Identification of the nitrate contamination sources of the Brusselian sands groundwater body (Belgium) using a dual-isotope approach

Isotopic fingerprinting is an advanced technique allowing the classification of the nitrate source pollution of groundwater, but needs further development and validation. In this study, we performed measurements of natural stable isotopic composition of nitrate (¹⁵N and ¹⁸O) in the groundwater body of the Brussels sands (Belgium) and studied the spatial and temporal dynamics of the isotope signature of this aquifer. Potential nitrogen sources sampled in the region had isotopic signatures that fell within the corresponding typical ranges found in the literature. For a few monitoring stations, the isotopic data strongly suggest that the sources of nitrate are from mineral fertiliser origin, as used in agriculture and golf courses. Other stations suggest that manure leaching from unprotected stockpiles in farms, domestic gardening practices, septic tanks and probably cemeteries contribute to the nitrate pollution of this groundwater body. For most monitoring stations, nitrate originates from a mixing of several nitrogen sources. The isotopic signature of the groundwater body was poorly structured in space, but exhibited a clear temporal structure. This temporal structure could be explained by groundwater recharge dynamics and cycling process of nitrogen in the soil-nitrogen pool.     

Natural radioactivity in groundwater – a review

The issue of natural radioactivity in groundwater is reviewed, with emphasis on those radioisotopes which contribute in a significant way to the overall effective dose received by members of the public due to the intake of drinking water originating from groundwater systems. The term ‘natural radioactivity’ is used in this context to cover all radioactivity present in the environment, including man-made (anthropogenic) radioactivity. Comprehensive discussion of radiological aspects of the presence of natural radionuclides in groundwater, including an overview of current regulations dealing with radioactivity in drinking water, is provided. The presented data indicate that thorough assessments of the committed doses resulting from the presence of natural radioactivity in groundwater are needed, particularly when such water is envisaged for regular intake by infants. They should be based on a precise determination of radioactivity concentration levels of the whole suite of radionuclides, including characterisation of their temporal variability. Equally important is a realistic assessment of water intake values for specific age groups. Only such an evaluation may provide the basis for possible remedial actions.     

Modified asymptotic Adomian decomposition method for solving Boussinesq equation of groundwater flow

The Adomian decomposition method （ADM） is an approximate analytic method for solving nonlinear equations. Generally, an approximate solution can be ob- tained by using only a few terms. However, in applications, we need to use it flexibly according to the real problem. In this paper, based on the ADM, we give a modified asymptotic Adomian decomposition method and use it to solve the nonlinear Boussinesq equation describing groundwater flows. The example shows effectiveness of the modified asymptotic Adomian decomposition method.     

一类抛物型偏微分方程的特征中心差分方法

运用特征中心差分方法来求解一类抛物型偏微分方程.通过对网格的不均匀剖分来离散方程,得到方程的特征中心差分格式.作了H1误差估计,给出了相应的定理.数值实验表明该方法对解此类问题是高效稳定的.     

A Layer-Integrated Model of Solute Transport in Heterogeneous Media

This study presents a numerical solution to the three-dimensional solute transport in heterogeneous media by using a layer-integrated approach. Omitting vertical spatial variation of soil and hydraulic properties within each layer, a three-dimensional solute transport can be simplified as a quasi-three-dimensional solute transport which couples a horizontal two-dimensional simulation and a vertical one-dimensional computation. The finite analytic numerical method was used to discretize the derived two-dimensional governing equation. A quadratic function was used to approximate the vertical one-dimensional concentration distribution in the layer to ensure the continuity of concentration and flux at the interface between the adjacent layers. By integration over each layer, a set of system of equations can be generated for a single column of vertical cells and solved numerically to give the vertical solute concentration profile. The solute concentration field was then obtained by solving all columns of vertical cells to achieve convergence with the iterative solution procedure. The proposed model was verified through examples from the published literatures including four verifications in terms of analytical and experimental cases. Comparison of simulation results indicates that the proposed model satisfies the solute concentration profiles obtained from experiments in time and space.     

Geochemical and isotopic evidences from groundwater and surface water for understanding of natural contamination in chronic kidney disease of unknown etiology (CKDu) endemic zones in Sri Lanka

Chronic kidney disease of unknown etiology (CKDu) is the main health issue in the dry zone of Sri Lanka. Despite many studies carried out, causative factors have not been identified yet clearly. According to the multidisciplinary researches carried out so far, potable water is considered as the main causative factor for CKDu. Hence, the present study was carried out with combined isotopic and chemical methods to understand possible relationships between groundwater; the main drinking water source, and CKDu in four endemic areas in the dry zone. Different water sources were evaluated isotopically (²H, ³H and ¹⁸O) and chemically from 2013 to 2015. Results revealed that prevalence of CKDu is significantly low with the groundwater replenished by surface water inputs. It is significantly high with the groundwater stagnated as well as groundwater recharged from regional flow paths. Thus, the origin, recharge mechanism and flow pattern of groundwater, as well as geological conditions which would be responsible for natural contamination of groundwater appear as the main causative factors for CKDu. Therefore, detailed investigations should be made in order to identify the element(s) in groundwater contributing to CKDu. The study recommends providing drinking water to the affected zones using water sources associated with surface waters.     

