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171.
172.
《Electroanalysis》2006,18(24):2451-2457
This paper describes a layer‐by‐layer (LBL) self‐assembly process of chitosan (CTS) and gold nanoparticles (Au) on the pretreated negatively charged glassy carbon (GC) electrode to fabricate electrochemistry immunosensor with a nontoxic biomimetic interface, which provided an environment similar to a native system and allowed more freedom in orientation for immobilization of carcinoembryonic antibody (anti‐CEA) to monitor carcinoembryonic antigen (CEA). UV‐vis spectroscope, atomic force microscopy (AFM), and cyclic voltammetric (CV) measurements were used to follow the multilayer film formation. The performance of the biominetic interface and factors influencing the assay system were investigated in detail. The differential pulse voltammetry (DPV) current response is used for the CEA concentration assay. The dynamic range was from 0.50 to 80.00 ng mL?1 with a detection limit of 0.27 ng mL?1 at 3σ. In addition, the experiment results indicate that immobilization described in this proposed method exhibits a good sensitivity, selectivity, and stability. 相似文献
173.
Nash Equilibria,Variational Inequalities,and Dynamical Systems 总被引:2,自引:0,他引:2
Cavazzuti E. Pappalardo M. Passacantando M. 《Journal of Optimization Theory and Applications》2002,114(3):491-506
In this paper, we introduce some relationships between Nash equilibria, variational equilibria, and dynamical equilibria for noncooperative games. 相似文献
174.
在backstepping程序中,把非线性自适应控制和鲁棒控制连接起来,为参数化的严格反馈系统在不确定性存在的情况下,建立了一种鲁棒自适应控制方案.非线性自适应控制被用来处理系统的线性参数化部分,而鲁棒控制通过引进非线性阻尼项被用来处理不确定性部分.与现有的方案不同,作者给出了非线性阻尼项的无限种选择,而不是仅仅一种选择.通过使用一种合适的选择,能够设计一个鲁棒自适应控制器.它不仅能够保证对不确定性的鲁棒性,而且能够使输出误差任意小,以及用较小的控制努力取得较好的性能. 相似文献
175.
Jeannette Van Iseghem 《Numerical Algorithms》2002,29(1-3):267-279
A method for solving a linear system is defined. It is a Lanczos-type method, but it uses formal vector orthogonality instead of scalar orthogonality. Moreover, the dimension of vector orthogonality may vary which gives a large freedom in leading the algorithm, and controlling the numerical problems. The ideas of truncated and restarted methods are revisited. The obtained residuals are exactly orthogonal to a space of increasing dimension. Some experiments are done, the problem of finding automaticaly good directions of projection remains partly open. 相似文献
176.
In this paper, a locally computed suboptimal control strategy for a class of interconnected systems is introduced. First, optimal statefeedback control equations are derived for a finite-horizon quadratic cost. Then, the control for each subsystem is separated into two portions. The first portion stabilizes the isolated subsystem, and the second portion corresponds to the interactions. To achieve a locally calculable control, an approximation to the optimal control equations is introduced, and two iterative suboptimal control algorithms are developed. In the first algorithm, the initial conditions of subsystems are assumed to be known; in the second algorithm, this information is replaced by statistical distributions. The orders of errors in the iterations of the algorithm and in the suboptimality are given in terms of interconnections. An example with comparisons is also included to show the performance of the approach. 相似文献
177.
We analyze the statistical behavior of signals in nonlinear circuits with delayed feedback in the presence of external Markovian noise. For the special class of circuits with intense phase mixing we develop an approach for the computation of the probability distributions and multitime correlation functions based on the random phase approximation. Both Gaussian and Kubo-Andersen models of external noise statistics are analyzed and the existence of the stationary (asymptotic) random process in the long-time limit is shown. We demonstrate that a nonlinear system with chaotic behavior becomes a noise amplifier with specific statistical transformation properties. 相似文献
178.
Upper bounds for survival probability of the contact process 总被引:3,自引:0,他引:3
179.
180.
苝二酸酐与嘧啶衍生物的氢键组装 总被引:1,自引:0,他引:1
用半经验AM1方法对苝二酸酐与嘧啶衍生物的1:1及1:2氢键复合物进行理论研究,表明随着氢键数目增多,弱相互作用能变大,主体上的供电基和客体上的吸电基有利于氢键相互作用,氢键导致电子从主体流向客体.用INDO/SCI方法计算配合物的电子光谱,表明其长波吸收峰与主体相比发生兰移,各配合物的长波吸收峰位置相差不大,与实验一致.讨论吸收峰兰移的原因并对电子跃迁进行理论指认,同时得到了配合物的双质子转移势能曲线,给出了相对于N-H键的过渡态和活化能. 相似文献