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291.
对正弦和余弦富立叶级数,通过合并相邻同号项,使其重排成交错级数.讨论了重排形成的交错级数的敛散性.指出根据自变量x的不同取值,该交错级数可能是单调递减或周期递减的级数.按照莱布尼茨判定法提出了不同精度要求的级数项数的计算公式.选取一到三阶收敛的富立叶级数计算了不同比值精度及差值精度要求的级数项数.计算表明,在x的取值为2π的等分点时,富立叶级数的部分和随项数的增加单调地逼近其收敛值.在x的取值为其它点时,富立叶级数的部分和随项数的增加围绕收敛值上下变动,周期地逼近其收敛值.低收敛阶富立叶级数的收敛速度较慢.要达到0.01%的精度,一收敛阶富立叶级数需要数万项,二收敛阶富立叶级数也需要数百项.在不同计算点处,要达到相同的计算精度,需要的级数项数差别较大. 相似文献
292.
In this paper we give a short geometric proof of a generalization of a well-known result about reduction of codimension for submanifolds of Riemannian symmetric spaces. 相似文献
293.
Relationships between molecular structure and thermomechanical properties of bio‐based thermosetting polymers 下载免费PDF全文
Jung Ho Yang Arun Srikanth Changwoon Jang Cameron F. Abrams 《Journal of Polymer Science.Polymer Physics》2017,55(3):285-292
Molecular dynamics simulations are used to study highly cross‐linked epoxy networks comprised of furanyl epoxy monomer, 2,5‐bis[(2‐oxiranylmethoxy)methyl]‐furan (BOF), that is cross‐linked by two furanyl amine hardeners, 5,5'‐methylenedifurfurylamine (DFDA) and 5,5'‐ethylidenedifurfirylamine (CH3‐DFDA). Important properties of these fully furan‐based systems, including room temperature density, glass transition temperature, and Young's modulus are found to agree with previous experimental results. We also compare the simulated and experimental values of four fully furan‐based thermosetting materials to those using the conventional resin diglycidyl ether of bisphenol A (DGEBA) cured with the two furanyl hardeners. Our simulation results predict a slight decrease in density and Young's modulus, but no impact on the glass transition temperature, upon adding the methyl group in DFDA. Detailed analyses of the MD trajectories reveal the underlying mechanisms responsible for the observed structure/property relations, which center on the lack of collinear covalent bonds in the BOF molecular structure. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 285–292 相似文献
294.
In this work we introduce a model of the boundary layer equations for a perfect conducting micropolar fluid with stretch, bounded by an infinite vertical flat plane surface of a constant temperature. This model is applied to study the effects of free convection currents on the flow of the fluid in the presence of a constant magnetic field. The state space technique is adopted for the solution of a one‐dimensional problem for any set of boundary conditions. The resulting formulation together with the Laplace transform techniques are applied to a thermal shock problem. The inversion of the Laplace transforms is carried out using a numerical approach. Numerical results are given and illustrated graphically for the problem. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
295.
Antonio M. Scarfone Hiroki Suyari Tatsuaki Wada 《Central European Journal of Physics》2009,7(3):414-420
We reformulate the Gauss’ law of error in presence of correlations which are taken into account by means of a deformed product
arising in the framework of the Sharma-Taneja-Mittal measure. Having reviewed the main proprieties of the generalized product
and its related algebra, we derive, according to the Maximum Likelihood Principle, a family of error distributions with an
asymptotic power-law behavior.
相似文献
296.
研究基于扩展Leslie投影矩阵的离散尺度结构种群模型的最优收获问题,约束条件包括生态平衡和开发成本等.运用凸优化理论证明了最优收获策略的存在性,导出了最优收获模式,应用模型参数给出了收获比率.结论显示:最优策略具有两阶段结构. 相似文献
297.
Brent D. Viers 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(2):131-138
End‐linking poly(dimethylsiloxane) was used to prepare bimodal elastomers networks so as to have inhomogeneous nanostructures, and also to prepare others having very broadly multimodal chain‐length distributions. Macroscopic phase separation, probably high crosslink density clusters, was observed to occur in some of the bimodal networks. The mechanical properties in simple extension and in equilibrium swelling were measured. The bimodal elastomers that were not obviously inhomogeneous showed very good mechanical properties, but the macroscopically phase‐separated networks, and the broadly multimodal network were weak. Analysis of the Mooney‐Rivlin profiles suggests that the reinforcing mechanism could have a structural component in addition to that from the limited extensibilities of the short chains. The mechanical properties and the extents of swelling support the cluster conjecture, in accord with previous morphological studies on spatially‐inhomogeneous polysiloxane elastomers. 相似文献
298.
《高分子科学杂志,A辑:纯化学与应用化学》2013,50(12):1401-1410
Abstract Electrostatically layered aluminosilicate nanocomposites have been prepared by the sequential deposition of poly(allylamine hydrochloride)/poly(acrylic acid)/poly(allylamine hydrochloride)/saponite (PAH/PAA/PAH/saponite)10 on poly(ethylene terephtalate) (PET) film. Exfoliated saponite nanoplatelets were obtained by extensive shaking, sonication, and centrifugation of a water suspension. To minimize permeability and improve the mechanical integrity, cross‐linking of composite films was carried out at different temperatures. The formation of amide linkage induced through heating was observed by Fourier Transform Infrared (FT‐IR) and x‐ray photoelectron spectroscopy (XPS). The cross‐linking of nanocomposites (PAH/PAA/PAH/saponite)10 showed 60% decrease in permeability of oxygen when compared with the pristine PET substrate film. In contrast, water permeability of the nanocomposite membrane was not affected by heating temperature and deposition cycles. 相似文献
299.
Sergio F. Sousa 《Journal of computational chemistry》2013,34(15):1354-1362
The determination of differences in solvation free energies between related drug molecules remains an important challenge in computational drug optimization, when fast and accurate calculation of differences in binding free energy are required. In this study, we have evaluated the performance of five commonly used polarized continuum model (PCM) methodologies in the determination of solvation free energies for 53 typical alcohol and alkane small molecules. In addition, the performance of these PCM methods, of a thermodynamic integration (TI) protocol and of the Poisson–Boltzmann (PB) and generalized Born (GB) methods, were tested in the determination of solvation free energies changes for 28 common alkane‐alcohol transformations, by the substitution of an hydrogen atom for a hydroxyl substituent. The results show that the solvation model D (SMD) performs better among the PCM‐based approaches in estimating solvation free energies for alcohol molecules, and solvation free energy changes for alkane‐alcohol transformations, with an average error below 1 kcal/mol for both quantities. However, for the determination of solvation free energy changes on alkane‐alcohol transformation, PB and TI yielded better results. TI was particularly accurate in the treatment of hydroxyl groups additions to aromatic rings (0.53 kcal/mol), a common transformation when optimizing drug‐binding in computer‐aided drug design. © 2013 Wiley Periodicals, Inc. 相似文献
300.
In this paper, as a first step to study the global structure of solution, we treat a class of reaction–diffusion systems with competitive interaction, and discuss a uniqueness theorem of radially symmetric solutions for the system. To do this, the comparison principle and the shooting method are employed, and the spatial profile is investigated. 相似文献