全文获取类型
收费全文 | 20817篇 |
免费 | 4311篇 |
国内免费 | 2538篇 |
专业分类
化学 | 8060篇 |
晶体学 | 530篇 |
力学 | 2066篇 |
综合类 | 280篇 |
数学 | 2249篇 |
物理学 | 14481篇 |
出版年
2024年 | 33篇 |
2023年 | 183篇 |
2022年 | 482篇 |
2021年 | 586篇 |
2020年 | 610篇 |
2019年 | 528篇 |
2018年 | 564篇 |
2017年 | 776篇 |
2016年 | 907篇 |
2015年 | 771篇 |
2014年 | 1120篇 |
2013年 | 1727篇 |
2012年 | 1404篇 |
2011年 | 1421篇 |
2010年 | 1308篇 |
2009年 | 1373篇 |
2008年 | 1341篇 |
2007年 | 1351篇 |
2006年 | 1290篇 |
2005年 | 1170篇 |
2004年 | 1160篇 |
2003年 | 994篇 |
2002年 | 886篇 |
2001年 | 737篇 |
2000年 | 725篇 |
1999年 | 649篇 |
1998年 | 540篇 |
1997年 | 444篇 |
1996年 | 392篇 |
1995年 | 304篇 |
1994年 | 270篇 |
1993年 | 256篇 |
1992年 | 216篇 |
1991年 | 150篇 |
1990年 | 144篇 |
1989年 | 145篇 |
1988年 | 140篇 |
1987年 | 92篇 |
1986年 | 93篇 |
1985年 | 61篇 |
1984年 | 43篇 |
1983年 | 22篇 |
1982年 | 50篇 |
1981年 | 43篇 |
1980年 | 32篇 |
1979年 | 35篇 |
1978年 | 28篇 |
1977年 | 18篇 |
1976年 | 14篇 |
1973年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
41.
42.
The transport of monodisperse as well as polydisperse colloid suspensions in a two-dimensional, water saturated fracture with spatially variable and anisotropic aperture is investigated with a particle tracking model. Both neutrally buoyant and dense colloid suspensions are considered. Although flow and transport in fractured subsurface formations have been studied extensively by numerous investigators, the transport of dense, polydisperse colloid suspensions in a fracture with spatially variable and anisotropic aperture has not been previously explored. Simulated snapshots and breakthrough curves of ensemble averages of several realizations of a log-normally distributed aperture field show that polydisperse colloids exhibit greater spreading than monodisperse colloids, and dense colloids show greater retardation than neutrally buoyant colloids. Moreover, it is demonstrated that aperture anisotropy oriented along the flow direction substantially increases colloid spreading; whereas, aperture anisotropy oriented transverse to the flow direction retards colloid movement. 相似文献
43.
Hiroto Kudo Nobuhito Ito Keiji Nakajima Masami Ochiai Tadatomi Nishikubo 《Journal of polymer science. Part A, Polymer chemistry》2007,45(19):4421-4429
The polyaddition of fluorine‐containing bis(epoxide)s and fluorine‐containing triazine di(aryl ether)s were examined to give the corresponding fluorine‐containing poly(cyanurate)s. It was observed that the synthesized fluoropolymers had good thermal stabilities and good film‐forming properties. The glass transition temperatures (Tg's) and refractive‐indices (nD's) of synthesized polymers were determined by differential scanning calorimetry and ellipsometry, respectively, and it was found that the values of Tg's and nD's were supported by their fluorine containing ratios and skeletons. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4421–4429, 2007 相似文献
44.
Ana Luísa Daniel‐da‐Silva João Carlos Moura Bordado José Miguel Martín‐Martínez 《Journal of Polymer Science.Polymer Physics》2007,45(22):3034-3045
The degree of phase separation in several moisture‐cured poly(urethane urea)s (PUUs) was studied by FTIR spectroscopy, wide angle X‐ray diffraction (WAXD), and temperature‐modulated differential scanning calorimetry (TMDSC). This latter technique was shown to be particularly useful in analysing the degree of phase separation in PUU polymers. Both phase mixing and phase segregation coexisted in the PUUs and the degree of phase separation increased as the urea hard segment (HS) content in the PUU increased. The maximum solubility of urea HSs into the polyol soft segments (SSs) was achieved for 50 wt % urea HS content in diol‐based PUUs, whereas for triol‐based PUUs the highest solubility between HS and SS was reached for lower urea HS amount. Finally, the higher the urea HS content the higher the extent of phase separation in the PUU. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3034–3045, 2007 相似文献
45.
