice spaceZ ^d . A simple method is developed which makes it possible to estimate intersection probalities of two random walks with killing ratem directly. It is expected that the method can be generalized and extended to other issues.     

单向环同态的一个新构造及两个多签名方案

本文对单向环同态提出了一种新的构造方法 ,即直接定义 Zn× U与 Zn× Imf( U,V是有限可换群 ,f 是 U→V的同态映射 )的两种运算而使 Zn× U与 Zn× Imf 是环 ,不必利用 U与 Imf是 Zn-模 ,这可避免某些运算在形式上易造成的混乱 ,并把单向环同态应用于椭圆曲线上 ,提出了一种基于椭圆曲线上单向环同态的多签名方案 .另外 ,本文对 Kazuo Ohta和 Tatsuaki Okamoto提出的一个多签名方案进行了改进 ,使原来需经过两个轮次而完成的多签名过程只需经一个轮次即可完成     

The 3D characteristics of post‐traumatic syringomyelia in a rat model: a propagation‐based synchrotron radiation microtomography study

Many published literature sources have described the histopathological characteristics of post‐traumatic syringomyelia (PTS). However, three‐dimensional (3D) visualization studies of PTS have been limited due to the lack of reliable 3D imaging techniques. In this study, the imaging efficiency of propagation‐based synchrotron radiation microtomography (PB‐SRµCT) was determined to detect the 3D morphology of the cavity and surrounding microvasculature network in a rat model of PTS. The rat model of PTS was established using the infinite horizon impactor to produce spinal cord injury (SCI), followed by a subarachnoid injection of kaolin to produce arachnoiditis. PB‐SRµCT imaging and histological examination, as well as fluorescence staining, were conducted on the animals at the tenth week after SCI. The 3D morphology of the cystic cavity was vividly visualized using PB‐SRµCT imaging. The quantitative parameters analyzed by PB‐SRµCT, including the lesion and spared spinal cord tissue area, the minimum and maximum diameters in the cystic cavity, and cavity volume, were largely consistent with the results of the histological assessment. Moreover, the 3D morphology of the cavity and surrounding angioarchitecture could be simultaneously detected on the PB‐SRµCT images. This study demonstrated that high‐resolution PB‐SRµCT could be used for the 3D visualization of trauma‐induced spinal cord cavities and provides valuable quantitative data for cavity characterization. PB‐SRµCT could be used as a reliable imaging technique and offers a novel platform for tracking cavity formation and morphological changes in an experimental animal model of PTS.