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51.
Tom Kennedy 《Journal of statistical physics》1990,59(1-2):195-220
A fixed-point equation on an infinite-dimensional space is proposed as an alternative to the usual definition of the infinite-volume limit in discrete lattice spin systems in the high-temperature phase. It is argued heuristically that the free energy and correlation functions one obtains by solving this equation agree with the usual definitions of these quantities. A theorem is then proved that says that if a certain finite-volume condition is satisfied, then this fixed-point equation has a solution and the resulting free energy is analytic in the parameters in the Hamiltonian. For particular values of the temperature this finite-volume condition may be checked with the help of a computer. The two-dimensional Ising model is considered as a test case, and it is shown that the finite-volume condition is satisfied for0.77
critical. 相似文献
52.
兖州高硫煤的加氢热解脱硫及脱硫动力学 总被引:5,自引:1,他引:5
在加压热天平上,考察了氢气和氮扬气氛下高硫煤的热解脱硫。利用气相色谱在线分析研究了硫化氢氢气的逸出规律。结果表明,加氢热解比氮气下的热解有着更显著的脱友作用,脱硫率可达90%以上。而且加氢热解下65%的脱除硫转化为气相硫化氢,而氮气下热解是有80%的硫转化为液相。 相似文献
53.
Yu. A. Dyadin F. V. Zhurko I. V. Bondaryuk G. O. Zhurko 《Journal of inclusion phenomena and macrocyclic chemistry》1991,10(1):39-56
Experimental data on the investigation of the water-trimethyleneoxide system,P, t, x phase diagram (up to 6 kbar) are presented. The results are compared with those on water systems with ethyleneoxide, 1,3- and 1,4-dioxane, 1,3-dioxolane and tetrahydrofuran, on the basis of which a summarizedP, t, x diagram is plotted for water-cyclic ether systems. It is shown that in all the systems in which a cubic structure II hydrate forms at 1 bar, it eventually turns to cubic structure I under pressure. The nature of high pressure hydrates is discussed.Dedicated to the memory of D. W. Davidson. 相似文献
54.
建立了反相高效液相色谱法监测人口服地尔硫艹卓缓释片后血药浓度。血样用正己烷-氯仿-异丙醇混合溶剂(60405)提取后,以C18化学键合硅胶为固定相,甲醇-水-三乙胺为流动相,安定为内标,在239nm波长处定量检测。血药浓度在15~300μg/L范围内线性关系良好,最低检测浓度为3μg/L。批内(n=7)及批间(n=5)测定相对标准偏差分别小于6.8%和8.4%,回收率为91%~104%。监测了8名健康人口服盐酸地尔硫艹卓缓释片后的不同时间的血药浓度变化,计算了有关的药代动力学参数。 相似文献
55.
56.
57.
Gunter Zwilling 《Monatshefte für Chemie / Chemical Monthly》1981,112(2):157-165
The anodic overvoltage on carbon and platinum electrodes in the electrochemical production of high purity gadolinium from molten 75 LiF-25 mol% GdF3 solutions is discussed. At the cell temperature of 840°C calciumimpregnated anodes led to the reduction of inert electrode films and to a current yield of nearly 100%.The deposited gadolinium contained 75, 22, 54 and less than 100 ppm of the interstitial elements H, N, O and C respectively; the concentrations of the highest other analysed impurities were: Si (89), Fe (15), Y (5), Zr (3), Nd (3), Tb (71), Ta (49), W (23) and Re (<3 ppm).Partly performed at the Ames Laboratory—U.S. Department of Energy. 相似文献
58.
E. U. Franck 《Journal of solution chemistry》1973,2(2-3):339-356
A survey is given of recent experimental results obtained from high-temperature, high-pressure investigations with water, aqueous solutions, and ionic fluids. Data on the static dielectric constant of water to 550°C and 5 kbar are given and discussed with respect to their relation to water structure. Infrared and Raman spectra of HDO in pure water have been obtained to 400°C and 4 kbar, which give information on hydrogen bonding. Xe–H2O and CO2–H2O mixtures were investigated in the infrared. Ni(II) and Cu(II) complexes were investigated by absorption spectroscopy in aqueous solutions of high chloride content to 350°C and 2–6 kbar. The gas-liquid critical point of ammonium chloride was found at 880°C and 1635 bars. This fluid appears to be predominantly ionic even in the critical region. The possibility of converting pure polar fluids such as ammonia and water into concentrated ionic solutions by self-ionization at very high pressures is mentioned.This paper was presented at the symposium, The Physical Chemistry of Aqueous Systems, held at the University of Pittsburgh, Pittsburgh, Pennsylvania, June 12–14, 1972, in honor of the 70th birthday of Professor H. S. Frank. 相似文献
59.
煤中有机硫形态结构和热解过程硫变迁特性的研究 总被引:10,自引:1,他引:10
利用热解 质谱并结合固定床热解反应装置,对煤中有机硫的形态主其对加氢热解过程 变迁特性的影响,进行了较系统的研究。结果表明,煤中有机硫的形态结构在褐煤中主要以脂肪族、芳香族硫化物为主,而在 煤中则主要以各种不同芳构化程度的噻吩结构为主,初步表明煤中有机硫形态结构随煤变质程度的变迁呈较强的连续递变性。煤热解过程中硫在呼产物中的变迁和分布与煤中有机硫的形态结构特点密切相关。较高芳构化噻吩结构不完全的氧 相似文献
60.
J. Díaz-Ferrero M.C. Rodríguez-Larena L. Comellas B. Jiménez 《Trends in analytical chemistry : TRAC》1997,16(10):1865-573
The usual methods for determining polychlorinated dibenzo-p-dioxins (PCDD), polychlorinated dibenzofurans (PCDF) and polychlorinated biphenyls (PCB) are generally expensive and time consuming. This fact has favored the development of faster and cheaper techniques, based on immunoassays and bioassays. This paper reviews these bioanalytical methods and their analytical importance at the present moment. 相似文献