Neutrino-photon processes, forbidden in vacuum, can take place in the presence of a thermal medium and/or an external electro-magnetic
field, mediated by the corresponding charged leptons (real or virtual). Such interactions affect the propagation of neutrinos
through a magnetized plasma. We investigate the neutrino-photon absorptive processes, at the one-loop level, for massless
neutrinos in a weakly magnetized plasma. We find that there is no correction to the absorptive part of the axial-vector-vector
amplitude due to the presence of a magnetic field, to the linear order in the field strength. 相似文献
46.
Alessandro Conflitti 《Finite Fields and Their Applications》2003,9(4):423-431
We propose a probabilistic algorithm to reduce computing the greatest common divisor of m polynomials over a finite field (which requires computing m−1 pairwise greatest common divisors) to computing the greatest common divisor of two polynomials over the same field. 相似文献
47.
使用结构简单的单温炉设备,通过三步升温热解二茂铁、三聚氰氨混合物方法,在二氧化硅、多晶陶瓷基底上分别合成了碳纳米管阵列、碳纳米管捆束.使用扫描电子显微镜、透射电子显微镜、电子能量损失谱和x射线光电子能谱对合成样品进行了结构和成分分析.结果显示:两种基底上合成的纳米管均为多壁纯碳管;生长于光滑二氧化硅表面的碳纳米管具有高度取向性和一致的外径,长度为10—40μm.碳纳米管采取催化剂顶端生长模式并展示出类杯状形貌;生长于粗糙多晶陶瓷表面的碳纳米管捆束随机取向,碳纳米管直径为15—80nm,长度在几百微米,展示
关键词:
碳纳米管
热解法
三步升温工艺 相似文献
48.
M. Faucher D. Garcia E. Antic-Fidancev M. Lemaitre-Blaise 《Journal of Physics and Chemistry of Solids》1989,50(12)
Some structural and spectroscopic features of rare earth orthoaluminates are examined.The trigonal→ orthorhombic transition is studied in a series of NdxSm1−xAlO3 compounds. The evolution of the crystal structure is followed by X-ray analysis and optical absorption. The free ion and crystal field parameters of Nd3+ (4f3 configuration) are determined in LuAlO3:Nd3+.The anomaly of the calculated splitting of the
levels is slight, but well characterized in NdAlO3. The spin correlated crystal field and orbitally correlated crystal field models are tested as well as an empirical correction which was proposed earlier. 相似文献
49.
Using the DFT/B3LYP method with a 6-31G(d) basis set, the structure, normal vibration frequencies, and the absolute band intensities in the IR spectra of the chlorin molecule and its four symmetric isotopomers have been calculated. Scaling of the force field by the Pulay method in independent and natural coordinates has been carried out. A method for obtaining effective force fields without using experimental data on the fundamental vibration frequencies is proposed. By comparing the vibration modes and constructing special matrices, complete assignment of the fundamental frequencies of porphin and chlorin has been carried out. It has been shown that the majority of porphin macroring vibrations upon pyrrolenine ring hydrogenation are frequency-characteristic and only 12 vibrations change considerably. A frequency correlation with regard for the mode transition between chlorin and all its isotopomers under consideration has been established. Comparative analysis of the force fields of porphin and chlorin in dependent natural coordinates has revealed the unique nonlocal character of the change in force constants of the macroring upon hydrogenation of one pyrrolenine ring. Modeling of the IR spectra of chlorin and its isotopomers has been performed. Assignment and interpretation of the normal vibrations of the molecules under consideration have been carried out. 相似文献
50.
利用场发射显微镜和四极质谱计研究了充入高纯O2的四极质谱和O2对单壁碳纳米管场发射的影响.单壁碳纳米管经过约1000℃的热处理得到清洁态场发射像后,充入O2,分别测量了O2吸附和脱附后场发射的I V特性.实验观测到在单壁碳纳米管上O2的吸附使场发射电流减小,说明逸出功增加.在10-4Pa的O2压强下对单壁碳纳米管进行约1000℃的热处理,可以产生氧化刻蚀作用,观测到场发射像的变化,并测量了氧化刻蚀产生的I V特性变化.
关键词:
单壁碳纳米管
场发射显微镜
场发射
四极质谱 相似文献