Interpretation of environmental tracer data for conceptual understanding of groundwater flow: an application for fractured aquifer systems in the Kłodzko Basin,Sudetes, Poland

Environmental isotopes and hydrogeological data have been used for the construction of a conceptual model of fresh groundwater flow in the K?odzko Basin, Sudetes, Poland. The model has allowed the verification of a groundwater circulation scheme resulting from the general morphological assumptions and the recharge role to the surrounding mountains. Combined interpretation of the tritium ages and the isotopic altitude effect allowed determining the volume of water-bearing rock V_r and hydrogeological parameters of systems drained by springs and wells. Prior to the final determination of the recharge zone of individual objects, calculations were made for the thickness of the flow zone (h) and the distance from the recharge zone to the drainage point (L). The recharge areas for springs are located within a distance of 1–1.5 km and are characterized by a width of 0.75–1.65 km. The recharge area of wells is located in significantly longer distances of 2.1–12 km but yet definitely lower width. The recharge of groundwater from the Western direction seems to be obvious for all the wells and springs located westward from Nysa K?odzka River. The eastern component of the recharge appeared during the interpretation of the well in D?ugopole.

Dedicated to Professor Peter Fritz on the occasion of his 80th birthday     

Hydrogeochemical and isotope study of perched aquifers in the Cuvelai-Etosha Basin,Namibia

A hydrogeochemical and stable isotope study (²H and ¹⁸O) was carried out in the Cuvelai-Etosha Basin in order to characterize available groundwater and to identify possible recharge mechanisms for the perched aquifers. Data were collected during seven field campaigns between 2013 and 2015 from a total of 24 shallow and deep groundwater hand-dug wells. In the investigated groundwaters, hydrogencarbonate is the dominating anion in both well types, whereas cations vary between calcium and magnesium in deep wells, and sodium and potassium in shallow wells. Groundwater chemistry is controlled by dissolution of carbonate minerals, silicate weathering and ion exchange. Stable isotopic composition suggests that deep groundwater is recharged by high-intensity/large rainfall events, whereas the shallow wells can even be recharged by less-intense/small rainfall events. Water in deep wells reflect a mixture of water influenced by evaporation during or before infiltration and water that infiltrated through fast preferential pathways, whereas shallow wells are strongly influenced by evaporation. The findings of this research contribute to improve the understanding of hydrogeochemistry, recharge paths and temporal variations of perched aquifers.     

针对RED脆弱性的分布式LDoS攻击构造

针对随机早期检测(random early detection,RED)算法在慢速拒绝服务攻击(low-rate deny of serv-ice,LDoS)面前的脆弱性问题,本文通过对比路由器分别在RED和尾丢弃Drop-Tail算法管理下遭受LDoS攻击时的队列平均占用率及吞吐量,指出虽然路由器在RED算法下具有较大的空闲缓冲区,却不能对网络流量攻击起到缓冲作用.仿真对比实验表明,LDoS攻击使得路由器在RED下比Drop-Tail具有更大的链路损失带宽.指出现有LDoS的防范和检测方法的不足,构造了一种分布式LDoS攻击模型并给出一组模型实例,该模型说明现有突发流量检测方法不足以弥补RED脆弱性,也说明网络流量行为的关联复杂性.     

Application of chlorine-36 technique in determining the age of modern groundwater in the Al-Zulfi province,Saudi Arabia

The present study aims to estimate the residence time of groundwater based on bomb-produced ³⁶Cl. ³⁶Cl/Cl ratios in the water samples are determined by inductively coupled plasma mass spectrometry and liquid scintillation counting. ³⁶Cl/Cl ratios in the groundwater were estimated to be 1.0–2.0?×?10^?12. Estimates of residence time were obtained by comparing the measured bomb-derived ³⁶Cl concentrations in groundwater with the background reference. Dating based on a ³⁶Cl bomb pulse may be more reliable and sensitive for groundwater recharged before 1975, back as far as the mid-1950s. The above ³⁶Cl background concentration was deduced by determining the background-corrected Dye-3 ice core data from the frozen Arctic data, according to the estimated total ³⁶Cl resources. The residence time of 7.81?×?10⁴ y is obtained from extrapolated groundwater flow velocity. ³⁶Cl concentration in groundwater does not reflect the input of bomb pulse ³⁶Cl, and it belongs to the era before 1950.